{2-[(2-Carbamothiol­ylhydrazin-1-yl­idene-κ(2) N (1),S)meth­yl]-6-hy­droxy­phenolato-κO (1)}(triphenyl­phosphine-κP)nickel(II) chloride

The deprotonated Schiff base ligand in the title compound, [Ni(C(8)H(8)N(3)O(2)S)(C(18)H(15)P)]Cl, functions as an N,O,S-chelating anion to the phosphine-coordinated Ni atom, which exists in a distorted square-planar geometry. The hy­droxy group forms an intra­molecular O—H⋯O hydrogen bond. The two...

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Detalles Bibliográficos
Autores principales: Shawish, Hana Bashir, Tan, Kong Wai, Maah, M. Jamil, Ng, Seik Weng
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007957/
https://www.ncbi.nlm.nih.gov/pubmed/21588494
http://dx.doi.org/10.1107/S1600536810031065
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author Shawish, Hana Bashir
Tan, Kong Wai
Maah, M. Jamil
Ng, Seik Weng
author_facet Shawish, Hana Bashir
Tan, Kong Wai
Maah, M. Jamil
Ng, Seik Weng
author_sort Shawish, Hana Bashir
collection PubMed
description The deprotonated Schiff base ligand in the title compound, [Ni(C(8)H(8)N(3)O(2)S)(C(18)H(15)P)]Cl, functions as an N,O,S-chelating anion to the phosphine-coordinated Ni atom, which exists in a distorted square-planar geometry. The hy­droxy group forms an intra­molecular O—H⋯O hydrogen bond. The two amino groups of the cation are hydrogen-bond donors to the chloride anion; the hydrogen bonds generate a chain structure running along the b axis.
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spelling pubmed-30079572010-12-30 {2-[(2-Carbamothiol­ylhydrazin-1-yl­idene-κ(2) N (1),S)meth­yl]-6-hy­droxy­phenolato-κO (1)}(triphenyl­phosphine-κP)nickel(II) chloride Shawish, Hana Bashir Tan, Kong Wai Maah, M. Jamil Ng, Seik Weng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The deprotonated Schiff base ligand in the title compound, [Ni(C(8)H(8)N(3)O(2)S)(C(18)H(15)P)]Cl, functions as an N,O,S-chelating anion to the phosphine-coordinated Ni atom, which exists in a distorted square-planar geometry. The hy­droxy group forms an intra­molecular O—H⋯O hydrogen bond. The two amino groups of the cation are hydrogen-bond donors to the chloride anion; the hydrogen bonds generate a chain structure running along the b axis. International Union of Crystallography 2010-08-11 /pmc/articles/PMC3007957/ /pubmed/21588494 http://dx.doi.org/10.1107/S1600536810031065 Text en © Shawish et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Shawish, Hana Bashir
Tan, Kong Wai
Maah, M. Jamil
Ng, Seik Weng
{2-[(2-Carbamothiol­ylhydrazin-1-yl­idene-κ(2) N (1),S)meth­yl]-6-hy­droxy­phenolato-κO (1)}(triphenyl­phosphine-κP)nickel(II) chloride
title {2-[(2-Carbamothiol­ylhydrazin-1-yl­idene-κ(2) N (1),S)meth­yl]-6-hy­droxy­phenolato-κO (1)}(triphenyl­phosphine-κP)nickel(II) chloride
title_full {2-[(2-Carbamothiol­ylhydrazin-1-yl­idene-κ(2) N (1),S)meth­yl]-6-hy­droxy­phenolato-κO (1)}(triphenyl­phosphine-κP)nickel(II) chloride
title_fullStr {2-[(2-Carbamothiol­ylhydrazin-1-yl­idene-κ(2) N (1),S)meth­yl]-6-hy­droxy­phenolato-κO (1)}(triphenyl­phosphine-κP)nickel(II) chloride
title_full_unstemmed {2-[(2-Carbamothiol­ylhydrazin-1-yl­idene-κ(2) N (1),S)meth­yl]-6-hy­droxy­phenolato-κO (1)}(triphenyl­phosphine-κP)nickel(II) chloride
title_short {2-[(2-Carbamothiol­ylhydrazin-1-yl­idene-κ(2) N (1),S)meth­yl]-6-hy­droxy­phenolato-κO (1)}(triphenyl­phosphine-κP)nickel(II) chloride
title_sort {2-[(2-carbamothiol­ylhydrazin-1-yl­idene-κ(2) n (1),s)meth­yl]-6-hy­droxy­phenolato-κo (1)}(triphenyl­phosphine-κp)nickel(ii) chloride
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007957/
https://www.ncbi.nlm.nih.gov/pubmed/21588494
http://dx.doi.org/10.1107/S1600536810031065
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AT ngseikweng 22carbamothiolylhydrazin1ylidenek2n1smethyl6hydroxyphenolatoko1triphenylphosphinekpnickeliichloride

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