K(3)Gd(PO(4))(2)

The title compound, tripotassium gadolinium(III) bis­[ortho­phosphate(V)], was synthesized by a high-temperature solution reaction. Of the 12 atoms of the asymmetric unit (1 × Gd, 2 × P, 3 × K, 6 × O), all but two O atoms (which are in general positions) lie on mirror planes. The crystal structure f...

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Detalles Bibliográficos
Autores principales: Zhao, Dan, Li, Fei Fei
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Inorganic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3008008/
https://www.ncbi.nlm.nih.gov/pubmed/21588471
http://dx.doi.org/10.1107/S160053681003103X
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author Zhao, Dan
Li, Fei Fei
author_facet Zhao, Dan
Li, Fei Fei
author_sort Zhao, Dan
collection PubMed
description The title compound, tripotassium gadolinium(III) bis­[ortho­phosphate(V)], was synthesized by a high-temperature solution reaction. Of the 12 atoms of the asymmetric unit (1 × Gd, 2 × P, 3 × K, 6 × O), all but two O atoms (which are in general positions) lie on mirror planes. The crystal structure features sheets of composition [Gd(PO(4))(2)](3−) which extend parallel to (100) and are built up from isolated PO(4) tetra­hedra and GdO(7) monocapped prisms through corner- and edge-sharing. The K(+) ions, which have coordination numbers of 10, 9 and 11, help to stack the anionic sheets along [100] into a three-dimensional structure.
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spelling pubmed-30080082010-12-30 K(3)Gd(PO(4))(2) Zhao, Dan Li, Fei Fei Acta Crystallogr Sect E Struct Rep Online Inorganic Papers The title compound, tripotassium gadolinium(III) bis­[ortho­phosphate(V)], was synthesized by a high-temperature solution reaction. Of the 12 atoms of the asymmetric unit (1 × Gd, 2 × P, 3 × K, 6 × O), all but two O atoms (which are in general positions) lie on mirror planes. The crystal structure features sheets of composition [Gd(PO(4))(2)](3−) which extend parallel to (100) and are built up from isolated PO(4) tetra­hedra and GdO(7) monocapped prisms through corner- and edge-sharing. The K(+) ions, which have coordination numbers of 10, 9 and 11, help to stack the anionic sheets along [100] into a three-dimensional structure. International Union of Crystallography 2010-08-11 /pmc/articles/PMC3008008/ /pubmed/21588471 http://dx.doi.org/10.1107/S160053681003103X Text en © Zhao and Li 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Inorganic Papers
Zhao, Dan
Li, Fei Fei
K(3)Gd(PO(4))(2)
title K(3)Gd(PO(4))(2)
title_full K(3)Gd(PO(4))(2)
title_fullStr K(3)Gd(PO(4))(2)
title_full_unstemmed K(3)Gd(PO(4))(2)
title_short K(3)Gd(PO(4))(2)
title_sort k(3)gd(po(4))(2)
topic Inorganic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3008008/
https://www.ncbi.nlm.nih.gov/pubmed/21588471
http://dx.doi.org/10.1107/S160053681003103X
work_keys_str_mv AT zhaodan k3gdpo42
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