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2,3-Diaminopyridinium (2E,4E)-hexa-2,4-dienoate
In the title salt, C(5)H(8)N(3) (+)·C(6)H(7)O(2) (−), the pyridine N atom of the 2,3-diaminopyridine molecule is protonated. The 2,3-diaminopyridinium cation is essentially planar, with a maximum deviation of 0.068 (2) Å for one of the amino N atoms. The sorbate anion adopts an extended conformat...
Autores principales: | , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2010
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007997/ https://www.ncbi.nlm.nih.gov/pubmed/21588709 http://dx.doi.org/10.1107/S1600536810032617 |
Sumario: | In the title salt, C(5)H(8)N(3) (+)·C(6)H(7)O(2) (−), the pyridine N atom of the 2,3-diaminopyridine molecule is protonated. The 2,3-diaminopyridinium cation is essentially planar, with a maximum deviation of 0.068 (2) Å for one of the amino N atoms. The sorbate anion adopts an extended conformation. In the crystal structure, the protonated N atom and one of the two amino-group H atoms are hydrogen bonded to the sorbate anion through a pair of N—H⋯O hydrogen bonds, forming an R (2) (2)(8) ring motif. The ion pairs are further connected via intermolecular N—H⋯O and C—H⋯O hydrogen bonds, forming two-dimensional networks parallel to (100). |
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