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2-(4-Methoxyphenoxy)-3-nitropyridine
In the title molecule, C(12)H(10)N(2)O(4), the pyridine and benzene rings are almost orthogonal [dihedral angle = 86.69 (11)°], with the pyridine N atom directed towards the centre of the benzene ring. The –NO(2) [O—N—C—C = −26.1 (3)°] and –OMe [C—O—C—C = 166.5 (2)°] substituents are not coplanar w...
Autores principales: | , , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2010
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007986/ https://www.ncbi.nlm.nih.gov/pubmed/21588752 http://dx.doi.org/10.1107/S1600536810034057 |
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author | Nasir, Shah Bakhtiar Abdullah, Zanariah Fairuz, Zainal A. Ng, Seik Weng Tiekink, Edward R. T. |
author_facet | Nasir, Shah Bakhtiar Abdullah, Zanariah Fairuz, Zainal A. Ng, Seik Weng Tiekink, Edward R. T. |
author_sort | Nasir, Shah Bakhtiar |
collection | PubMed |
description | In the title molecule, C(12)H(10)N(2)O(4), the pyridine and benzene rings are almost orthogonal [dihedral angle = 86.69 (11)°], with the pyridine N atom directed towards the centre of the benzene ring. The –NO(2) [O—N—C—C = −26.1 (3)°] and –OMe [C—O—C—C = 166.5 (2)°] substituents are not coplanar with their respective aromatic rings. In the crystal, supramolecular layers in the ab plane are formed via C—H⋯π interactions involving methyl H atoms and the pyridine and benzene rings. Short N—O⋯π contacts (where the π-system is derived from the pyridine ring) occur between layers in the c-axis direction. |
format | Text |
id | pubmed-3007986 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2010 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-30079862010-12-30 2-(4-Methoxyphenoxy)-3-nitropyridine Nasir, Shah Bakhtiar Abdullah, Zanariah Fairuz, Zainal A. Ng, Seik Weng Tiekink, Edward R. T. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title molecule, C(12)H(10)N(2)O(4), the pyridine and benzene rings are almost orthogonal [dihedral angle = 86.69 (11)°], with the pyridine N atom directed towards the centre of the benzene ring. The –NO(2) [O—N—C—C = −26.1 (3)°] and –OMe [C—O—C—C = 166.5 (2)°] substituents are not coplanar with their respective aromatic rings. In the crystal, supramolecular layers in the ab plane are formed via C—H⋯π interactions involving methyl H atoms and the pyridine and benzene rings. Short N—O⋯π contacts (where the π-system is derived from the pyridine ring) occur between layers in the c-axis direction. International Union of Crystallography 2010-08-28 /pmc/articles/PMC3007986/ /pubmed/21588752 http://dx.doi.org/10.1107/S1600536810034057 Text en © Nasir et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Nasir, Shah Bakhtiar Abdullah, Zanariah Fairuz, Zainal A. Ng, Seik Weng Tiekink, Edward R. T. 2-(4-Methoxyphenoxy)-3-nitropyridine |
title | 2-(4-Methoxyphenoxy)-3-nitropyridine |
title_full | 2-(4-Methoxyphenoxy)-3-nitropyridine |
title_fullStr | 2-(4-Methoxyphenoxy)-3-nitropyridine |
title_full_unstemmed | 2-(4-Methoxyphenoxy)-3-nitropyridine |
title_short | 2-(4-Methoxyphenoxy)-3-nitropyridine |
title_sort | 2-(4-methoxyphenoxy)-3-nitropyridine |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007986/ https://www.ncbi.nlm.nih.gov/pubmed/21588752 http://dx.doi.org/10.1107/S1600536810034057 |
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