4-Amino-N-(4,6-dimethyl­pyrimidin-2-yl)benzene­sulfonamide–benzoic acid (1/1)

The constituents of the title co-crystal, C(12)H(14)N(4)O(2)S·C(7)H(6)O(2), are connected by an eight-membered hetero-synthon {⋯NCNH⋯OCOH}, whereby the carb­oxy­lic acid forms donor and acceptor hydrogen bonds with a pyrimidine N atom and the adjacent amine, respectively. The dimeric aggregates thus...

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Detalles Bibliográficos
Autores principales: Arman, Hadi D., Kaulgud, Trupta, Tiekink, Edward R. T.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3008015/
https://www.ncbi.nlm.nih.gov/pubmed/21588754
http://dx.doi.org/10.1107/S1600536810034094
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author Arman, Hadi D.
Kaulgud, Trupta
Tiekink, Edward R. T.
author_facet Arman, Hadi D.
Kaulgud, Trupta
Tiekink, Edward R. T.
author_sort Arman, Hadi D.
collection PubMed
description The constituents of the title co-crystal, C(12)H(14)N(4)O(2)S·C(7)H(6)O(2), are connected by an eight-membered hetero-synthon {⋯NCNH⋯OCOH}, whereby the carb­oxy­lic acid forms donor and acceptor hydrogen bonds with a pyrimidine N atom and the adjacent amine, respectively. The dimeric aggregates thus formed are arranged in rows with their terminal NH(2) groups forming N—H⋯O hydrogen bonds with neighbouring aggregates to form a two-dimensional array in the ac plane with an overall T-shaped topology. Layers inter­digitate along the b axis being connected by C—H⋯O, C—H⋯π and π–π [centroid–centroid distance = 3.6316 (19) Å] inter­actions.
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spelling pubmed-30080152010-12-30 4-Amino-N-(4,6-dimethyl­pyrimidin-2-yl)benzene­sulfonamide–benzoic acid (1/1) Arman, Hadi D. Kaulgud, Trupta Tiekink, Edward R. T. Acta Crystallogr Sect E Struct Rep Online Organic Papers The constituents of the title co-crystal, C(12)H(14)N(4)O(2)S·C(7)H(6)O(2), are connected by an eight-membered hetero-synthon {⋯NCNH⋯OCOH}, whereby the carb­oxy­lic acid forms donor and acceptor hydrogen bonds with a pyrimidine N atom and the adjacent amine, respectively. The dimeric aggregates thus formed are arranged in rows with their terminal NH(2) groups forming N—H⋯O hydrogen bonds with neighbouring aggregates to form a two-dimensional array in the ac plane with an overall T-shaped topology. Layers inter­digitate along the b axis being connected by C—H⋯O, C—H⋯π and π–π [centroid–centroid distance = 3.6316 (19) Å] inter­actions. International Union of Crystallography 2010-08-28 /pmc/articles/PMC3008015/ /pubmed/21588754 http://dx.doi.org/10.1107/S1600536810034094 Text en © Arman et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Arman, Hadi D.
Kaulgud, Trupta
Tiekink, Edward R. T.
4-Amino-N-(4,6-dimethyl­pyrimidin-2-yl)benzene­sulfonamide–benzoic acid (1/1)
title 4-Amino-N-(4,6-dimethyl­pyrimidin-2-yl)benzene­sulfonamide–benzoic acid (1/1)
title_full 4-Amino-N-(4,6-dimethyl­pyrimidin-2-yl)benzene­sulfonamide–benzoic acid (1/1)
title_fullStr 4-Amino-N-(4,6-dimethyl­pyrimidin-2-yl)benzene­sulfonamide–benzoic acid (1/1)
title_full_unstemmed 4-Amino-N-(4,6-dimethyl­pyrimidin-2-yl)benzene­sulfonamide–benzoic acid (1/1)
title_short 4-Amino-N-(4,6-dimethyl­pyrimidin-2-yl)benzene­sulfonamide–benzoic acid (1/1)
title_sort 4-amino-n-(4,6-dimethyl­pyrimidin-2-yl)benzene­sulfonamide–benzoic acid (1/1)
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3008015/
https://www.ncbi.nlm.nih.gov/pubmed/21588754
http://dx.doi.org/10.1107/S1600536810034094
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AT kaulgudtrupta 4aminon46dimethylpyrimidin2ylbenzenesulfonamidebenzoicacid11
AT tiekinkedwardrt 4aminon46dimethylpyrimidin2ylbenzenesulfonamidebenzoicacid11

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