Bis[1-(2-eth­oxy­phen­yl)-3-(4-nitro­phen­yl)triazenido]mercury(II)

In the title compound, [Hg(C(14)H(13)N(4)O(3))(2)], the central Hg atom (site symmetry 2) is six-coordinated by two tridentate 1-(2-eth­oxy­phen­yl)-3-(4-nitro­phen­yl)triazenide ligands through two N and one O atoms. The mononuclear complex mol­ecules are connected into two parallel chains by inter...

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Autores principales: Rofouei, Mohammad Kazem, Fereyduni, Ehsan, Attar Gharamaleki, Jafar, Bruno, Giuseppe, Amiri Rudbari, Hadi
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007946/
https://www.ncbi.nlm.nih.gov/pubmed/21588500
http://dx.doi.org/10.1107/S1600536810031326
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author Rofouei, Mohammad Kazem
Fereyduni, Ehsan
Attar Gharamaleki, Jafar
Bruno, Giuseppe
Amiri Rudbari, Hadi
author_facet Rofouei, Mohammad Kazem
Fereyduni, Ehsan
Attar Gharamaleki, Jafar
Bruno, Giuseppe
Amiri Rudbari, Hadi
author_sort Rofouei, Mohammad Kazem
collection PubMed
description In the title compound, [Hg(C(14)H(13)N(4)O(3))(2)], the central Hg atom (site symmetry 2) is six-coordinated by two tridentate 1-(2-eth­oxy­phen­yl)-3-(4-nitro­phen­yl)triazenide ligands through two N and one O atoms. The mononuclear complex mol­ecules are connected into two parallel chains by inter­molecular C—H⋯O hydrogen-bonding inter­actions. These chains are connected to each other by face-to-edge C—H⋯π inter­actions between the CH of the ethoxy groups and the aromatic rings, resulting in a two-dimensional architecture in the ac plane.
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spelling pubmed-30079462010-12-30 Bis[1-(2-eth­oxy­phen­yl)-3-(4-nitro­phen­yl)triazenido]mercury(II) Rofouei, Mohammad Kazem Fereyduni, Ehsan Attar Gharamaleki, Jafar Bruno, Giuseppe Amiri Rudbari, Hadi Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Hg(C(14)H(13)N(4)O(3))(2)], the central Hg atom (site symmetry 2) is six-coordinated by two tridentate 1-(2-eth­oxy­phen­yl)-3-(4-nitro­phen­yl)triazenide ligands through two N and one O atoms. The mononuclear complex mol­ecules are connected into two parallel chains by inter­molecular C—H⋯O hydrogen-bonding inter­actions. These chains are connected to each other by face-to-edge C—H⋯π inter­actions between the CH of the ethoxy groups and the aromatic rings, resulting in a two-dimensional architecture in the ac plane. International Union of Crystallography 2010-08-11 /pmc/articles/PMC3007946/ /pubmed/21588500 http://dx.doi.org/10.1107/S1600536810031326 Text en © Rofouei et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Rofouei, Mohammad Kazem
Fereyduni, Ehsan
Attar Gharamaleki, Jafar
Bruno, Giuseppe
Amiri Rudbari, Hadi
Bis[1-(2-eth­oxy­phen­yl)-3-(4-nitro­phen­yl)triazenido]mercury(II)
title Bis[1-(2-eth­oxy­phen­yl)-3-(4-nitro­phen­yl)triazenido]mercury(II)
title_full Bis[1-(2-eth­oxy­phen­yl)-3-(4-nitro­phen­yl)triazenido]mercury(II)
title_fullStr Bis[1-(2-eth­oxy­phen­yl)-3-(4-nitro­phen­yl)triazenido]mercury(II)
title_full_unstemmed Bis[1-(2-eth­oxy­phen­yl)-3-(4-nitro­phen­yl)triazenido]mercury(II)
title_short Bis[1-(2-eth­oxy­phen­yl)-3-(4-nitro­phen­yl)triazenido]mercury(II)
title_sort bis[1-(2-eth­oxy­phen­yl)-3-(4-nitro­phen­yl)triazenido]mercury(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007946/
https://www.ncbi.nlm.nih.gov/pubmed/21588500
http://dx.doi.org/10.1107/S1600536810031326
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