Cargando…

2-(4-Meth­oxy­phen­oxy)-3-nitro­pyridine

In the title mol­ecule, C(12)H(10)N(2)O(4), the pyridine and benzene rings are almost orthogonal [dihedral angle = 86.69 (11)°], with the pyridine N atom directed towards the centre of the benzene ring. The –NO(2) [O—N—C—C = −26.1 (3)°] and –OMe [C—O—C—C = 166.5 (2)°] substituents are not coplanar w...

Descripción completa

Detalles Bibliográficos
Autores principales: Nasir, Shah Bakhtiar, Abdullah, Zanariah, Fairuz, Zainal A., Ng, Seik Weng, Tiekink, Edward R. T.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007986/
https://www.ncbi.nlm.nih.gov/pubmed/21588752
http://dx.doi.org/10.1107/S1600536810034057
_version_ 1782194474891345920
author Nasir, Shah Bakhtiar
Abdullah, Zanariah
Fairuz, Zainal A.
Ng, Seik Weng
Tiekink, Edward R. T.
author_facet Nasir, Shah Bakhtiar
Abdullah, Zanariah
Fairuz, Zainal A.
Ng, Seik Weng
Tiekink, Edward R. T.
author_sort Nasir, Shah Bakhtiar
collection PubMed
description In the title mol­ecule, C(12)H(10)N(2)O(4), the pyridine and benzene rings are almost orthogonal [dihedral angle = 86.69 (11)°], with the pyridine N atom directed towards the centre of the benzene ring. The –NO(2) [O—N—C—C = −26.1 (3)°] and –OMe [C—O—C—C = 166.5 (2)°] substituents are not coplanar with their respective aromatic rings. In the crystal, supra­molecular layers in the ab plane are formed via C—H⋯π inter­actions involving methyl H atoms and the pyridine and benzene rings. Short N—O⋯π contacts (where the π-system is derived from the pyridine ring) occur between layers in the c-axis direction.
format Text
id pubmed-3007986
institution National Center for Biotechnology Information
language English
publishDate 2010
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-30079862010-12-30 2-(4-Meth­oxy­phen­oxy)-3-nitro­pyridine Nasir, Shah Bakhtiar Abdullah, Zanariah Fairuz, Zainal A. Ng, Seik Weng Tiekink, Edward R. T. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title mol­ecule, C(12)H(10)N(2)O(4), the pyridine and benzene rings are almost orthogonal [dihedral angle = 86.69 (11)°], with the pyridine N atom directed towards the centre of the benzene ring. The –NO(2) [O—N—C—C = −26.1 (3)°] and –OMe [C—O—C—C = 166.5 (2)°] substituents are not coplanar with their respective aromatic rings. In the crystal, supra­molecular layers in the ab plane are formed via C—H⋯π inter­actions involving methyl H atoms and the pyridine and benzene rings. Short N—O⋯π contacts (where the π-system is derived from the pyridine ring) occur between layers in the c-axis direction. International Union of Crystallography 2010-08-28 /pmc/articles/PMC3007986/ /pubmed/21588752 http://dx.doi.org/10.1107/S1600536810034057 Text en © Nasir et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Nasir, Shah Bakhtiar
Abdullah, Zanariah
Fairuz, Zainal A.
Ng, Seik Weng
Tiekink, Edward R. T.
2-(4-Meth­oxy­phen­oxy)-3-nitro­pyridine
title 2-(4-Meth­oxy­phen­oxy)-3-nitro­pyridine
title_full 2-(4-Meth­oxy­phen­oxy)-3-nitro­pyridine
title_fullStr 2-(4-Meth­oxy­phen­oxy)-3-nitro­pyridine
title_full_unstemmed 2-(4-Meth­oxy­phen­oxy)-3-nitro­pyridine
title_short 2-(4-Meth­oxy­phen­oxy)-3-nitro­pyridine
title_sort 2-(4-meth­oxy­phen­oxy)-3-nitro­pyridine
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007986/
https://www.ncbi.nlm.nih.gov/pubmed/21588752
http://dx.doi.org/10.1107/S1600536810034057
work_keys_str_mv AT nasirshahbakhtiar 24methoxyphenoxy3nitropyridine
AT abdullahzanariah 24methoxyphenoxy3nitropyridine
AT fairuzzainala 24methoxyphenoxy3nitropyridine
AT ngseikweng 24methoxyphenoxy3nitropyridine
AT tiekinkedwardrt 24methoxyphenoxy3nitropyridine