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Ethyl 2-[(Z)-2-benzylhydrazin-1-ylidene]-2-bromoacetate
In the title compound, C(11)H(13)BrN(2)O(2), the dihedral angle between the phenyl ring and the almost planar (r.m.s. deviation = 0.011 Å) C—C(Br)=N—N(H)— fragment is 74.94 (16)°. In the crystal, molecules are linked by N—H⋯O hydrogen bonds, which generate C(6) chains propagating in [010]. Weak aro...
Autores principales: | , , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2010
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007982/ https://www.ncbi.nlm.nih.gov/pubmed/21588679 http://dx.doi.org/10.1107/S1600536810032071 |
Sumario: | In the title compound, C(11)H(13)BrN(2)O(2), the dihedral angle between the phenyl ring and the almost planar (r.m.s. deviation = 0.011 Å) C—C(Br)=N—N(H)— fragment is 74.94 (16)°. In the crystal, molecules are linked by N—H⋯O hydrogen bonds, which generate C(6) chains propagating in [010]. Weak aromatic π–π stacking [centroid–centroid separation = 3.784 (3) Å] may also help to consolidate the packing. |
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