(2E)-N′-[(E)-4-Chloro­benzyl­idene]-3-phenyl­prop-2-enohydrazide monohydrate

The conformation about each of the imine and ethene bonds in the title hydrazide hydrate, C(16)H(13)ClN(2)O·H(2)O, is E. The hydrazide mol­ecule is approximately planar (r.m.s. deviation of the 20 non-H atoms = 0.172 Å). The most significant twist occurs about the ethene bond [C—C=C—C = 164.1 (5)°]...

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Autores principales: Carvalho, Samir A., da Silva, Edson F., Fraga, Carlos A. M., Wardell, Solange M. S. V., Wardell, James L., Tiekink, Edward R. T.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007965/
https://www.ncbi.nlm.nih.gov/pubmed/21588739
http://dx.doi.org/10.1107/S160053681003388X
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author Carvalho, Samir A.
da Silva, Edson F.
Fraga, Carlos A. M.
Wardell, Solange M. S. V.
Wardell, James L.
Tiekink, Edward R. T.
author_facet Carvalho, Samir A.
da Silva, Edson F.
Fraga, Carlos A. M.
Wardell, Solange M. S. V.
Wardell, James L.
Tiekink, Edward R. T.
author_sort Carvalho, Samir A.
collection PubMed
description The conformation about each of the imine and ethene bonds in the title hydrazide hydrate, C(16)H(13)ClN(2)O·H(2)O, is E. The hydrazide mol­ecule is approximately planar (r.m.s. deviation of the 20 non-H atoms = 0.172 Å). The most significant twist occurs about the ethene bond [C—C=C—C = 164.1 (5)°] and the dihedral angle formed between the benzene rings is 5.3 (2)°]. In the crystal, the presence of N—H⋯O(w) and O—H⋯O(c) (× 2; w = water and c = carbon­yl) hydrogen bonds leads to a supra­molecular array in the bc plane.
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spelling pubmed-30079652010-12-30 (2E)-N′-[(E)-4-Chloro­benzyl­idene]-3-phenyl­prop-2-enohydrazide monohydrate Carvalho, Samir A. da Silva, Edson F. Fraga, Carlos A. M. Wardell, Solange M. S. V. Wardell, James L. Tiekink, Edward R. T. Acta Crystallogr Sect E Struct Rep Online Organic Papers The conformation about each of the imine and ethene bonds in the title hydrazide hydrate, C(16)H(13)ClN(2)O·H(2)O, is E. The hydrazide mol­ecule is approximately planar (r.m.s. deviation of the 20 non-H atoms = 0.172 Å). The most significant twist occurs about the ethene bond [C—C=C—C = 164.1 (5)°] and the dihedral angle formed between the benzene rings is 5.3 (2)°]. In the crystal, the presence of N—H⋯O(w) and O—H⋯O(c) (× 2; w = water and c = carbon­yl) hydrogen bonds leads to a supra­molecular array in the bc plane. International Union of Crystallography 2010-08-28 /pmc/articles/PMC3007965/ /pubmed/21588739 http://dx.doi.org/10.1107/S160053681003388X Text en © Carvalho et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Carvalho, Samir A.
da Silva, Edson F.
Fraga, Carlos A. M.
Wardell, Solange M. S. V.
Wardell, James L.
Tiekink, Edward R. T.
(2E)-N′-[(E)-4-Chloro­benzyl­idene]-3-phenyl­prop-2-enohydrazide monohydrate
title (2E)-N′-[(E)-4-Chloro­benzyl­idene]-3-phenyl­prop-2-enohydrazide monohydrate
title_full (2E)-N′-[(E)-4-Chloro­benzyl­idene]-3-phenyl­prop-2-enohydrazide monohydrate
title_fullStr (2E)-N′-[(E)-4-Chloro­benzyl­idene]-3-phenyl­prop-2-enohydrazide monohydrate
title_full_unstemmed (2E)-N′-[(E)-4-Chloro­benzyl­idene]-3-phenyl­prop-2-enohydrazide monohydrate
title_short (2E)-N′-[(E)-4-Chloro­benzyl­idene]-3-phenyl­prop-2-enohydrazide monohydrate
title_sort (2e)-n′-[(e)-4-chloro­benzyl­idene]-3-phenyl­prop-2-enohydrazide monohydrate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007965/
https://www.ncbi.nlm.nih.gov/pubmed/21588739
http://dx.doi.org/10.1107/S160053681003388X
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