Racemic tricarbonyl[(4a,5,6,7,8,8a-η)-2-phenyl-3,4-dihydro-2H-1-benzopyran]chromium(0)

The title compound, [Cr(C(15)H(14)O)(CO)(3)], displays a distorted envelope configuration of the dihydro­pyrane ring. The dihedral angle between the phenyl and phenyl­ene rings is 50.63 (4)°. The Cr(0) atom is coordinated by three CO groups and the phenyl­ene ring of the flavan ligand in an η(6) mod...

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Autores principales: van Tonder, Johannes H., Bezuidenhoudt, Barend C. B., Janse van Rensburg, J. Marthinus
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007955/
https://www.ncbi.nlm.nih.gov/pubmed/21588503
http://dx.doi.org/10.1107/S1600536810031028
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author van Tonder, Johannes H.
Bezuidenhoudt, Barend C. B.
Janse van Rensburg, J. Marthinus
author_facet van Tonder, Johannes H.
Bezuidenhoudt, Barend C. B.
Janse van Rensburg, J. Marthinus
author_sort van Tonder, Johannes H.
collection PubMed
description The title compound, [Cr(C(15)H(14)O)(CO)(3)], displays a distorted envelope configuration of the dihydro­pyrane ring. The dihedral angle between the phenyl and phenyl­ene rings is 50.63 (4)°. The Cr(0) atom is coordinated by three CO groups and the phenyl­ene ring of the flavan ligand in an η(6) mode, with a common arene-to-metal distance
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spelling pubmed-30079552010-12-30 Racemic tricarbonyl[(4a,5,6,7,8,8a-η)-2-phenyl-3,4-dihydro-2H-1-benzopyran]chromium(0) van Tonder, Johannes H. Bezuidenhoudt, Barend C. B. Janse van Rensburg, J. Marthinus Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Cr(C(15)H(14)O)(CO)(3)], displays a distorted envelope configuration of the dihydro­pyrane ring. The dihedral angle between the phenyl and phenyl­ene rings is 50.63 (4)°. The Cr(0) atom is coordinated by three CO groups and the phenyl­ene ring of the flavan ligand in an η(6) mode, with a common arene-to-metal distance International Union of Crystallography 2010-08-11 /pmc/articles/PMC3007955/ /pubmed/21588503 http://dx.doi.org/10.1107/S1600536810031028 Text en © Tonder et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
van Tonder, Johannes H.
Bezuidenhoudt, Barend C. B.
Janse van Rensburg, J. Marthinus
Racemic tricarbonyl[(4a,5,6,7,8,8a-η)-2-phenyl-3,4-dihydro-2H-1-benzopyran]chromium(0)
title Racemic tricarbonyl[(4a,5,6,7,8,8a-η)-2-phenyl-3,4-dihydro-2H-1-benzopyran]chromium(0)
title_full Racemic tricarbonyl[(4a,5,6,7,8,8a-η)-2-phenyl-3,4-dihydro-2H-1-benzopyran]chromium(0)
title_fullStr Racemic tricarbonyl[(4a,5,6,7,8,8a-η)-2-phenyl-3,4-dihydro-2H-1-benzopyran]chromium(0)
title_full_unstemmed Racemic tricarbonyl[(4a,5,6,7,8,8a-η)-2-phenyl-3,4-dihydro-2H-1-benzopyran]chromium(0)
title_short Racemic tricarbonyl[(4a,5,6,7,8,8a-η)-2-phenyl-3,4-dihydro-2H-1-benzopyran]chromium(0)
title_sort racemic tricarbonyl[(4a,5,6,7,8,8a-η)-2-phenyl-3,4-dihydro-2h-1-benzopyran]chromium(0)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007955/
https://www.ncbi.nlm.nih.gov/pubmed/21588503
http://dx.doi.org/10.1107/S1600536810031028
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AT jansevanrensburgjmarthinus racemictricarbonyl4a56788aē2phenyl34dihydro2h1benzopyranchromium0

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