Cargando…

Tetra-μ-acetato-κ(8) O:O′-bis­{[4-methyl-N-(4-methyl­phen­yl)pyridin-2-amine-κN (1)]copper(II)}

The title complex, [Cu(2)(CH(3)COO)(4)(C(13)H(14)N(2))(2)], features a binuclear mol­ecule, which lies about a crystallographic centre of inversion; the four acetate ions each bridge a pair of Cu(II) atoms. The coordination of the metal atom is distorted octa­hedral within a donor set defined by fou...

Descripción completa

Detalles Bibliográficos
Autores principales: Fairuz, Zainal A., Aiyub, Zaharah, Abdullah, Zanariah, Ng, Seik Weng, Tiekink, Edward R. T.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007970/
https://www.ncbi.nlm.nih.gov/pubmed/21588497
http://dx.doi.org/10.1107/S1600536810031168
_version_ 1782194471112278016
author Fairuz, Zainal A.
Aiyub, Zaharah
Abdullah, Zanariah
Ng, Seik Weng
Tiekink, Edward R. T.
author_facet Fairuz, Zainal A.
Aiyub, Zaharah
Abdullah, Zanariah
Ng, Seik Weng
Tiekink, Edward R. T.
author_sort Fairuz, Zainal A.
collection PubMed
description The title complex, [Cu(2)(CH(3)COO)(4)(C(13)H(14)N(2))(2)], features a binuclear mol­ecule, which lies about a crystallographic centre of inversion; the four acetate ions each bridge a pair of Cu(II) atoms. The coordination of the metal atom is distorted octa­hedral within a donor set defined by four O atoms, the heterocyclic N atom and the second Cu atom. The pyridine ring is twisted with respect to the tolyl ring and forms a dihedral angle of 35.34 (9)°. A bifurcated N—H⋯(O,O) hydrogen bond is present, linking the amine group to two carboxyl­ate O atoms derived from different acetate ions. In the crystal, C—H⋯π inter­actions link mol­ecules into a supra­molecular array in the bc plane.
format Text
id pubmed-3007970
institution National Center for Biotechnology Information
language English
publishDate 2010
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-30079702010-12-30 Tetra-μ-acetato-κ(8) O:O′-bis­{[4-methyl-N-(4-methyl­phen­yl)pyridin-2-amine-κN (1)]copper(II)} Fairuz, Zainal A. Aiyub, Zaharah Abdullah, Zanariah Ng, Seik Weng Tiekink, Edward R. T. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title complex, [Cu(2)(CH(3)COO)(4)(C(13)H(14)N(2))(2)], features a binuclear mol­ecule, which lies about a crystallographic centre of inversion; the four acetate ions each bridge a pair of Cu(II) atoms. The coordination of the metal atom is distorted octa­hedral within a donor set defined by four O atoms, the heterocyclic N atom and the second Cu atom. The pyridine ring is twisted with respect to the tolyl ring and forms a dihedral angle of 35.34 (9)°. A bifurcated N—H⋯(O,O) hydrogen bond is present, linking the amine group to two carboxyl­ate O atoms derived from different acetate ions. In the crystal, C—H⋯π inter­actions link mol­ecules into a supra­molecular array in the bc plane. International Union of Crystallography 2010-08-11 /pmc/articles/PMC3007970/ /pubmed/21588497 http://dx.doi.org/10.1107/S1600536810031168 Text en © Fairuz et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Fairuz, Zainal A.
Aiyub, Zaharah
Abdullah, Zanariah
Ng, Seik Weng
Tiekink, Edward R. T.
Tetra-μ-acetato-κ(8) O:O′-bis­{[4-methyl-N-(4-methyl­phen­yl)pyridin-2-amine-κN (1)]copper(II)}
title Tetra-μ-acetato-κ(8) O:O′-bis­{[4-methyl-N-(4-methyl­phen­yl)pyridin-2-amine-κN (1)]copper(II)}
title_full Tetra-μ-acetato-κ(8) O:O′-bis­{[4-methyl-N-(4-methyl­phen­yl)pyridin-2-amine-κN (1)]copper(II)}
title_fullStr Tetra-μ-acetato-κ(8) O:O′-bis­{[4-methyl-N-(4-methyl­phen­yl)pyridin-2-amine-κN (1)]copper(II)}
title_full_unstemmed Tetra-μ-acetato-κ(8) O:O′-bis­{[4-methyl-N-(4-methyl­phen­yl)pyridin-2-amine-κN (1)]copper(II)}
title_short Tetra-μ-acetato-κ(8) O:O′-bis­{[4-methyl-N-(4-methyl­phen­yl)pyridin-2-amine-κN (1)]copper(II)}
title_sort tetra-μ-acetato-κ(8) o:o′-bis­{[4-methyl-n-(4-methyl­phen­yl)pyridin-2-amine-κn (1)]copper(ii)}
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007970/
https://www.ncbi.nlm.nih.gov/pubmed/21588497
http://dx.doi.org/10.1107/S1600536810031168
work_keys_str_mv AT fairuzzainala tetramacetatok8oobis4methyln4methylphenylpyridin2aminekn1copperii
AT aiyubzaharah tetramacetatok8oobis4methyln4methylphenylpyridin2aminekn1copperii
AT abdullahzanariah tetramacetatok8oobis4methyln4methylphenylpyridin2aminekn1copperii
AT ngseikweng tetramacetatok8oobis4methyln4methylphenylpyridin2aminekn1copperii
AT tiekinkedwardrt tetramacetatok8oobis4methyln4methylphenylpyridin2aminekn1copperii