Bis(N-sec-butyl-N-n-propyl­dithio­carbamato-κ(2) S,S′)(1,10-phenanthroline-κ(2) N,N′)zinc(II)

Two independent but very similar mol­ecules comprise the asymmetric unit of the title compound, [Zn(C(8)H(16)NS(2))(2)(C(12)H(8)N(2))]. The N(2)S(4) donor set about Zn is defined by two symmetrically chelating dithio­carbamate ligands and a 1,10-phenanthroline ligand. Distortions from the ideal octa...

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Detalles Bibliográficos
Autores principales: Alzaalouk, Amna Salem, Baba, Ibrahim, Mohamed Tahir, Mohamed Ibrahim, Ng, Seik Weng, Tiekink, Edward R. T.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3008025/
https://www.ncbi.nlm.nih.gov/pubmed/21588557
http://dx.doi.org/10.1107/S1600536810033672
Descripción
Sumario:Two independent but very similar mol­ecules comprise the asymmetric unit of the title compound, [Zn(C(8)H(16)NS(2))(2)(C(12)H(8)N(2))]. The N(2)S(4) donor set about Zn is defined by two symmetrically chelating dithio­carbamate ligands and a 1,10-phenanthroline ligand. Distortions from the ideal octa­hedral coordination geometry arise from the restricted bite angles of the ligands. The main feature of the crystal packing is the formation of tetra­meric supra­molecular aggregates mediated by C—H⋯S inter­actions. Disorder was found in each of the sec-butyl groups. This was resolved over two positions in each case with the major components of the disorder having site occupancies in the range 0.551 (6)–0.725 (5).

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