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4-[4-Eth­oxy­carbonyl-5-(3,4-methyl­ene­dioxy­phen­yl)-3-oxocyclo­hex-1-en-1-yl]-3-phenyl­sydnone

In the title compound {systematic name: 4-[4-eth­oxy­carbonyl-5-(3,4-methyl­ene­dioxy­phen­yl)-3-oxocyclo­hex-1-en-1-yl]-3-phenyl-1,2,3-oxadiazol-3-ium-5-olate}, C(24)H(20)N(2)O(7), the cyclo­hexene and dioxole rings adopt envelope conformations. The sydnone ring and the attached phenyl ring form a...

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Autores principales: Fun, Hoong-Kun, Loh, Wan-Sin, Nithinchandra, Kalluraya, Balakrishna, Nayak, Suresh P.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3008016/
https://www.ncbi.nlm.nih.gov/pubmed/21588708
http://dx.doi.org/10.1107/S1600536810033106
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author Fun, Hoong-Kun
Loh, Wan-Sin
Nithinchandra,
Kalluraya, Balakrishna
Nayak, Suresh P.
author_facet Fun, Hoong-Kun
Loh, Wan-Sin
Nithinchandra,
Kalluraya, Balakrishna
Nayak, Suresh P.
author_sort Fun, Hoong-Kun
collection PubMed
description In the title compound {systematic name: 4-[4-eth­oxy­carbonyl-5-(3,4-methyl­ene­dioxy­phen­yl)-3-oxocyclo­hex-1-en-1-yl]-3-phenyl-1,2,3-oxadiazol-3-ium-5-olate}, C(24)H(20)N(2)O(7), the cyclo­hexene and dioxole rings adopt envelope conformations. The sydnone ring and the attached phenyl ring form a dihedral angle of 79.0 (1)°. In the mol­ecular structure, a C—H⋯O hydrogen bond generates an S(6) ring and a C—H⋯π inter­action involving the phenyl ring is observed. In the crystal structure, mol­ecules are linked into a ribbon-like structure along the a axis by C—H⋯O hydrogen bonds.
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spelling pubmed-30080162010-12-30 4-[4-Eth­oxy­carbonyl-5-(3,4-methyl­ene­dioxy­phen­yl)-3-oxocyclo­hex-1-en-1-yl]-3-phenyl­sydnone Fun, Hoong-Kun Loh, Wan-Sin Nithinchandra, Kalluraya, Balakrishna Nayak, Suresh P. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound {systematic name: 4-[4-eth­oxy­carbonyl-5-(3,4-methyl­ene­dioxy­phen­yl)-3-oxocyclo­hex-1-en-1-yl]-3-phenyl-1,2,3-oxadiazol-3-ium-5-olate}, C(24)H(20)N(2)O(7), the cyclo­hexene and dioxole rings adopt envelope conformations. The sydnone ring and the attached phenyl ring form a dihedral angle of 79.0 (1)°. In the mol­ecular structure, a C—H⋯O hydrogen bond generates an S(6) ring and a C—H⋯π inter­action involving the phenyl ring is observed. In the crystal structure, mol­ecules are linked into a ribbon-like structure along the a axis by C—H⋯O hydrogen bonds. International Union of Crystallography 2010-08-21 /pmc/articles/PMC3008016/ /pubmed/21588708 http://dx.doi.org/10.1107/S1600536810033106 Text en © Fun et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Fun, Hoong-Kun
Loh, Wan-Sin
Nithinchandra,
Kalluraya, Balakrishna
Nayak, Suresh P.
4-[4-Eth­oxy­carbonyl-5-(3,4-methyl­ene­dioxy­phen­yl)-3-oxocyclo­hex-1-en-1-yl]-3-phenyl­sydnone
title 4-[4-Eth­oxy­carbonyl-5-(3,4-methyl­ene­dioxy­phen­yl)-3-oxocyclo­hex-1-en-1-yl]-3-phenyl­sydnone
title_full 4-[4-Eth­oxy­carbonyl-5-(3,4-methyl­ene­dioxy­phen­yl)-3-oxocyclo­hex-1-en-1-yl]-3-phenyl­sydnone
title_fullStr 4-[4-Eth­oxy­carbonyl-5-(3,4-methyl­ene­dioxy­phen­yl)-3-oxocyclo­hex-1-en-1-yl]-3-phenyl­sydnone
title_full_unstemmed 4-[4-Eth­oxy­carbonyl-5-(3,4-methyl­ene­dioxy­phen­yl)-3-oxocyclo­hex-1-en-1-yl]-3-phenyl­sydnone
title_short 4-[4-Eth­oxy­carbonyl-5-(3,4-methyl­ene­dioxy­phen­yl)-3-oxocyclo­hex-1-en-1-yl]-3-phenyl­sydnone
title_sort 4-[4-eth­oxy­carbonyl-5-(3,4-methyl­ene­dioxy­phen­yl)-3-oxocyclo­hex-1-en-1-yl]-3-phenyl­sydnone
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3008016/
https://www.ncbi.nlm.nih.gov/pubmed/21588708
http://dx.doi.org/10.1107/S1600536810033106
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