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2-(4-Chlorophenyl)acetic acid–2-{(E)-[(E)-2-(2-pyridylmethylidene)hydrazin-1-ylidene]methyl}pyridine (1/1)
In the crystal of the title 1:1 adduct, C(8)H(7)ClO(2)·C(12)H(10)N(4), the components are linked by an O—H⋯N hydrogen bond between the carboxylic acid and one of the pyridine N atoms. In the acid, the carboxylic acid group is approximately normal to [dihedral angle = 72.9 (2)°] but twisted with...
Autores principales: | , , |
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2010
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3008031/ https://www.ncbi.nlm.nih.gov/pubmed/21588698 http://dx.doi.org/10.1107/S1600536810032721 |
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author | Arman, Hadi D. Kaulgud, Trupta Tiekink, Edward R. T. |
author_facet | Arman, Hadi D. Kaulgud, Trupta Tiekink, Edward R. T. |
author_sort | Arman, Hadi D. |
collection | PubMed |
description | In the crystal of the title 1:1 adduct, C(8)H(7)ClO(2)·C(12)H(10)N(4), the components are linked by an O—H⋯N hydrogen bond between the carboxylic acid and one of the pyridine N atoms. In the acid, the carboxylic acid group is approximately normal to [dihedral angle = 72.9 (2)°] but twisted with respect to the plane through the benzene ring [C—C—C—O torsion angle = 25.4 (5)°]. The base is roughly planar [dihedral angle between rings = 12.66 (15)°; r.m.s. deviation of the 16 non-H atoms = 0.107 Å] and the conformations about both imine bonds are E. The dimeric aggregates are linked into a supramolecular layer in the ab plane by C—H⋯O interactions. |
format | Text |
id | pubmed-3008031 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2010 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-30080312010-12-30 2-(4-Chlorophenyl)acetic acid–2-{(E)-[(E)-2-(2-pyridylmethylidene)hydrazin-1-ylidene]methyl}pyridine (1/1) Arman, Hadi D. Kaulgud, Trupta Tiekink, Edward R. T. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the crystal of the title 1:1 adduct, C(8)H(7)ClO(2)·C(12)H(10)N(4), the components are linked by an O—H⋯N hydrogen bond between the carboxylic acid and one of the pyridine N atoms. In the acid, the carboxylic acid group is approximately normal to [dihedral angle = 72.9 (2)°] but twisted with respect to the plane through the benzene ring [C—C—C—O torsion angle = 25.4 (5)°]. The base is roughly planar [dihedral angle between rings = 12.66 (15)°; r.m.s. deviation of the 16 non-H atoms = 0.107 Å] and the conformations about both imine bonds are E. The dimeric aggregates are linked into a supramolecular layer in the ab plane by C—H⋯O interactions. International Union of Crystallography 2010-08-21 /pmc/articles/PMC3008031/ /pubmed/21588698 http://dx.doi.org/10.1107/S1600536810032721 Text en © Arman et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Arman, Hadi D. Kaulgud, Trupta Tiekink, Edward R. T. 2-(4-Chlorophenyl)acetic acid–2-{(E)-[(E)-2-(2-pyridylmethylidene)hydrazin-1-ylidene]methyl}pyridine (1/1) |
title | 2-(4-Chlorophenyl)acetic acid–2-{(E)-[(E)-2-(2-pyridylmethylidene)hydrazin-1-ylidene]methyl}pyridine (1/1) |
title_full | 2-(4-Chlorophenyl)acetic acid–2-{(E)-[(E)-2-(2-pyridylmethylidene)hydrazin-1-ylidene]methyl}pyridine (1/1) |
title_fullStr | 2-(4-Chlorophenyl)acetic acid–2-{(E)-[(E)-2-(2-pyridylmethylidene)hydrazin-1-ylidene]methyl}pyridine (1/1) |
title_full_unstemmed | 2-(4-Chlorophenyl)acetic acid–2-{(E)-[(E)-2-(2-pyridylmethylidene)hydrazin-1-ylidene]methyl}pyridine (1/1) |
title_short | 2-(4-Chlorophenyl)acetic acid–2-{(E)-[(E)-2-(2-pyridylmethylidene)hydrazin-1-ylidene]methyl}pyridine (1/1) |
title_sort | 2-(4-chlorophenyl)acetic acid–2-{(e)-[(e)-2-(2-pyridylmethylidene)hydrazin-1-ylidene]methyl}pyridine (1/1) |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3008031/ https://www.ncbi.nlm.nih.gov/pubmed/21588698 http://dx.doi.org/10.1107/S1600536810032721 |
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