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Methyl 2-(tert-but­oxy­carbonyl­amino)-1,3-thia­zole-5-carboxyl­ate

The title compound, C(10)H(14)N(2)O(4)S, was synthesized by the reaction of methyl 2-amino­thia­zole-5-carboxyl­ate and di-tert-butyl carbonate. In this structure, the thia­zole ring is planar (mean deviation = 0.0011 Å). Two weak intra­molecular C—H⋯O hydrogen bonds are formed between two of the me...

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Detalles Bibliográficos
Autores principales: An, Kang, Guan, Jiannin, Yu, Pen, Yang, Hao, Wan, Rong
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007983/
https://www.ncbi.nlm.nih.gov/pubmed/21588688
http://dx.doi.org/10.1107/S1600536810032277
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author An, Kang
Guan, Jiannin
Yu, Pen
Yang, Hao
Wan, Rong
author_facet An, Kang
Guan, Jiannin
Yu, Pen
Yang, Hao
Wan, Rong
author_sort An, Kang
collection PubMed
description The title compound, C(10)H(14)N(2)O(4)S, was synthesized by the reaction of methyl 2-amino­thia­zole-5-carboxyl­ate and di-tert-butyl carbonate. In this structure, the thia­zole ring is planar (mean deviation = 0.0011 Å). Two weak intra­molecular C—H⋯O hydrogen bonds are formed between two of the methyl groups and one carbonyl O atom, resulting in the formation of two twisted six-membered rings. Inter­molecular N—H⋯N hydrogen bonds link the mol­ecules to form centrosymmetric dimeric units, and the hydrogen-bond scheme is completed by inter­molecular C—H⋯O contacts.
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spelling pubmed-30079832010-12-30 Methyl 2-(tert-but­oxy­carbonyl­amino)-1,3-thia­zole-5-carboxyl­ate An, Kang Guan, Jiannin Yu, Pen Yang, Hao Wan, Rong Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(10)H(14)N(2)O(4)S, was synthesized by the reaction of methyl 2-amino­thia­zole-5-carboxyl­ate and di-tert-butyl carbonate. In this structure, the thia­zole ring is planar (mean deviation = 0.0011 Å). Two weak intra­molecular C—H⋯O hydrogen bonds are formed between two of the methyl groups and one carbonyl O atom, resulting in the formation of two twisted six-membered rings. Inter­molecular N—H⋯N hydrogen bonds link the mol­ecules to form centrosymmetric dimeric units, and the hydrogen-bond scheme is completed by inter­molecular C—H⋯O contacts. International Union of Crystallography 2010-08-18 /pmc/articles/PMC3007983/ /pubmed/21588688 http://dx.doi.org/10.1107/S1600536810032277 Text en © An et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
An, Kang
Guan, Jiannin
Yu, Pen
Yang, Hao
Wan, Rong
Methyl 2-(tert-but­oxy­carbonyl­amino)-1,3-thia­zole-5-carboxyl­ate
title Methyl 2-(tert-but­oxy­carbonyl­amino)-1,3-thia­zole-5-carboxyl­ate
title_full Methyl 2-(tert-but­oxy­carbonyl­amino)-1,3-thia­zole-5-carboxyl­ate
title_fullStr Methyl 2-(tert-but­oxy­carbonyl­amino)-1,3-thia­zole-5-carboxyl­ate
title_full_unstemmed Methyl 2-(tert-but­oxy­carbonyl­amino)-1,3-thia­zole-5-carboxyl­ate
title_short Methyl 2-(tert-but­oxy­carbonyl­amino)-1,3-thia­zole-5-carboxyl­ate
title_sort methyl 2-(tert-but­oxy­carbonyl­amino)-1,3-thia­zole-5-carboxyl­ate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007983/
https://www.ncbi.nlm.nih.gov/pubmed/21588688
http://dx.doi.org/10.1107/S1600536810032277
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