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Tetra-μ-acetato-κ(8) O:O′-bis{[4-methyl-N-(4-methylphenyl)pyridin-2-amine-κN (1)]copper(II)}
The title complex, [Cu(2)(CH(3)COO)(4)(C(13)H(14)N(2))(2)], features a binuclear molecule, which lies about a crystallographic centre of inversion; the four acetate ions each bridge a pair of Cu(II) atoms. The coordination of the metal atom is distorted octahedral within a donor set defined by fou...
Autores principales: | , , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2010
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007970/ https://www.ncbi.nlm.nih.gov/pubmed/21588497 http://dx.doi.org/10.1107/S1600536810031168 |
Sumario: | The title complex, [Cu(2)(CH(3)COO)(4)(C(13)H(14)N(2))(2)], features a binuclear molecule, which lies about a crystallographic centre of inversion; the four acetate ions each bridge a pair of Cu(II) atoms. The coordination of the metal atom is distorted octahedral within a donor set defined by four O atoms, the heterocyclic N atom and the second Cu atom. The pyridine ring is twisted with respect to the tolyl ring and forms a dihedral angle of 35.34 (9)°. A bifurcated N—H⋯(O,O) hydrogen bond is present, linking the amine group to two carboxylate O atoms derived from different acetate ions. In the crystal, C—H⋯π interactions link molecules into a supramolecular array in the bc plane. |
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