Ethyl 2-[(Z)-2-benzyl­hydrazin-1-yl­idene]-2-bromo­acetate

In the title compound, C(11)H(13)BrN(2)O(2), the dihedral angle between the phenyl ring and the almost planar (r.m.s. deviation = 0.011 Å) C—C(Br)=N—N(H)— fragment is 74.94 (16)°. In the crystal, mol­ecules are linked by N—H⋯O hydrogen bonds, which generate C(6) chains propagating in [010]. Weak aro...

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Detalles Bibliográficos
Autores principales: Yang, Qian-Jiao, Liu, Dan, Zuo, Jian, Hu, Guo-Dong, Zhao, Lin-Xiang
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007982/
https://www.ncbi.nlm.nih.gov/pubmed/21588679
http://dx.doi.org/10.1107/S1600536810032071
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author Yang, Qian-Jiao
Liu, Dan
Zuo, Jian
Hu, Guo-Dong
Zhao, Lin-Xiang
author_facet Yang, Qian-Jiao
Liu, Dan
Zuo, Jian
Hu, Guo-Dong
Zhao, Lin-Xiang
author_sort Yang, Qian-Jiao
collection PubMed
description In the title compound, C(11)H(13)BrN(2)O(2), the dihedral angle between the phenyl ring and the almost planar (r.m.s. deviation = 0.011 Å) C—C(Br)=N—N(H)— fragment is 74.94 (16)°. In the crystal, mol­ecules are linked by N—H⋯O hydrogen bonds, which generate C(6) chains propagating in [010]. Weak aromatic π–π stacking [centroid–centroid separation = 3.784 (3) Å] may also help to consolidate the packing.
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spelling pubmed-30079822010-12-30 Ethyl 2-[(Z)-2-benzyl­hydrazin-1-yl­idene]-2-bromo­acetate Yang, Qian-Jiao Liu, Dan Zuo, Jian Hu, Guo-Dong Zhao, Lin-Xiang Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(11)H(13)BrN(2)O(2), the dihedral angle between the phenyl ring and the almost planar (r.m.s. deviation = 0.011 Å) C—C(Br)=N—N(H)— fragment is 74.94 (16)°. In the crystal, mol­ecules are linked by N—H⋯O hydrogen bonds, which generate C(6) chains propagating in [010]. Weak aromatic π–π stacking [centroid–centroid separation = 3.784 (3) Å] may also help to consolidate the packing. International Union of Crystallography 2010-08-18 /pmc/articles/PMC3007982/ /pubmed/21588679 http://dx.doi.org/10.1107/S1600536810032071 Text en © Yang et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Yang, Qian-Jiao
Liu, Dan
Zuo, Jian
Hu, Guo-Dong
Zhao, Lin-Xiang
Ethyl 2-[(Z)-2-benzyl­hydrazin-1-yl­idene]-2-bromo­acetate
title Ethyl 2-[(Z)-2-benzyl­hydrazin-1-yl­idene]-2-bromo­acetate
title_full Ethyl 2-[(Z)-2-benzyl­hydrazin-1-yl­idene]-2-bromo­acetate
title_fullStr Ethyl 2-[(Z)-2-benzyl­hydrazin-1-yl­idene]-2-bromo­acetate
title_full_unstemmed Ethyl 2-[(Z)-2-benzyl­hydrazin-1-yl­idene]-2-bromo­acetate
title_short Ethyl 2-[(Z)-2-benzyl­hydrazin-1-yl­idene]-2-bromo­acetate
title_sort ethyl 2-[(z)-2-benzyl­hydrazin-1-yl­idene]-2-bromo­acetate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007982/
https://www.ncbi.nlm.nih.gov/pubmed/21588679
http://dx.doi.org/10.1107/S1600536810032071
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