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(Z)-1-Acetyl-3-[2-oxo-1-phenyl-2-(3-pyridyl)ethylidene]indolin-2-one
The title compound, C(23)H(16)N(2)O(3), exists in a Z configuration with respect to the acyclic C=C bond. The pyridine and phenyl rings are oriented at dihedral angles of 72.97 (4) and 45.05 (4)°, respectively, with respect to the almost planar indoline ring system [maximum deviation 0.080 (1) Å]. T...
Autores principales: | , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2010
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007968/ https://www.ncbi.nlm.nih.gov/pubmed/21588602 http://dx.doi.org/10.1107/S1600536810030874 |
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author | Fun, Hoong-Kun Goh, Jia Hao Yu, Haitao Zhang, Yan |
author_facet | Fun, Hoong-Kun Goh, Jia Hao Yu, Haitao Zhang, Yan |
author_sort | Fun, Hoong-Kun |
collection | PubMed |
description | The title compound, C(23)H(16)N(2)O(3), exists in a Z configuration with respect to the acyclic C=C bond. The pyridine and phenyl rings are oriented at dihedral angles of 72.97 (4) and 45.05 (4)°, respectively, with respect to the almost planar indoline ring system [maximum deviation 0.080 (1) Å]. The pyridine and phenyl rings are oriented almost perpendicular to each other [dihedral angle 88.93 (5)°]. In the crystal, molecules are interconnected into a three-dimensional framework via intermolecular C—H⋯O and C—H⋯N hydrogen bonds and weak π–π interactions [centroid–centroid distance = 3.681 (1) Å]. |
format | Text |
id | pubmed-3007968 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2010 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-30079682010-12-30 (Z)-1-Acetyl-3-[2-oxo-1-phenyl-2-(3-pyridyl)ethylidene]indolin-2-one Fun, Hoong-Kun Goh, Jia Hao Yu, Haitao Zhang, Yan Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(23)H(16)N(2)O(3), exists in a Z configuration with respect to the acyclic C=C bond. The pyridine and phenyl rings are oriented at dihedral angles of 72.97 (4) and 45.05 (4)°, respectively, with respect to the almost planar indoline ring system [maximum deviation 0.080 (1) Å]. The pyridine and phenyl rings are oriented almost perpendicular to each other [dihedral angle 88.93 (5)°]. In the crystal, molecules are interconnected into a three-dimensional framework via intermolecular C—H⋯O and C—H⋯N hydrogen bonds and weak π–π interactions [centroid–centroid distance = 3.681 (1) Å]. International Union of Crystallography 2010-08-11 /pmc/articles/PMC3007968/ /pubmed/21588602 http://dx.doi.org/10.1107/S1600536810030874 Text en © Fun et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Fun, Hoong-Kun Goh, Jia Hao Yu, Haitao Zhang, Yan (Z)-1-Acetyl-3-[2-oxo-1-phenyl-2-(3-pyridyl)ethylidene]indolin-2-one |
title | (Z)-1-Acetyl-3-[2-oxo-1-phenyl-2-(3-pyridyl)ethylidene]indolin-2-one |
title_full | (Z)-1-Acetyl-3-[2-oxo-1-phenyl-2-(3-pyridyl)ethylidene]indolin-2-one |
title_fullStr | (Z)-1-Acetyl-3-[2-oxo-1-phenyl-2-(3-pyridyl)ethylidene]indolin-2-one |
title_full_unstemmed | (Z)-1-Acetyl-3-[2-oxo-1-phenyl-2-(3-pyridyl)ethylidene]indolin-2-one |
title_short | (Z)-1-Acetyl-3-[2-oxo-1-phenyl-2-(3-pyridyl)ethylidene]indolin-2-one |
title_sort | (z)-1-acetyl-3-[2-oxo-1-phenyl-2-(3-pyridyl)ethylidene]indolin-2-one |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007968/ https://www.ncbi.nlm.nih.gov/pubmed/21588602 http://dx.doi.org/10.1107/S1600536810030874 |
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