catena-Poly[(S)-2-methyl­piperazine-1,4-diium [[trichloridobismuthate(III)]-di-μ-chlorido]]

In the crystal structure of the title compound, {(C(5)H(14)N(2))[BiCl(5)]}(n), the Bi(III) cation is coordinated by six Cl(−) anions in a distorted octa­hedral geometry. Two Cl(−) anions bridge neighboring Bi(III) cations, forming a zigzag polymeric chain along the a axis. The discrete methylpiperaz...

Descripción completa

Detalles Bibliográficos
Autor principal: Ru, Zong-Ling
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007984/
https://www.ncbi.nlm.nih.gov/pubmed/21588498
http://dx.doi.org/10.1107/S1600536810031417
_version_ 1782194474415292416
author Ru, Zong-Ling
author_facet Ru, Zong-Ling
author_sort Ru, Zong-Ling
collection PubMed
description In the crystal structure of the title compound, {(C(5)H(14)N(2))[BiCl(5)]}(n), the Bi(III) cation is coordinated by six Cl(−) anions in a distorted octa­hedral geometry. Two Cl(−) anions bridge neighboring Bi(III) cations, forming a zigzag polymeric chain along the a axis. The discrete methylpiperazinediium cation adopts a normal chair conformation and is linked to the polymeric chains by N—H⋯Cl hydrogen bonding.
format Text
id pubmed-3007984
institution National Center for Biotechnology Information
language English
publishDate 2010
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-30079842010-12-30 catena-Poly[(S)-2-methyl­piperazine-1,4-diium [[trichloridobismuthate(III)]-di-μ-chlorido]] Ru, Zong-Ling Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the crystal structure of the title compound, {(C(5)H(14)N(2))[BiCl(5)]}(n), the Bi(III) cation is coordinated by six Cl(−) anions in a distorted octa­hedral geometry. Two Cl(−) anions bridge neighboring Bi(III) cations, forming a zigzag polymeric chain along the a axis. The discrete methylpiperazinediium cation adopts a normal chair conformation and is linked to the polymeric chains by N—H⋯Cl hydrogen bonding. International Union of Crystallography 2010-08-11 /pmc/articles/PMC3007984/ /pubmed/21588498 http://dx.doi.org/10.1107/S1600536810031417 Text en © Zong-Ling Ru 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Ru, Zong-Ling
catena-Poly[(S)-2-methyl­piperazine-1,4-diium [[trichloridobismuthate(III)]-di-μ-chlorido]]
title catena-Poly[(S)-2-methyl­piperazine-1,4-diium [[trichloridobismuthate(III)]-di-μ-chlorido]]
title_full catena-Poly[(S)-2-methyl­piperazine-1,4-diium [[trichloridobismuthate(III)]-di-μ-chlorido]]
title_fullStr catena-Poly[(S)-2-methyl­piperazine-1,4-diium [[trichloridobismuthate(III)]-di-μ-chlorido]]
title_full_unstemmed catena-Poly[(S)-2-methyl­piperazine-1,4-diium [[trichloridobismuthate(III)]-di-μ-chlorido]]
title_short catena-Poly[(S)-2-methyl­piperazine-1,4-diium [[trichloridobismuthate(III)]-di-μ-chlorido]]
title_sort catena-poly[(s)-2-methyl­piperazine-1,4-diium [[trichloridobismuthate(iii)]-di-μ-chlorido]]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007984/
https://www.ncbi.nlm.nih.gov/pubmed/21588498
http://dx.doi.org/10.1107/S1600536810031417
work_keys_str_mv AT ruzongling catenapolys2methylpiperazine14diiumtrichloridobismuthateiiidimchlorido

Ejemplares similares