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2,3-Diaminopyridinium (2E,4E)-hexa-2,4-dienoate
In the title salt, C(5)H(8)N(3) (+)·C(6)H(7)O(2) (−), the pyridine N atom of the 2,3-diaminopyridine molecule is protonated. The 2,3-diaminopyridinium cation is essentially planar, with a maximum deviation of 0.068 (2) Å for one of the amino N atoms. The sorbate anion adopts an extended conformat...
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2010
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007997/ https://www.ncbi.nlm.nih.gov/pubmed/21588709 http://dx.doi.org/10.1107/S1600536810032617 |
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author | Hemamalini, Madhukar Fun, Hoong-Kun |
author_facet | Hemamalini, Madhukar Fun, Hoong-Kun |
author_sort | Hemamalini, Madhukar |
collection | PubMed |
description | In the title salt, C(5)H(8)N(3) (+)·C(6)H(7)O(2) (−), the pyridine N atom of the 2,3-diaminopyridine molecule is protonated. The 2,3-diaminopyridinium cation is essentially planar, with a maximum deviation of 0.068 (2) Å for one of the amino N atoms. The sorbate anion adopts an extended conformation. In the crystal structure, the protonated N atom and one of the two amino-group H atoms are hydrogen bonded to the sorbate anion through a pair of N—H⋯O hydrogen bonds, forming an R (2) (2)(8) ring motif. The ion pairs are further connected via intermolecular N—H⋯O and C—H⋯O hydrogen bonds, forming two-dimensional networks parallel to (100). |
format | Text |
id | pubmed-3007997 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2010 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-30079972010-12-30 2,3-Diaminopyridinium (2E,4E)-hexa-2,4-dienoate Hemamalini, Madhukar Fun, Hoong-Kun Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title salt, C(5)H(8)N(3) (+)·C(6)H(7)O(2) (−), the pyridine N atom of the 2,3-diaminopyridine molecule is protonated. The 2,3-diaminopyridinium cation is essentially planar, with a maximum deviation of 0.068 (2) Å for one of the amino N atoms. The sorbate anion adopts an extended conformation. In the crystal structure, the protonated N atom and one of the two amino-group H atoms are hydrogen bonded to the sorbate anion through a pair of N—H⋯O hydrogen bonds, forming an R (2) (2)(8) ring motif. The ion pairs are further connected via intermolecular N—H⋯O and C—H⋯O hydrogen bonds, forming two-dimensional networks parallel to (100). International Union of Crystallography 2010-08-21 /pmc/articles/PMC3007997/ /pubmed/21588709 http://dx.doi.org/10.1107/S1600536810032617 Text en © Hemamalini and Fun 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Hemamalini, Madhukar Fun, Hoong-Kun 2,3-Diaminopyridinium (2E,4E)-hexa-2,4-dienoate |
title | 2,3-Diaminopyridinium (2E,4E)-hexa-2,4-dienoate |
title_full | 2,3-Diaminopyridinium (2E,4E)-hexa-2,4-dienoate |
title_fullStr | 2,3-Diaminopyridinium (2E,4E)-hexa-2,4-dienoate |
title_full_unstemmed | 2,3-Diaminopyridinium (2E,4E)-hexa-2,4-dienoate |
title_short | 2,3-Diaminopyridinium (2E,4E)-hexa-2,4-dienoate |
title_sort | 2,3-diaminopyridinium (2e,4e)-hexa-2,4-dienoate |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007997/ https://www.ncbi.nlm.nih.gov/pubmed/21588709 http://dx.doi.org/10.1107/S1600536810032617 |
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