Bis(4-meth­oxy­benzoato)-κ(2) O,O′;κO-bis­(nicotinamide-κN (1))zinc(II)

The asymmetric unit of the title complex, [Zn(C(8)H(7)O(3))(2)(C(6)H(6)N(2)O)(2)], contains three crystallographically independent mol­ecules with similar configurations. The Zn(II) cation is coordinated by two N atoms of two nicotinamide ligands and three O atoms from two 4-meth­oxy­benzoate anions...

Descripción completa

Detalles Bibliográficos
Autores principales: Hökelek, Tuncer, Saka, Güner, Tercan, Barış, Tenlik, Erdinç, Necefoğlu, Hacali
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007960/
https://www.ncbi.nlm.nih.gov/pubmed/21588535
http://dx.doi.org/10.1107/S1600536810032885
_version_ 1782194468720476160
author Hökelek, Tuncer
Saka, Güner
Tercan, Barış
Tenlik, Erdinç
Necefoğlu, Hacali
author_facet Hökelek, Tuncer
Saka, Güner
Tercan, Barış
Tenlik, Erdinç
Necefoğlu, Hacali
author_sort Hökelek, Tuncer
collection PubMed
description The asymmetric unit of the title complex, [Zn(C(8)H(7)O(3))(2)(C(6)H(6)N(2)O)(2)], contains three crystallographically independent mol­ecules with similar configurations. The Zn(II) cation is coordinated by two N atoms of two nicotinamide ligands and three O atoms from two 4-meth­oxy­benzoate anions in a distorted trigonal-bipyramidal geometry. In each independent mol­ecule, one Zn—O bond distance [2.5181 (12), 2.5931 (12) and 2.4085 (12) Å for the three mol­ecules] is significantly longer than the other two. In the crystal structure, extensive N—H⋯O and C—H⋯O hydrogen bonding links the mol­ecules into a three-dimensional network. π–π contacts between the pyridine rings and between the pyridine and benzene rings [centroid–centroid distances = 3.7655 (9) and 3.8453 (10) Å, respectively] further stabilize the crystal structure.
format Text
id pubmed-3007960
institution National Center for Biotechnology Information
language English
publishDate 2010
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-30079602010-12-30 Bis(4-meth­oxy­benzoato)-κ(2) O,O′;κO-bis­(nicotinamide-κN (1))zinc(II) Hökelek, Tuncer Saka, Güner Tercan, Barış Tenlik, Erdinç Necefoğlu, Hacali Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the title complex, [Zn(C(8)H(7)O(3))(2)(C(6)H(6)N(2)O)(2)], contains three crystallographically independent mol­ecules with similar configurations. The Zn(II) cation is coordinated by two N atoms of two nicotinamide ligands and three O atoms from two 4-meth­oxy­benzoate anions in a distorted trigonal-bipyramidal geometry. In each independent mol­ecule, one Zn—O bond distance [2.5181 (12), 2.5931 (12) and 2.4085 (12) Å for the three mol­ecules] is significantly longer than the other two. In the crystal structure, extensive N—H⋯O and C—H⋯O hydrogen bonding links the mol­ecules into a three-dimensional network. π–π contacts between the pyridine rings and between the pyridine and benzene rings [centroid–centroid distances = 3.7655 (9) and 3.8453 (10) Å, respectively] further stabilize the crystal structure. International Union of Crystallography 2010-08-21 /pmc/articles/PMC3007960/ /pubmed/21588535 http://dx.doi.org/10.1107/S1600536810032885 Text en © Hökelek et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Hökelek, Tuncer
Saka, Güner
Tercan, Barış
Tenlik, Erdinç
Necefoğlu, Hacali
Bis(4-meth­oxy­benzoato)-κ(2) O,O′;κO-bis­(nicotinamide-κN (1))zinc(II)
title Bis(4-meth­oxy­benzoato)-κ(2) O,O′;κO-bis­(nicotinamide-κN (1))zinc(II)
title_full Bis(4-meth­oxy­benzoato)-κ(2) O,O′;κO-bis­(nicotinamide-κN (1))zinc(II)
title_fullStr Bis(4-meth­oxy­benzoato)-κ(2) O,O′;κO-bis­(nicotinamide-κN (1))zinc(II)
title_full_unstemmed Bis(4-meth­oxy­benzoato)-κ(2) O,O′;κO-bis­(nicotinamide-κN (1))zinc(II)
title_short Bis(4-meth­oxy­benzoato)-κ(2) O,O′;κO-bis­(nicotinamide-κN (1))zinc(II)
title_sort bis(4-meth­oxy­benzoato)-κ(2) o,o′;κo-bis­(nicotinamide-κn (1))zinc(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007960/
https://www.ncbi.nlm.nih.gov/pubmed/21588535
http://dx.doi.org/10.1107/S1600536810032885
work_keys_str_mv AT hokelektuncer bis4methoxybenzoatok2ookobisnicotinamidekn1zincii
AT sakaguner bis4methoxybenzoatok2ookobisnicotinamidekn1zincii
AT tercanbarıs bis4methoxybenzoatok2ookobisnicotinamidekn1zincii
AT tenlikerdinc bis4methoxybenzoatok2ookobisnicotinamidekn1zincii
AT necefogluhacali bis4methoxybenzoatok2ookobisnicotinamidekn1zincii

Ejemplares similares