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(E)-1-(2,5-Dimethyl-3-thienyl)-3-(2-hydroxyphenyl)prop-2-en-1-one
In the title compound, C(15)H(14)O(2)S, the dihedral angle between the aromatic rings is 8.46 –(8)°. The central enone group is planar (r.m.s. deviation = 0.0267 Å) and is oriented at a dihedral angle of 1.20 (9)° with respect to the benzene ring and at 8.27 (9)° with respect to the thiophene group...
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2010
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007990/ https://www.ncbi.nlm.nih.gov/pubmed/21588620 http://dx.doi.org/10.1107/S1600536810031284 |
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author | Asiri, Abdullah M. Khan, Salman A. Tahir, M. Nawaz |
author_facet | Asiri, Abdullah M. Khan, Salman A. Tahir, M. Nawaz |
author_sort | Asiri, Abdullah M. |
collection | PubMed |
description | In the title compound, C(15)H(14)O(2)S, the dihedral angle between the aromatic rings is 8.46 –(8)°. The central enone group is planar (r.m.s. deviation = 0.0267 Å) and is oriented at a dihedral angle of 1.20 (9)° with respect to the benzene ring and at 8.27 (9)° with respect to the thiophene group. In the crystal, the molecules are linked into polymeric chains extending along the b axis due to intermolecular O—H⋯O hydrogen bonding. An S(6) ring motif is formed due to a short intramolecular C—H⋯O contact. C—H⋯π interactions involving a methyl group of the 2,5-dimethylthienyl group and the benzene ring are present. π–π interactions between the centroids of the benzene and heterocyclic rings [3.7691 (9) Å] also occur. |
format | Text |
id | pubmed-3007990 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2010 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-30079902010-12-30 (E)-1-(2,5-Dimethyl-3-thienyl)-3-(2-hydroxyphenyl)prop-2-en-1-one Asiri, Abdullah M. Khan, Salman A. Tahir, M. Nawaz Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(15)H(14)O(2)S, the dihedral angle between the aromatic rings is 8.46 –(8)°. The central enone group is planar (r.m.s. deviation = 0.0267 Å) and is oriented at a dihedral angle of 1.20 (9)° with respect to the benzene ring and at 8.27 (9)° with respect to the thiophene group. In the crystal, the molecules are linked into polymeric chains extending along the b axis due to intermolecular O—H⋯O hydrogen bonding. An S(6) ring motif is formed due to a short intramolecular C—H⋯O contact. C—H⋯π interactions involving a methyl group of the 2,5-dimethylthienyl group and the benzene ring are present. π–π interactions between the centroids of the benzene and heterocyclic rings [3.7691 (9) Å] also occur. International Union of Crystallography 2010-08-11 /pmc/articles/PMC3007990/ /pubmed/21588620 http://dx.doi.org/10.1107/S1600536810031284 Text en © Asiri et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Asiri, Abdullah M. Khan, Salman A. Tahir, M. Nawaz (E)-1-(2,5-Dimethyl-3-thienyl)-3-(2-hydroxyphenyl)prop-2-en-1-one |
title | (E)-1-(2,5-Dimethyl-3-thienyl)-3-(2-hydroxyphenyl)prop-2-en-1-one |
title_full | (E)-1-(2,5-Dimethyl-3-thienyl)-3-(2-hydroxyphenyl)prop-2-en-1-one |
title_fullStr | (E)-1-(2,5-Dimethyl-3-thienyl)-3-(2-hydroxyphenyl)prop-2-en-1-one |
title_full_unstemmed | (E)-1-(2,5-Dimethyl-3-thienyl)-3-(2-hydroxyphenyl)prop-2-en-1-one |
title_short | (E)-1-(2,5-Dimethyl-3-thienyl)-3-(2-hydroxyphenyl)prop-2-en-1-one |
title_sort | (e)-1-(2,5-dimethyl-3-thienyl)-3-(2-hydroxyphenyl)prop-2-en-1-one |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007990/ https://www.ncbi.nlm.nih.gov/pubmed/21588620 http://dx.doi.org/10.1107/S1600536810031284 |
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