Arborinol methyl ether from Areca catechu L.

The title compound isolated from Areca catechu L. (common name: arborinol methyl ether; a member of the arborane family) was established as 3α-methoxyarbor-9(11)-ene, C(31)H(52)O. Rings A/B/C/D assume a chair conformation, while ring E has an envelope conformation. The absolute configuration was det...

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Detalles Bibliográficos
Autores principales: He, Xixin, Li, Yajun, Zhang, Cuixian, Hu, Xiaopeng
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007998/
https://www.ncbi.nlm.nih.gov/pubmed/21588629
http://dx.doi.org/10.1107/S1600536810030758
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author He, Xixin
Li, Yajun
Zhang, Cuixian
Hu, Xiaopeng
author_facet He, Xixin
Li, Yajun
Zhang, Cuixian
Hu, Xiaopeng
author_sort He, Xixin
collection PubMed
description The title compound isolated from Areca catechu L. (common name: arborinol methyl ether; a member of the arborane family) was established as 3α-methoxyarbor-9(11)-ene, C(31)H(52)O. Rings A/B/C/D assume a chair conformation, while ring E has an envelope conformation. The absolute configuration was determined to be (3R,5R,8S,10S,13R,14S,17S,18S, 21S) by analysis of Bijvoet pairs based on resonant scattering of light atoms, yielding a Hooft parameter y of −0.03 (3).
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spelling pubmed-30079982010-12-30 Arborinol methyl ether from Areca catechu L. He, Xixin Li, Yajun Zhang, Cuixian Hu, Xiaopeng Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound isolated from Areca catechu L. (common name: arborinol methyl ether; a member of the arborane family) was established as 3α-methoxyarbor-9(11)-ene, C(31)H(52)O. Rings A/B/C/D assume a chair conformation, while ring E has an envelope conformation. The absolute configuration was determined to be (3R,5R,8S,10S,13R,14S,17S,18S, 21S) by analysis of Bijvoet pairs based on resonant scattering of light atoms, yielding a Hooft parameter y of −0.03 (3). International Union of Crystallography 2010-08-11 /pmc/articles/PMC3007998/ /pubmed/21588629 http://dx.doi.org/10.1107/S1600536810030758 Text en © He et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
He, Xixin
Li, Yajun
Zhang, Cuixian
Hu, Xiaopeng
Arborinol methyl ether from Areca catechu L.
title Arborinol methyl ether from Areca catechu L.
title_full Arborinol methyl ether from Areca catechu L.
title_fullStr Arborinol methyl ether from Areca catechu L.
title_full_unstemmed Arborinol methyl ether from Areca catechu L.
title_short Arborinol methyl ether from Areca catechu L.
title_sort arborinol methyl ether from areca catechu l.
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007998/
https://www.ncbi.nlm.nih.gov/pubmed/21588629
http://dx.doi.org/10.1107/S1600536810030758
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AT liyajun arborinolmethyletherfromarecacatechul
AT zhangcuixian arborinolmethyletherfromarecacatechul
AT huxiaopeng arborinolmethyletherfromarecacatechul

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