(N-sec-Butyl-N-n-propyl­dithio­carbamato-κ(2) S,S′)triphenyl­tin(IV)

The Sn atom in the title compound, [Sn(C(6)H(5))(3)(C(8)H(16)NS(2))], is penta­coordinated by two S atoms, derived from an asymmetrically coordinating dithio­carbamate ligand, and three ipso-C atoms. The coordination geometry is inter­mediate between square-pyramidal and trigonal-bipyramidal, with a...

Descripción completa

Detalles Bibliográficos
Autores principales: Awang, Normah, Baba, Ibrahim, Yamin, Bohari M., Ng, Seik Weng, Tiekink, Edward R. T.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007978/
https://www.ncbi.nlm.nih.gov/pubmed/21588542
http://dx.doi.org/10.1107/S1600536810033039
_version_ 1782194473011249152
author Awang, Normah
Baba, Ibrahim
Yamin, Bohari M.
Ng, Seik Weng
Tiekink, Edward R. T.
author_facet Awang, Normah
Baba, Ibrahim
Yamin, Bohari M.
Ng, Seik Weng
Tiekink, Edward R. T.
author_sort Awang, Normah
collection PubMed
description The Sn atom in the title compound, [Sn(C(6)H(5))(3)(C(8)H(16)NS(2))], is penta­coordinated by two S atoms, derived from an asymmetrically coordinating dithio­carbamate ligand, and three ipso-C atoms. The coordination geometry is inter­mediate between square-pyramidal and trigonal-bipyramidal, with a leaning towards the latter. The presence of close intra­molecular C—H⋯S contacts preclude the S atoms from forming significant inter­molecular inter­actions. Rather, mol­ecules are consolid­ated in the crystal structure by C—H⋯π inter­actions.
format Text
id pubmed-3007978
institution National Center for Biotechnology Information
language English
publishDate 2010
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-30079782010-12-30 (N-sec-Butyl-N-n-propyl­dithio­carbamato-κ(2) S,S′)triphenyl­tin(IV) Awang, Normah Baba, Ibrahim Yamin, Bohari M. Ng, Seik Weng Tiekink, Edward R. T. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The Sn atom in the title compound, [Sn(C(6)H(5))(3)(C(8)H(16)NS(2))], is penta­coordinated by two S atoms, derived from an asymmetrically coordinating dithio­carbamate ligand, and three ipso-C atoms. The coordination geometry is inter­mediate between square-pyramidal and trigonal-bipyramidal, with a leaning towards the latter. The presence of close intra­molecular C—H⋯S contacts preclude the S atoms from forming significant inter­molecular inter­actions. Rather, mol­ecules are consolid­ated in the crystal structure by C—H⋯π inter­actions. International Union of Crystallography 2010-08-21 /pmc/articles/PMC3007978/ /pubmed/21588542 http://dx.doi.org/10.1107/S1600536810033039 Text en © Awang et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Awang, Normah
Baba, Ibrahim
Yamin, Bohari M.
Ng, Seik Weng
Tiekink, Edward R. T.
(N-sec-Butyl-N-n-propyl­dithio­carbamato-κ(2) S,S′)triphenyl­tin(IV)
title (N-sec-Butyl-N-n-propyl­dithio­carbamato-κ(2) S,S′)triphenyl­tin(IV)
title_full (N-sec-Butyl-N-n-propyl­dithio­carbamato-κ(2) S,S′)triphenyl­tin(IV)
title_fullStr (N-sec-Butyl-N-n-propyl­dithio­carbamato-κ(2) S,S′)triphenyl­tin(IV)
title_full_unstemmed (N-sec-Butyl-N-n-propyl­dithio­carbamato-κ(2) S,S′)triphenyl­tin(IV)
title_short (N-sec-Butyl-N-n-propyl­dithio­carbamato-κ(2) S,S′)triphenyl­tin(IV)
title_sort (n-sec-butyl-n-n-propyl­dithio­carbamato-κ(2) s,s′)triphenyl­tin(iv)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007978/
https://www.ncbi.nlm.nih.gov/pubmed/21588542
http://dx.doi.org/10.1107/S1600536810033039
work_keys_str_mv AT awangnormah nsecbutylnnpropyldithiocarbamatok2sstriphenyltiniv
AT babaibrahim nsecbutylnnpropyldithiocarbamatok2sstriphenyltiniv
AT yaminboharim nsecbutylnnpropyldithiocarbamatok2sstriphenyltiniv
AT ngseikweng nsecbutylnnpropyldithiocarbamatok2sstriphenyltiniv
AT tiekinkedwardrt nsecbutylnnpropyldithiocarbamatok2sstriphenyltiniv

Ejemplares similares