Tris(ethane-1,2-diamine-κ(2) N,N′)cobalt(III) carbonate iodide tetra­hydrate

The title compound, [Co(C(2)H(8)N(2))(3)](CO(3))I·4H(2)O, crystallizes with a [Co(en)(3)](3+) cation (en is ethane-1,2-diamine), CO(3) (2−) and I(−) anions and four water mol­ecules in the asymmetric unit. In the cation, the three rings formed by the ethyl­enediamine units and the Co(III) metal ion...

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Detalles Bibliográficos
Autores principales: Brewer, Greg, Butcher, Ray J., Jasinski, Jerry P.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007973/
https://www.ncbi.nlm.nih.gov/pubmed/21588545
http://dx.doi.org/10.1107/S1600536810033143
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author Brewer, Greg
Butcher, Ray J.
Jasinski, Jerry P.
author_facet Brewer, Greg
Butcher, Ray J.
Jasinski, Jerry P.
author_sort Brewer, Greg
collection PubMed
description The title compound, [Co(C(2)H(8)N(2))(3)](CO(3))I·4H(2)O, crystallizes with a [Co(en)(3)](3+) cation (en is ethane-1,2-diamine), CO(3) (2−) and I(−) anions and four water mol­ecules in the asymmetric unit. In the cation, the three rings formed by the ethyl­enediamine units and the Co(III) metal ion are in slightly distorted twist conformations. Numerous O—H⋯O, N—H⋯O, N—H⋯I and O—H⋯I inter­molecular hydrogen bonds between the cation and two anions in concert with the four water mol­ecules dominate the crystal packing and create a supra­molecular infinite three-dimensional framework.
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spelling pubmed-30079732010-12-30 Tris(ethane-1,2-diamine-κ(2) N,N′)cobalt(III) carbonate iodide tetra­hydrate Brewer, Greg Butcher, Ray J. Jasinski, Jerry P. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Co(C(2)H(8)N(2))(3)](CO(3))I·4H(2)O, crystallizes with a [Co(en)(3)](3+) cation (en is ethane-1,2-diamine), CO(3) (2−) and I(−) anions and four water mol­ecules in the asymmetric unit. In the cation, the three rings formed by the ethyl­enediamine units and the Co(III) metal ion are in slightly distorted twist conformations. Numerous O—H⋯O, N—H⋯O, N—H⋯I and O—H⋯I inter­molecular hydrogen bonds between the cation and two anions in concert with the four water mol­ecules dominate the crystal packing and create a supra­molecular infinite three-dimensional framework. International Union of Crystallography 2010-08-21 /pmc/articles/PMC3007973/ /pubmed/21588545 http://dx.doi.org/10.1107/S1600536810033143 Text en © Brewer et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Brewer, Greg
Butcher, Ray J.
Jasinski, Jerry P.
Tris(ethane-1,2-diamine-κ(2) N,N′)cobalt(III) carbonate iodide tetra­hydrate
title Tris(ethane-1,2-diamine-κ(2) N,N′)cobalt(III) carbonate iodide tetra­hydrate
title_full Tris(ethane-1,2-diamine-κ(2) N,N′)cobalt(III) carbonate iodide tetra­hydrate
title_fullStr Tris(ethane-1,2-diamine-κ(2) N,N′)cobalt(III) carbonate iodide tetra­hydrate
title_full_unstemmed Tris(ethane-1,2-diamine-κ(2) N,N′)cobalt(III) carbonate iodide tetra­hydrate
title_short Tris(ethane-1,2-diamine-κ(2) N,N′)cobalt(III) carbonate iodide tetra­hydrate
title_sort tris(ethane-1,2-diamine-κ(2) n,n′)cobalt(iii) carbonate iodide tetra­hydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007973/
https://www.ncbi.nlm.nih.gov/pubmed/21588545
http://dx.doi.org/10.1107/S1600536810033143
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AT butcherrayj trisethane12diaminek2nncobaltiiicarbonateiodidetetrahydrate
AT jasinskijerryp trisethane12diaminek2nncobaltiiicarbonateiodidetetrahydrate

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