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2,3-Diamino­pyridinium (2E,4E)-hexa-2,4-dienoate

In the title salt, C(5)H(8)N(3) (+)·C(6)H(7)O(2) (−), the pyridine N atom of the 2,3-diamino­pyridine mol­ecule is protonated. The 2,3-diamino­pyridinium cation is essentially planar, with a maximum deviation of 0.068 (2) Å for one of the amino N atoms. The sorbate anion adopts an extended conformat...

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Detalles Bibliográficos
Autores principales: Hemamalini, Madhukar, Fun, Hoong-Kun
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007997/
https://www.ncbi.nlm.nih.gov/pubmed/21588709
http://dx.doi.org/10.1107/S1600536810032617
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author Hemamalini, Madhukar
Fun, Hoong-Kun
author_facet Hemamalini, Madhukar
Fun, Hoong-Kun
author_sort Hemamalini, Madhukar
collection PubMed
description In the title salt, C(5)H(8)N(3) (+)·C(6)H(7)O(2) (−), the pyridine N atom of the 2,3-diamino­pyridine mol­ecule is protonated. The 2,3-diamino­pyridinium cation is essentially planar, with a maximum deviation of 0.068 (2) Å for one of the amino N atoms. The sorbate anion adopts an extended conformation. In the crystal structure, the protonated N atom and one of the two amino-group H atoms are hydrogen bonded to the sorbate anion through a pair of N—H⋯O hydrogen bonds, forming an R (2) (2)(8) ring motif. The ion pairs are further connected via inter­molecular N—H⋯O and C—H⋯O hydrogen bonds, forming two-dimensional networks parallel to (100).
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spelling pubmed-30079972010-12-30 2,3-Diamino­pyridinium (2E,4E)-hexa-2,4-dienoate Hemamalini, Madhukar Fun, Hoong-Kun Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title salt, C(5)H(8)N(3) (+)·C(6)H(7)O(2) (−), the pyridine N atom of the 2,3-diamino­pyridine mol­ecule is protonated. The 2,3-diamino­pyridinium cation is essentially planar, with a maximum deviation of 0.068 (2) Å for one of the amino N atoms. The sorbate anion adopts an extended conformation. In the crystal structure, the protonated N atom and one of the two amino-group H atoms are hydrogen bonded to the sorbate anion through a pair of N—H⋯O hydrogen bonds, forming an R (2) (2)(8) ring motif. The ion pairs are further connected via inter­molecular N—H⋯O and C—H⋯O hydrogen bonds, forming two-dimensional networks parallel to (100). International Union of Crystallography 2010-08-21 /pmc/articles/PMC3007997/ /pubmed/21588709 http://dx.doi.org/10.1107/S1600536810032617 Text en © Hemamalini and Fun 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Hemamalini, Madhukar
Fun, Hoong-Kun
2,3-Diamino­pyridinium (2E,4E)-hexa-2,4-dienoate
title 2,3-Diamino­pyridinium (2E,4E)-hexa-2,4-dienoate
title_full 2,3-Diamino­pyridinium (2E,4E)-hexa-2,4-dienoate
title_fullStr 2,3-Diamino­pyridinium (2E,4E)-hexa-2,4-dienoate
title_full_unstemmed 2,3-Diamino­pyridinium (2E,4E)-hexa-2,4-dienoate
title_short 2,3-Diamino­pyridinium (2E,4E)-hexa-2,4-dienoate
title_sort 2,3-diamino­pyridinium (2e,4e)-hexa-2,4-dienoate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007997/
https://www.ncbi.nlm.nih.gov/pubmed/21588709
http://dx.doi.org/10.1107/S1600536810032617
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