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catena-Poly[[[aqua­pyridine­zinc(II)]-μ(2)-3,3′-(p-phenyl­ene)diacrylato] pyridine solvate]

The title compound, {[Zn(C(12)H(8)O(4))(C(5)H(5)N)(H(2)O)]·C(5)H(5)N}(n), has been prepared by hydro­thermal reaction. The Zn(II) atom is six-coordinated by four carboxyl­ate O atoms of two p-phenylenediacrylate (ppda(2−)) ligands, one N atom of a pyridine mol­ecule and one O atom of a water mol­ecu...

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Detalles Bibliográficos
Autores principales: Su, Dongpo, Song, Desheng, Fu, Zhiyong
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007971/
https://www.ncbi.nlm.nih.gov/pubmed/21588555
http://dx.doi.org/10.1107/S1600536810033167
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author Su, Dongpo
Song, Desheng
Fu, Zhiyong
author_facet Su, Dongpo
Song, Desheng
Fu, Zhiyong
author_sort Su, Dongpo
collection PubMed
description The title compound, {[Zn(C(12)H(8)O(4))(C(5)H(5)N)(H(2)O)]·C(5)H(5)N}(n), has been prepared by hydro­thermal reaction. The Zn(II) atom is six-coordinated by four carboxyl­ate O atoms of two p-phenylenediacrylate (ppda(2−)) ligands, one N atom of a pyridine mol­ecule and one O atom of a water mol­ecule in a distorted octa­hedral environment. The carboxyl­ate groups of the ppda(2−) anions are in a bridging–chelating mode, in which two O atoms chelate one Zn(2+) ion. These connections result in an extended chain structure. Parallel packing of the chains forms a two-dimensional network with inter­molecular edge-to-face inter­actions. Further linkages between the layers through O—H⋯O hydrogen-bonding inter­actions result in a three-dimensional supra­molecular architecture with one-dimensional recta­nglar channels.
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spelling pubmed-30079712010-12-30 catena-Poly[[[aqua­pyridine­zinc(II)]-μ(2)-3,3′-(p-phenyl­ene)diacrylato] pyridine solvate] Su, Dongpo Song, Desheng Fu, Zhiyong Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, {[Zn(C(12)H(8)O(4))(C(5)H(5)N)(H(2)O)]·C(5)H(5)N}(n), has been prepared by hydro­thermal reaction. The Zn(II) atom is six-coordinated by four carboxyl­ate O atoms of two p-phenylenediacrylate (ppda(2−)) ligands, one N atom of a pyridine mol­ecule and one O atom of a water mol­ecule in a distorted octa­hedral environment. The carboxyl­ate groups of the ppda(2−) anions are in a bridging–chelating mode, in which two O atoms chelate one Zn(2+) ion. These connections result in an extended chain structure. Parallel packing of the chains forms a two-dimensional network with inter­molecular edge-to-face inter­actions. Further linkages between the layers through O—H⋯O hydrogen-bonding inter­actions result in a three-dimensional supra­molecular architecture with one-dimensional recta­nglar channels. International Union of Crystallography 2010-08-28 /pmc/articles/PMC3007971/ /pubmed/21588555 http://dx.doi.org/10.1107/S1600536810033167 Text en © Su et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Su, Dongpo
Song, Desheng
Fu, Zhiyong
catena-Poly[[[aqua­pyridine­zinc(II)]-μ(2)-3,3′-(p-phenyl­ene)diacrylato] pyridine solvate]
title catena-Poly[[[aqua­pyridine­zinc(II)]-μ(2)-3,3′-(p-phenyl­ene)diacrylato] pyridine solvate]
title_full catena-Poly[[[aqua­pyridine­zinc(II)]-μ(2)-3,3′-(p-phenyl­ene)diacrylato] pyridine solvate]
title_fullStr catena-Poly[[[aqua­pyridine­zinc(II)]-μ(2)-3,3′-(p-phenyl­ene)diacrylato] pyridine solvate]
title_full_unstemmed catena-Poly[[[aqua­pyridine­zinc(II)]-μ(2)-3,3′-(p-phenyl­ene)diacrylato] pyridine solvate]
title_short catena-Poly[[[aqua­pyridine­zinc(II)]-μ(2)-3,3′-(p-phenyl­ene)diacrylato] pyridine solvate]
title_sort catena-poly[[[aqua­pyridine­zinc(ii)]-μ(2)-3,3′-(p-phenyl­ene)diacrylato] pyridine solvate]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007971/
https://www.ncbi.nlm.nih.gov/pubmed/21588555
http://dx.doi.org/10.1107/S1600536810033167
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AT songdesheng catenapolyaquapyridinezinciim233pphenylenediacrylatopyridinesolvate
AT fuzhiyong catenapolyaquapyridinezinciim233pphenylenediacrylatopyridinesolvate