(E)-1-(2,2-Dimeth­oxy­eth­yl)-2-(nitro­methyl­idene)imidazolidine

In the title compound, C(8)H(15)N(3)O(4), the 2-(nitro­methyl­ene)imidazolidine fragment is close to being planar (r.m.s. deviation = 0.027 Å), which may be correlated with delocalization of the electrons and the effect of the strongly electron-withdrawing NO(2) group. An intra­molecular N—H⋯O link...

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Detalles Bibliográficos
Autores principales: Li, Dongmei, Tian, Zhongzhen, Wang, Gaolei, Wei, Peifeng, Zhang, Yanming
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3008036/
https://www.ncbi.nlm.nih.gov/pubmed/21588587
http://dx.doi.org/10.1107/S1600536810030266
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author Li, Dongmei
Tian, Zhongzhen
Wang, Gaolei
Wei, Peifeng
Zhang, Yanming
author_facet Li, Dongmei
Tian, Zhongzhen
Wang, Gaolei
Wei, Peifeng
Zhang, Yanming
author_sort Li, Dongmei
collection PubMed
description In the title compound, C(8)H(15)N(3)O(4), the 2-(nitro­methyl­ene)imidazolidine fragment is close to being planar (r.m.s. deviation = 0.027 Å), which may be correlated with delocalization of the electrons and the effect of the strongly electron-withdrawing NO(2) group. An intra­molecular N—H⋯O link generates an S(6) ring. The same H atom also forms a weak inter­molecular N—H⋯O hydrogen bond, which results in C(7) chains propagating in [010].
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spelling pubmed-30080362010-12-30 (E)-1-(2,2-Dimeth­oxy­eth­yl)-2-(nitro­methyl­idene)imidazolidine Li, Dongmei Tian, Zhongzhen Wang, Gaolei Wei, Peifeng Zhang, Yanming Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(8)H(15)N(3)O(4), the 2-(nitro­methyl­ene)imidazolidine fragment is close to being planar (r.m.s. deviation = 0.027 Å), which may be correlated with delocalization of the electrons and the effect of the strongly electron-withdrawing NO(2) group. An intra­molecular N—H⋯O link generates an S(6) ring. The same H atom also forms a weak inter­molecular N—H⋯O hydrogen bond, which results in C(7) chains propagating in [010]. International Union of Crystallography 2010-08-04 /pmc/articles/PMC3008036/ /pubmed/21588587 http://dx.doi.org/10.1107/S1600536810030266 Text en © Li et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Li, Dongmei
Tian, Zhongzhen
Wang, Gaolei
Wei, Peifeng
Zhang, Yanming
(E)-1-(2,2-Dimeth­oxy­eth­yl)-2-(nitro­methyl­idene)imidazolidine
title (E)-1-(2,2-Dimeth­oxy­eth­yl)-2-(nitro­methyl­idene)imidazolidine
title_full (E)-1-(2,2-Dimeth­oxy­eth­yl)-2-(nitro­methyl­idene)imidazolidine
title_fullStr (E)-1-(2,2-Dimeth­oxy­eth­yl)-2-(nitro­methyl­idene)imidazolidine
title_full_unstemmed (E)-1-(2,2-Dimeth­oxy­eth­yl)-2-(nitro­methyl­idene)imidazolidine
title_short (E)-1-(2,2-Dimeth­oxy­eth­yl)-2-(nitro­methyl­idene)imidazolidine
title_sort (e)-1-(2,2-dimeth­oxy­eth­yl)-2-(nitro­methyl­idene)imidazolidine
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3008036/
https://www.ncbi.nlm.nih.gov/pubmed/21588587
http://dx.doi.org/10.1107/S1600536810030266
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