Ethyl (Z)-2-chloro-2-(2-phenyl­hydrazin-1-yl­idene)acetate

The title compound, C(10)H(11)ClN(2)O(2), features an almost planar C(ar)—N(H)—N=C(Cl) unit [torsion angle = 0.8 (1)° whose phenyl substituent is almost coplanar with it [dihedral angle = 2.8 (2)°]; this unit is slightly twisted with respect to the carboxyl –CO(2) fragment [dihedral angle = 10.3 (2)...

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Detalles Bibliográficos
Autores principales: Asiri, Abdullah M., Zayed, Mohie E. M., Ng, Seik Weng
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007979/
https://www.ncbi.nlm.nih.gov/pubmed/21588713
http://dx.doi.org/10.1107/S1600536810032587
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author Asiri, Abdullah M.
Zayed, Mohie E. M.
Ng, Seik Weng
author_facet Asiri, Abdullah M.
Zayed, Mohie E. M.
Ng, Seik Weng
author_sort Asiri, Abdullah M.
collection PubMed
description The title compound, C(10)H(11)ClN(2)O(2), features an almost planar C(ar)—N(H)—N=C(Cl) unit [torsion angle = 0.8 (1)° whose phenyl substituent is almost coplanar with it [dihedral angle = 2.8 (2)°]; this unit is slightly twisted with respect to the carboxyl –CO(2) fragment [dihedral angle = 10.3 (2)°]. In the crystal, the amino group acts as a hydrogen-bond donor to the carbonyl O atom of an adjacent mol­ecule; the hydrogen bond generates a helical chain that runs along the b axis of the monoclinic unit cell.
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spelling pubmed-30079792010-12-30 Ethyl (Z)-2-chloro-2-(2-phenyl­hydrazin-1-yl­idene)acetate Asiri, Abdullah M. Zayed, Mohie E. M. Ng, Seik Weng Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(10)H(11)ClN(2)O(2), features an almost planar C(ar)—N(H)—N=C(Cl) unit [torsion angle = 0.8 (1)° whose phenyl substituent is almost coplanar with it [dihedral angle = 2.8 (2)°]; this unit is slightly twisted with respect to the carboxyl –CO(2) fragment [dihedral angle = 10.3 (2)°]. In the crystal, the amino group acts as a hydrogen-bond donor to the carbonyl O atom of an adjacent mol­ecule; the hydrogen bond generates a helical chain that runs along the b axis of the monoclinic unit cell. International Union of Crystallography 2010-08-21 /pmc/articles/PMC3007979/ /pubmed/21588713 http://dx.doi.org/10.1107/S1600536810032587 Text en © Asiri et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Asiri, Abdullah M.
Zayed, Mohie E. M.
Ng, Seik Weng
Ethyl (Z)-2-chloro-2-(2-phenyl­hydrazin-1-yl­idene)acetate
title Ethyl (Z)-2-chloro-2-(2-phenyl­hydrazin-1-yl­idene)acetate
title_full Ethyl (Z)-2-chloro-2-(2-phenyl­hydrazin-1-yl­idene)acetate
title_fullStr Ethyl (Z)-2-chloro-2-(2-phenyl­hydrazin-1-yl­idene)acetate
title_full_unstemmed Ethyl (Z)-2-chloro-2-(2-phenyl­hydrazin-1-yl­idene)acetate
title_short Ethyl (Z)-2-chloro-2-(2-phenyl­hydrazin-1-yl­idene)acetate
title_sort ethyl (z)-2-chloro-2-(2-phenyl­hydrazin-1-yl­idene)acetate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007979/
https://www.ncbi.nlm.nih.gov/pubmed/21588713
http://dx.doi.org/10.1107/S1600536810032587
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AT zayedmohieem ethylz2chloro22phenylhydrazin1ylideneacetate
AT ngseikweng ethylz2chloro22phenylhydrazin1ylideneacetate

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