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4-[4-Ethoxycarbonyl-5-(3,4-methylenedioxyphenyl)-3-oxocyclohex-1-en-1-yl]-3-phenylsydnone
In the title compound {systematic name: 4-[4-ethoxycarbonyl-5-(3,4-methylenedioxyphenyl)-3-oxocyclohex-1-en-1-yl]-3-phenyl-1,2,3-oxadiazol-3-ium-5-olate}, C(24)H(20)N(2)O(7), the cyclohexene and dioxole rings adopt envelope conformations. The sydnone ring and the attached phenyl ring form a...
Autores principales: | , , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2010
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3008016/ https://www.ncbi.nlm.nih.gov/pubmed/21588708 http://dx.doi.org/10.1107/S1600536810033106 |
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author | Fun, Hoong-Kun Loh, Wan-Sin Nithinchandra, Kalluraya, Balakrishna Nayak, Suresh P. |
author_facet | Fun, Hoong-Kun Loh, Wan-Sin Nithinchandra, Kalluraya, Balakrishna Nayak, Suresh P. |
author_sort | Fun, Hoong-Kun |
collection | PubMed |
description | In the title compound {systematic name: 4-[4-ethoxycarbonyl-5-(3,4-methylenedioxyphenyl)-3-oxocyclohex-1-en-1-yl]-3-phenyl-1,2,3-oxadiazol-3-ium-5-olate}, C(24)H(20)N(2)O(7), the cyclohexene and dioxole rings adopt envelope conformations. The sydnone ring and the attached phenyl ring form a dihedral angle of 79.0 (1)°. In the molecular structure, a C—H⋯O hydrogen bond generates an S(6) ring and a C—H⋯π interaction involving the phenyl ring is observed. In the crystal structure, molecules are linked into a ribbon-like structure along the a axis by C—H⋯O hydrogen bonds. |
format | Text |
id | pubmed-3008016 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2010 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-30080162010-12-30 4-[4-Ethoxycarbonyl-5-(3,4-methylenedioxyphenyl)-3-oxocyclohex-1-en-1-yl]-3-phenylsydnone Fun, Hoong-Kun Loh, Wan-Sin Nithinchandra, Kalluraya, Balakrishna Nayak, Suresh P. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound {systematic name: 4-[4-ethoxycarbonyl-5-(3,4-methylenedioxyphenyl)-3-oxocyclohex-1-en-1-yl]-3-phenyl-1,2,3-oxadiazol-3-ium-5-olate}, C(24)H(20)N(2)O(7), the cyclohexene and dioxole rings adopt envelope conformations. The sydnone ring and the attached phenyl ring form a dihedral angle of 79.0 (1)°. In the molecular structure, a C—H⋯O hydrogen bond generates an S(6) ring and a C—H⋯π interaction involving the phenyl ring is observed. In the crystal structure, molecules are linked into a ribbon-like structure along the a axis by C—H⋯O hydrogen bonds. International Union of Crystallography 2010-08-21 /pmc/articles/PMC3008016/ /pubmed/21588708 http://dx.doi.org/10.1107/S1600536810033106 Text en © Fun et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Fun, Hoong-Kun Loh, Wan-Sin Nithinchandra, Kalluraya, Balakrishna Nayak, Suresh P. 4-[4-Ethoxycarbonyl-5-(3,4-methylenedioxyphenyl)-3-oxocyclohex-1-en-1-yl]-3-phenylsydnone |
title | 4-[4-Ethoxycarbonyl-5-(3,4-methylenedioxyphenyl)-3-oxocyclohex-1-en-1-yl]-3-phenylsydnone |
title_full | 4-[4-Ethoxycarbonyl-5-(3,4-methylenedioxyphenyl)-3-oxocyclohex-1-en-1-yl]-3-phenylsydnone |
title_fullStr | 4-[4-Ethoxycarbonyl-5-(3,4-methylenedioxyphenyl)-3-oxocyclohex-1-en-1-yl]-3-phenylsydnone |
title_full_unstemmed | 4-[4-Ethoxycarbonyl-5-(3,4-methylenedioxyphenyl)-3-oxocyclohex-1-en-1-yl]-3-phenylsydnone |
title_short | 4-[4-Ethoxycarbonyl-5-(3,4-methylenedioxyphenyl)-3-oxocyclohex-1-en-1-yl]-3-phenylsydnone |
title_sort | 4-[4-ethoxycarbonyl-5-(3,4-methylenedioxyphenyl)-3-oxocyclohex-1-en-1-yl]-3-phenylsydnone |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3008016/ https://www.ncbi.nlm.nih.gov/pubmed/21588708 http://dx.doi.org/10.1107/S1600536810033106 |
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