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(E)-1-(2,5-Dimethyl-3-thien­yl)-3-(2-hy­droxy­phen­yl)prop-2-en-1-one

In the title compound, C(15)H(14)O(2)S, the dihedral angle between the aromatic rings is 8.46 –(8)°. The central enone group is planar (r.m.s. deviation = 0.0267 Å) and is oriented at a dihedral angle of 1.20 (9)° with respect to the benzene ring and at 8.27 (9)° with respect to the thio­phene group...

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Detalles Bibliográficos
Autores principales: Asiri, Abdullah M., Khan, Salman A., Tahir, M. Nawaz
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007990/
https://www.ncbi.nlm.nih.gov/pubmed/21588620
http://dx.doi.org/10.1107/S1600536810031284
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author Asiri, Abdullah M.
Khan, Salman A.
Tahir, M. Nawaz
author_facet Asiri, Abdullah M.
Khan, Salman A.
Tahir, M. Nawaz
author_sort Asiri, Abdullah M.
collection PubMed
description In the title compound, C(15)H(14)O(2)S, the dihedral angle between the aromatic rings is 8.46 –(8)°. The central enone group is planar (r.m.s. deviation = 0.0267 Å) and is oriented at a dihedral angle of 1.20 (9)° with respect to the benzene ring and at 8.27 (9)° with respect to the thio­phene group. In the crystal, the mol­ecules are linked into polymeric chains extending along the b axis due to inter­molecular O—H⋯O hydrogen bonding. An S(6) ring motif is formed due to a short intra­molecular C—H⋯O contact. C—H⋯π inter­actions involving a methyl group of the 2,5-dimethyl­thienyl group and the benzene ring are present. π–π inter­actions between the centroids of the benzene and heterocyclic rings [3.7691 (9) Å] also occur.
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spelling pubmed-30079902010-12-30 (E)-1-(2,5-Dimethyl-3-thien­yl)-3-(2-hy­droxy­phen­yl)prop-2-en-1-one Asiri, Abdullah M. Khan, Salman A. Tahir, M. Nawaz Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(15)H(14)O(2)S, the dihedral angle between the aromatic rings is 8.46 –(8)°. The central enone group is planar (r.m.s. deviation = 0.0267 Å) and is oriented at a dihedral angle of 1.20 (9)° with respect to the benzene ring and at 8.27 (9)° with respect to the thio­phene group. In the crystal, the mol­ecules are linked into polymeric chains extending along the b axis due to inter­molecular O—H⋯O hydrogen bonding. An S(6) ring motif is formed due to a short intra­molecular C—H⋯O contact. C—H⋯π inter­actions involving a methyl group of the 2,5-dimethyl­thienyl group and the benzene ring are present. π–π inter­actions between the centroids of the benzene and heterocyclic rings [3.7691 (9) Å] also occur. International Union of Crystallography 2010-08-11 /pmc/articles/PMC3007990/ /pubmed/21588620 http://dx.doi.org/10.1107/S1600536810031284 Text en © Asiri et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Asiri, Abdullah M.
Khan, Salman A.
Tahir, M. Nawaz
(E)-1-(2,5-Dimethyl-3-thien­yl)-3-(2-hy­droxy­phen­yl)prop-2-en-1-one
title (E)-1-(2,5-Dimethyl-3-thien­yl)-3-(2-hy­droxy­phen­yl)prop-2-en-1-one
title_full (E)-1-(2,5-Dimethyl-3-thien­yl)-3-(2-hy­droxy­phen­yl)prop-2-en-1-one
title_fullStr (E)-1-(2,5-Dimethyl-3-thien­yl)-3-(2-hy­droxy­phen­yl)prop-2-en-1-one
title_full_unstemmed (E)-1-(2,5-Dimethyl-3-thien­yl)-3-(2-hy­droxy­phen­yl)prop-2-en-1-one
title_short (E)-1-(2,5-Dimethyl-3-thien­yl)-3-(2-hy­droxy­phen­yl)prop-2-en-1-one
title_sort (e)-1-(2,5-dimethyl-3-thien­yl)-3-(2-hy­droxy­phen­yl)prop-2-en-1-one
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007990/
https://www.ncbi.nlm.nih.gov/pubmed/21588620
http://dx.doi.org/10.1107/S1600536810031284
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