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5,5′-Bis(diethylamino)-2,2′-[2,2-dimethylpropane-1,3-diylbis(nitrilomethylidyne)]diphenol
The asymmetric unit of the title compound, C(27)H(40)N(4)O(2), comprises one molecule of a potentially tetradentate Schiff base ligand. The dihedral angle between the two phenyl rings is 67.13 (10)°. Strong intramolecular O—H⋯N hydrogen bonds generate S(6) ring motifs. One terminal methyl among t...
Autores principales: | , , , |
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2010
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3008013/ https://www.ncbi.nlm.nih.gov/pubmed/21588648 http://dx.doi.org/10.1107/S1600536810031430 |
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author | Kia, Reza Kargar, Hadi Tahir, Muhammad Nawaz Kianoosh, Fatemeh |
author_facet | Kia, Reza Kargar, Hadi Tahir, Muhammad Nawaz Kianoosh, Fatemeh |
author_sort | Kia, Reza |
collection | PubMed |
description | The asymmetric unit of the title compound, C(27)H(40)N(4)O(2), comprises one molecule of a potentially tetradentate Schiff base ligand. The dihedral angle between the two phenyl rings is 67.13 (10)°. Strong intramolecular O—H⋯N hydrogen bonds generate S(6) ring motifs. One terminal methyl among the four diethylamino groups is disordered over two positions with the refined site occupancy ratio of 0.660 (7)/0.340 (7). |
format | Text |
id | pubmed-3008013 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2010 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-30080132010-12-30 5,5′-Bis(diethylamino)-2,2′-[2,2-dimethylpropane-1,3-diylbis(nitrilomethylidyne)]diphenol Kia, Reza Kargar, Hadi Tahir, Muhammad Nawaz Kianoosh, Fatemeh Acta Crystallogr Sect E Struct Rep Online Organic Papers The asymmetric unit of the title compound, C(27)H(40)N(4)O(2), comprises one molecule of a potentially tetradentate Schiff base ligand. The dihedral angle between the two phenyl rings is 67.13 (10)°. Strong intramolecular O—H⋯N hydrogen bonds generate S(6) ring motifs. One terminal methyl among the four diethylamino groups is disordered over two positions with the refined site occupancy ratio of 0.660 (7)/0.340 (7). International Union of Crystallography 2010-08-11 /pmc/articles/PMC3008013/ /pubmed/21588648 http://dx.doi.org/10.1107/S1600536810031430 Text en © Kia et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Kia, Reza Kargar, Hadi Tahir, Muhammad Nawaz Kianoosh, Fatemeh 5,5′-Bis(diethylamino)-2,2′-[2,2-dimethylpropane-1,3-diylbis(nitrilomethylidyne)]diphenol |
title | 5,5′-Bis(diethylamino)-2,2′-[2,2-dimethylpropane-1,3-diylbis(nitrilomethylidyne)]diphenol |
title_full | 5,5′-Bis(diethylamino)-2,2′-[2,2-dimethylpropane-1,3-diylbis(nitrilomethylidyne)]diphenol |
title_fullStr | 5,5′-Bis(diethylamino)-2,2′-[2,2-dimethylpropane-1,3-diylbis(nitrilomethylidyne)]diphenol |
title_full_unstemmed | 5,5′-Bis(diethylamino)-2,2′-[2,2-dimethylpropane-1,3-diylbis(nitrilomethylidyne)]diphenol |
title_short | 5,5′-Bis(diethylamino)-2,2′-[2,2-dimethylpropane-1,3-diylbis(nitrilomethylidyne)]diphenol |
title_sort | 5,5′-bis(diethylamino)-2,2′-[2,2-dimethylpropane-1,3-diylbis(nitrilomethylidyne)]diphenol |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3008013/ https://www.ncbi.nlm.nih.gov/pubmed/21588648 http://dx.doi.org/10.1107/S1600536810031430 |
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