(Methanol-κO)(2-methyl-3-nitro­benzoato-κO)triphenyl­tin(IV)

The five-coordinate Sn atom in the title compound, [Sn(C(6)H(5))(3)(C(8)H(6)NO(4))(CH(3)OH)], exists in a trans-C(3)SnO(2) trigonal-bipyramidal coordination polyhedron of which the O atoms of the methanol mol­ecule and carboxyl­ate group occupy the apical sites. In the crystal, adjacent mol­ecules a...

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Detalles Bibliográficos
Autores principales: Yip, Foo Win, Teoh, Siang Guan, Yamin, Bohari M., Ng, Seik Weng
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007999/
https://www.ncbi.nlm.nih.gov/pubmed/21588556
http://dx.doi.org/10.1107/S1600536810033623
Descripción
Sumario:The five-coordinate Sn atom in the title compound, [Sn(C(6)H(5))(3)(C(8)H(6)NO(4))(CH(3)OH)], exists in a trans-C(3)SnO(2) trigonal-bipyramidal coordination polyhedron of which the O atoms of the methanol mol­ecule and carboxyl­ate group occupy the apical sites. In the crystal, adjacent mol­ecules are linked by inter­molecular O—H⋯O inter­actions, generating a helical hydrogen-bonded chain running along the b axis.

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