Dieth­yl(hy­droxy)ammonium 3-carb­oxy­benzoate

In the title molecular compound, C(4)H(12)NO(+)·C(8)H(5)O(4) (−), the N,N-dieth­yl(hy­droxy)ammonium cation (DTHA) is linked to the 3-carb­oxy­benzoate anion (HBDL) by O—H⋯O and N—H⋯O hydrogen bonds with a graph-set motif R (2) (2)(7). In the crystal, helical chains are formed by O—H⋯O hydrogen bond...

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Detalles Bibliográficos
Autores principales: Guo, Yun, Wang, Cong, Chen, Hai-Xiang
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007967/
https://www.ncbi.nlm.nih.gov/pubmed/21588674
http://dx.doi.org/10.1107/S1600536810030746
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author Guo, Yun
Wang, Cong
Chen, Hai-Xiang
author_facet Guo, Yun
Wang, Cong
Chen, Hai-Xiang
author_sort Guo, Yun
collection PubMed
description In the title molecular compound, C(4)H(12)NO(+)·C(8)H(5)O(4) (−), the N,N-dieth­yl(hy­droxy)ammonium cation (DTHA) is linked to the 3-carb­oxy­benzoate anion (HBDL) by O—H⋯O and N—H⋯O hydrogen bonds with a graph-set motif R (2) (2)(7). In the crystal, helical chains are formed by O—H⋯O hydrogen bonds, propagating along [010]. The crystal structure is further stabilized by π–π inter­actions between inversion-related HBDL benzene rings [centroid–centroid distance = 3.900 (4) Å] and C—H⋯O inter­actions.
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spelling pubmed-30079672010-12-30 Dieth­yl(hy­droxy)ammonium 3-carb­oxy­benzoate Guo, Yun Wang, Cong Chen, Hai-Xiang Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title molecular compound, C(4)H(12)NO(+)·C(8)H(5)O(4) (−), the N,N-dieth­yl(hy­droxy)ammonium cation (DTHA) is linked to the 3-carb­oxy­benzoate anion (HBDL) by O—H⋯O and N—H⋯O hydrogen bonds with a graph-set motif R (2) (2)(7). In the crystal, helical chains are formed by O—H⋯O hydrogen bonds, propagating along [010]. The crystal structure is further stabilized by π–π inter­actions between inversion-related HBDL benzene rings [centroid–centroid distance = 3.900 (4) Å] and C—H⋯O inter­actions. International Union of Crystallography 2010-08-18 /pmc/articles/PMC3007967/ /pubmed/21588674 http://dx.doi.org/10.1107/S1600536810030746 Text en © Guo et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Guo, Yun
Wang, Cong
Chen, Hai-Xiang
Dieth­yl(hy­droxy)ammonium 3-carb­oxy­benzoate
title Dieth­yl(hy­droxy)ammonium 3-carb­oxy­benzoate
title_full Dieth­yl(hy­droxy)ammonium 3-carb­oxy­benzoate
title_fullStr Dieth­yl(hy­droxy)ammonium 3-carb­oxy­benzoate
title_full_unstemmed Dieth­yl(hy­droxy)ammonium 3-carb­oxy­benzoate
title_short Dieth­yl(hy­droxy)ammonium 3-carb­oxy­benzoate
title_sort dieth­yl(hy­droxy)ammonium 3-carb­oxy­benzoate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007967/
https://www.ncbi.nlm.nih.gov/pubmed/21588674
http://dx.doi.org/10.1107/S1600536810030746
work_keys_str_mv AT guoyun diethylhydroxyammonium3carboxybenzoate
AT wangcong diethylhydroxyammonium3carboxybenzoate
AT chenhaixiang diethylhydroxyammonium3carboxybenzoate

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