Ethyl 2-chloro-[2-(4-chloro­phen­yl)hydrazin-1-yl­idene]acetate

The title compound, C(10)H(10)Cl(2)N(2)O(2), features a planar C(ar)—N(H)—N=C(Cl) unit [torsion angle = 5.5 (4)°] whose benzene substituent is coplanar with it [dihedral angle = 4.7 (4)°]; this unit is slightly twisted with respect to the carboxyl –CO(2) fragment [dihedral angle = 2.2 (52)°]. The am...

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Detalles Bibliográficos
Autores principales: Asiri, Abdullah M., Zayed, Mohie E. M., Ng, Seik Weng
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007972/
https://www.ncbi.nlm.nih.gov/pubmed/21588714
http://dx.doi.org/10.1107/S1600536810032599
Descripción
Sumario:The title compound, C(10)H(10)Cl(2)N(2)O(2), features a planar C(ar)—N(H)—N=C(Cl) unit [torsion angle = 5.5 (4)°] whose benzene substituent is coplanar with it [dihedral angle = 4.7 (4)°]; this unit is slightly twisted with respect to the carboxyl –CO(2) fragment [dihedral angle = 2.2 (52)°]. The amino group acts as a hydrogen-bond donor to the carbonyl O atom of an adjacent mol­ecule; the hydrogen bond generates a helical polymer that runs along the b axis of the monoclinic unit cell.

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