Cargando…
catena-Poly[[[aquapyridinezinc(II)]-μ(2)-3,3′-(p-phenylene)diacrylato] pyridine solvate]
The title compound, {[Zn(C(12)H(8)O(4))(C(5)H(5)N)(H(2)O)]·C(5)H(5)N}(n), has been prepared by hydrothermal reaction. The Zn(II) atom is six-coordinated by four carboxylate O atoms of two p-phenylenediacrylate (ppda(2−)) ligands, one N atom of a pyridine molecule and one O atom of a water molecu...
Autores principales: | , , |
---|---|
Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2010
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007971/ https://www.ncbi.nlm.nih.gov/pubmed/21588555 http://dx.doi.org/10.1107/S1600536810033167 |
_version_ | 1782194471339819008 |
---|---|
author | Su, Dongpo Song, Desheng Fu, Zhiyong |
author_facet | Su, Dongpo Song, Desheng Fu, Zhiyong |
author_sort | Su, Dongpo |
collection | PubMed |
description | The title compound, {[Zn(C(12)H(8)O(4))(C(5)H(5)N)(H(2)O)]·C(5)H(5)N}(n), has been prepared by hydrothermal reaction. The Zn(II) atom is six-coordinated by four carboxylate O atoms of two p-phenylenediacrylate (ppda(2−)) ligands, one N atom of a pyridine molecule and one O atom of a water molecule in a distorted octahedral environment. The carboxylate groups of the ppda(2−) anions are in a bridging–chelating mode, in which two O atoms chelate one Zn(2+) ion. These connections result in an extended chain structure. Parallel packing of the chains forms a two-dimensional network with intermolecular edge-to-face interactions. Further linkages between the layers through O—H⋯O hydrogen-bonding interactions result in a three-dimensional supramolecular architecture with one-dimensional rectanglar channels. |
format | Text |
id | pubmed-3007971 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2010 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-30079712010-12-30 catena-Poly[[[aquapyridinezinc(II)]-μ(2)-3,3′-(p-phenylene)diacrylato] pyridine solvate] Su, Dongpo Song, Desheng Fu, Zhiyong Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, {[Zn(C(12)H(8)O(4))(C(5)H(5)N)(H(2)O)]·C(5)H(5)N}(n), has been prepared by hydrothermal reaction. The Zn(II) atom is six-coordinated by four carboxylate O atoms of two p-phenylenediacrylate (ppda(2−)) ligands, one N atom of a pyridine molecule and one O atom of a water molecule in a distorted octahedral environment. The carboxylate groups of the ppda(2−) anions are in a bridging–chelating mode, in which two O atoms chelate one Zn(2+) ion. These connections result in an extended chain structure. Parallel packing of the chains forms a two-dimensional network with intermolecular edge-to-face interactions. Further linkages between the layers through O—H⋯O hydrogen-bonding interactions result in a three-dimensional supramolecular architecture with one-dimensional rectanglar channels. International Union of Crystallography 2010-08-28 /pmc/articles/PMC3007971/ /pubmed/21588555 http://dx.doi.org/10.1107/S1600536810033167 Text en © Su et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Su, Dongpo Song, Desheng Fu, Zhiyong catena-Poly[[[aquapyridinezinc(II)]-μ(2)-3,3′-(p-phenylene)diacrylato] pyridine solvate] |
title |
catena-Poly[[[aquapyridinezinc(II)]-μ(2)-3,3′-(p-phenylene)diacrylato] pyridine solvate] |
title_full |
catena-Poly[[[aquapyridinezinc(II)]-μ(2)-3,3′-(p-phenylene)diacrylato] pyridine solvate] |
title_fullStr |
catena-Poly[[[aquapyridinezinc(II)]-μ(2)-3,3′-(p-phenylene)diacrylato] pyridine solvate] |
title_full_unstemmed |
catena-Poly[[[aquapyridinezinc(II)]-μ(2)-3,3′-(p-phenylene)diacrylato] pyridine solvate] |
title_short |
catena-Poly[[[aquapyridinezinc(II)]-μ(2)-3,3′-(p-phenylene)diacrylato] pyridine solvate] |
title_sort | catena-poly[[[aquapyridinezinc(ii)]-μ(2)-3,3′-(p-phenylene)diacrylato] pyridine solvate] |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007971/ https://www.ncbi.nlm.nih.gov/pubmed/21588555 http://dx.doi.org/10.1107/S1600536810033167 |
work_keys_str_mv | AT sudongpo catenapolyaquapyridinezinciim233pphenylenediacrylatopyridinesolvate AT songdesheng catenapolyaquapyridinezinciim233pphenylenediacrylatopyridinesolvate AT fuzhiyong catenapolyaquapyridinezinciim233pphenylenediacrylatopyridinesolvate |