Paraherquamide E

In the title compound, C(28)H(35)N(3)O(4), also known as 14-de­oxy­paraherquamide A,the two pyrrolidine rings adopt envelope conformations. The piperazine ring of the diaza­bicyclo­[2.2.2]octan-3-one unit adopts a boat conformation whereas the two piperidine rings are in distorted boat conformations...

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Detalles Bibliográficos
Autores principales: Aree, Thammarat, Antia, Bassey S., Ekpa, Okon D., Kittakoop, Prasat
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3008018/
https://www.ncbi.nlm.nih.gov/pubmed/21588597
http://dx.doi.org/10.1107/S1600536810030795
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author Aree, Thammarat
Antia, Bassey S.
Ekpa, Okon D.
Kittakoop, Prasat
author_facet Aree, Thammarat
Antia, Bassey S.
Ekpa, Okon D.
Kittakoop, Prasat
author_sort Aree, Thammarat
collection PubMed
description In the title compound, C(28)H(35)N(3)O(4), also known as 14-de­oxy­paraherquamide A,the two pyrrolidine rings adopt envelope conformations. The piperazine ring of the diaza­bicyclo­[2.2.2]octan-3-one unit adopts a boat conformation whereas the two piperidine rings are in distorted boat conformations. Intra­molecular C—H⋯O hydrogen bonds are observed. In the crystal, the mol­ecules are linked into chains along the b axis by inter­molecular N—H⋯O hydrogen bonds.
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spelling pubmed-30080182010-12-30 Paraherquamide E Aree, Thammarat Antia, Bassey S. Ekpa, Okon D. Kittakoop, Prasat Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(28)H(35)N(3)O(4), also known as 14-de­oxy­paraherquamide A,the two pyrrolidine rings adopt envelope conformations. The piperazine ring of the diaza­bicyclo­[2.2.2]octan-3-one unit adopts a boat conformation whereas the two piperidine rings are in distorted boat conformations. Intra­molecular C—H⋯O hydrogen bonds are observed. In the crystal, the mol­ecules are linked into chains along the b axis by inter­molecular N—H⋯O hydrogen bonds. International Union of Crystallography 2010-08-11 /pmc/articles/PMC3008018/ /pubmed/21588597 http://dx.doi.org/10.1107/S1600536810030795 Text en © Aree et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Aree, Thammarat
Antia, Bassey S.
Ekpa, Okon D.
Kittakoop, Prasat
Paraherquamide E
title Paraherquamide E
title_full Paraherquamide E
title_fullStr Paraherquamide E
title_full_unstemmed Paraherquamide E
title_short Paraherquamide E
title_sort paraherquamide e
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3008018/
https://www.ncbi.nlm.nih.gov/pubmed/21588597
http://dx.doi.org/10.1107/S1600536810030795
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AT antiabasseys paraherquamidee
AT ekpaokond paraherquamidee
AT kittakoopprasat paraherquamidee

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