(E)-1-(2,4,6-Trihy­droxy­benzyl­idene)-4-ethyl­thio­semicarbazide dihydrate

In the title mol­ecule, C(10)H(13)N(3)O(3)S·2H(2)O, the thio­semi­carbazide =N—NH—C(=S)—NH– fragment [torsion angle = 0.2 (1)°] is nearly coplanar with the benzene ring [dihedral angle = 2.4 (1)°]. The benzene ring and semicarbazide moiety are located on opposite sites of the C=N bond, showing an E...

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Detalles Bibliográficos
Autores principales: Shawish, Hana Bashir, Tan, Kong Wai, Maah, M. Jamil, Ng, Seik Weng
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007985/
https://www.ncbi.nlm.nih.gov/pubmed/21588600
http://dx.doi.org/10.1107/S1600536810030783
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author Shawish, Hana Bashir
Tan, Kong Wai
Maah, M. Jamil
Ng, Seik Weng
author_facet Shawish, Hana Bashir
Tan, Kong Wai
Maah, M. Jamil
Ng, Seik Weng
author_sort Shawish, Hana Bashir
collection PubMed
description In the title mol­ecule, C(10)H(13)N(3)O(3)S·2H(2)O, the thio­semi­carbazide =N—NH—C(=S)—NH– fragment [torsion angle = 0.2 (1)°] is nearly coplanar with the benzene ring [dihedral angle = 2.4 (1)°]. The benzene ring and semicarbazide moiety are located on opposite sites of the C=N bond, showing an E configuration. The hy­droxy, imino and water H atoms are engaged in extensive hydrogen bonding, forming a three-dimensional network.
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spelling pubmed-30079852010-12-30 (E)-1-(2,4,6-Trihy­droxy­benzyl­idene)-4-ethyl­thio­semicarbazide dihydrate Shawish, Hana Bashir Tan, Kong Wai Maah, M. Jamil Ng, Seik Weng Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title mol­ecule, C(10)H(13)N(3)O(3)S·2H(2)O, the thio­semi­carbazide =N—NH—C(=S)—NH– fragment [torsion angle = 0.2 (1)°] is nearly coplanar with the benzene ring [dihedral angle = 2.4 (1)°]. The benzene ring and semicarbazide moiety are located on opposite sites of the C=N bond, showing an E configuration. The hy­droxy, imino and water H atoms are engaged in extensive hydrogen bonding, forming a three-dimensional network. International Union of Crystallography 2010-08-11 /pmc/articles/PMC3007985/ /pubmed/21588600 http://dx.doi.org/10.1107/S1600536810030783 Text en © Shawish et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Shawish, Hana Bashir
Tan, Kong Wai
Maah, M. Jamil
Ng, Seik Weng
(E)-1-(2,4,6-Trihy­droxy­benzyl­idene)-4-ethyl­thio­semicarbazide dihydrate
title (E)-1-(2,4,6-Trihy­droxy­benzyl­idene)-4-ethyl­thio­semicarbazide dihydrate
title_full (E)-1-(2,4,6-Trihy­droxy­benzyl­idene)-4-ethyl­thio­semicarbazide dihydrate
title_fullStr (E)-1-(2,4,6-Trihy­droxy­benzyl­idene)-4-ethyl­thio­semicarbazide dihydrate
title_full_unstemmed (E)-1-(2,4,6-Trihy­droxy­benzyl­idene)-4-ethyl­thio­semicarbazide dihydrate
title_short (E)-1-(2,4,6-Trihy­droxy­benzyl­idene)-4-ethyl­thio­semicarbazide dihydrate
title_sort (e)-1-(2,4,6-trihy­droxy­benzyl­idene)-4-ethyl­thio­semicarbazide dihydrate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007985/
https://www.ncbi.nlm.nih.gov/pubmed/21588600
http://dx.doi.org/10.1107/S1600536810030783
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