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(Methanol-κO)(2-methyl-3-nitro­benzoato-κO)triphenyl­tin(IV)

The five-coordinate Sn atom in the title compound, [Sn(C(6)H(5))(3)(C(8)H(6)NO(4))(CH(3)OH)], exists in a trans-C(3)SnO(2) trigonal-bipyramidal coordination polyhedron of which the O atoms of the methanol mol­ecule and carboxyl­ate group occupy the apical sites. In the crystal, adjacent mol­ecules a...

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Detalles Bibliográficos
Autores principales: Yip, Foo Win, Teoh, Siang Guan, Yamin, Bohari M., Ng, Seik Weng
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007999/
https://www.ncbi.nlm.nih.gov/pubmed/21588556
http://dx.doi.org/10.1107/S1600536810033623
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author Yip, Foo Win
Teoh, Siang Guan
Yamin, Bohari M.
Ng, Seik Weng
author_facet Yip, Foo Win
Teoh, Siang Guan
Yamin, Bohari M.
Ng, Seik Weng
author_sort Yip, Foo Win
collection PubMed
description The five-coordinate Sn atom in the title compound, [Sn(C(6)H(5))(3)(C(8)H(6)NO(4))(CH(3)OH)], exists in a trans-C(3)SnO(2) trigonal-bipyramidal coordination polyhedron of which the O atoms of the methanol mol­ecule and carboxyl­ate group occupy the apical sites. In the crystal, adjacent mol­ecules are linked by inter­molecular O—H⋯O inter­actions, generating a helical hydrogen-bonded chain running along the b axis.
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spelling pubmed-30079992010-12-30 (Methanol-κO)(2-methyl-3-nitro­benzoato-κO)triphenyl­tin(IV) Yip, Foo Win Teoh, Siang Guan Yamin, Bohari M. Ng, Seik Weng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The five-coordinate Sn atom in the title compound, [Sn(C(6)H(5))(3)(C(8)H(6)NO(4))(CH(3)OH)], exists in a trans-C(3)SnO(2) trigonal-bipyramidal coordination polyhedron of which the O atoms of the methanol mol­ecule and carboxyl­ate group occupy the apical sites. In the crystal, adjacent mol­ecules are linked by inter­molecular O—H⋯O inter­actions, generating a helical hydrogen-bonded chain running along the b axis. International Union of Crystallography 2010-08-28 /pmc/articles/PMC3007999/ /pubmed/21588556 http://dx.doi.org/10.1107/S1600536810033623 Text en © Yip et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Yip, Foo Win
Teoh, Siang Guan
Yamin, Bohari M.
Ng, Seik Weng
(Methanol-κO)(2-methyl-3-nitro­benzoato-κO)triphenyl­tin(IV)
title (Methanol-κO)(2-methyl-3-nitro­benzoato-κO)triphenyl­tin(IV)
title_full (Methanol-κO)(2-methyl-3-nitro­benzoato-κO)triphenyl­tin(IV)
title_fullStr (Methanol-κO)(2-methyl-3-nitro­benzoato-κO)triphenyl­tin(IV)
title_full_unstemmed (Methanol-κO)(2-methyl-3-nitro­benzoato-κO)triphenyl­tin(IV)
title_short (Methanol-κO)(2-methyl-3-nitro­benzoato-κO)triphenyl­tin(IV)
title_sort (methanol-κo)(2-methyl-3-nitro­benzoato-κo)triphenyl­tin(iv)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3007999/
https://www.ncbi.nlm.nih.gov/pubmed/21588556
http://dx.doi.org/10.1107/S1600536810033623
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