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Undecacarbonyl-1κ(3) C,2κ(4) C,3κ(4) C-{tris[4-(methylsulfanyl)phenyl]arsine-1κAs}-triangulo-triruthenium(0)
The crystal structure of the title triangulo-triruthenium compound, [Ru(3)(C(21)H(21)AsS(3))(CO)(11)], confirms that during the synthesis one equatorial carbonyl ligand is substituted by a monodentate arsine ligand, leaving one equatorial and two axial carbonyl substituents on an Ru atom. The other...
| Autores principales: | , , , , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2010
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007950/ https://www.ncbi.nlm.nih.gov/pubmed/21588476 http://dx.doi.org/10.1107/S1600536810029223 |
| _version_ | 1782194466392637440 |
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| author | Shawkataly, Omar bin Khan, Imthyaz Ahmed Sirat, Siti Syaida Yeap, Chin Sing Fun, Hoong-Kun |
| author_facet | Shawkataly, Omar bin Khan, Imthyaz Ahmed Sirat, Siti Syaida Yeap, Chin Sing Fun, Hoong-Kun |
| author_sort | Shawkataly, Omar bin |
| collection | PubMed |
| description | The crystal structure of the title triangulo-triruthenium compound, [Ru(3)(C(21)H(21)AsS(3))(CO)(11)], confirms that during the synthesis one equatorial carbonyl ligand is substituted by a monodentate arsine ligand, leaving one equatorial and two axial carbonyl substituents on an Ru atom. The other two Ru atoms each carry two equatorial and two axial carbonyl ligands. The three arsine-substituted benzene rings make dihedral angles of 77.94 (13), 86.37 (13) and 73.22 (12)° with each other. Two of the methylsulfanyl groups are disordered over two positions with refined site occupancies of 0.720 (7):0.280 (7) and 0.644 (8):0.356 (8). In the crystal structure, molecules are linked into infinite chains along the a axis by weak intermolecular C—H⋯O hydrogen bonds. |
| format | Text |
| id | pubmed-3007950 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2010 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-30079502010-12-30 Undecacarbonyl-1κ(3) C,2κ(4) C,3κ(4) C-{tris[4-(methylsulfanyl)phenyl]arsine-1κAs}-triangulo-triruthenium(0) Shawkataly, Omar bin Khan, Imthyaz Ahmed Sirat, Siti Syaida Yeap, Chin Sing Fun, Hoong-Kun Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The crystal structure of the title triangulo-triruthenium compound, [Ru(3)(C(21)H(21)AsS(3))(CO)(11)], confirms that during the synthesis one equatorial carbonyl ligand is substituted by a monodentate arsine ligand, leaving one equatorial and two axial carbonyl substituents on an Ru atom. The other two Ru atoms each carry two equatorial and two axial carbonyl ligands. The three arsine-substituted benzene rings make dihedral angles of 77.94 (13), 86.37 (13) and 73.22 (12)° with each other. Two of the methylsulfanyl groups are disordered over two positions with refined site occupancies of 0.720 (7):0.280 (7) and 0.644 (8):0.356 (8). In the crystal structure, molecules are linked into infinite chains along the a axis by weak intermolecular C—H⋯O hydrogen bonds. International Union of Crystallography 2010-08-04 /pmc/articles/PMC3007950/ /pubmed/21588476 http://dx.doi.org/10.1107/S1600536810029223 Text en © Shawkataly et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Shawkataly, Omar bin Khan, Imthyaz Ahmed Sirat, Siti Syaida Yeap, Chin Sing Fun, Hoong-Kun Undecacarbonyl-1κ(3) C,2κ(4) C,3κ(4) C-{tris[4-(methylsulfanyl)phenyl]arsine-1κAs}-triangulo-triruthenium(0) |
| title | Undecacarbonyl-1κ(3)
C,2κ(4)
C,3κ(4)
C-{tris[4-(methylsulfanyl)phenyl]arsine-1κAs}-triangulo-triruthenium(0) |
| title_full | Undecacarbonyl-1κ(3)
C,2κ(4)
C,3κ(4)
C-{tris[4-(methylsulfanyl)phenyl]arsine-1κAs}-triangulo-triruthenium(0) |
| title_fullStr | Undecacarbonyl-1κ(3)
C,2κ(4)
C,3κ(4)
C-{tris[4-(methylsulfanyl)phenyl]arsine-1κAs}-triangulo-triruthenium(0) |
| title_full_unstemmed | Undecacarbonyl-1κ(3)
C,2κ(4)
C,3κ(4)
C-{tris[4-(methylsulfanyl)phenyl]arsine-1κAs}-triangulo-triruthenium(0) |
| title_short | Undecacarbonyl-1κ(3)
C,2κ(4)
C,3κ(4)
C-{tris[4-(methylsulfanyl)phenyl]arsine-1κAs}-triangulo-triruthenium(0) |
| title_sort | undecacarbonyl-1κ(3)
c,2κ(4)
c,3κ(4)
c-{tris[4-(methylsulfanyl)phenyl]arsine-1κas}-triangulo-triruthenium(0) |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007950/ https://www.ncbi.nlm.nih.gov/pubmed/21588476 http://dx.doi.org/10.1107/S1600536810029223 |
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