[(1,2,5,6-η)-1,5-Cyclo­octa­diene](1-isopropyl-3-methyl­imidazolin-2-yl­idene)(triphenyl­phosphine)iridium(I) tetra­fluorido­borate dichloro­methane solvate

In the title compound, [Ir(C(8)H(12))(C(7)H(12)N(2))(C(18)H(15)P)]BF(4)·CH(2)Cl(2), the Ir(I) atom has a square-planar conformation with normal bond lengths. One of the phenyl rings, and the solvent dichloro­methane mol­ecule, were refined using separate two part disorder models, each in an approxim...

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Detalles Bibliográficos
Autores principales: Nichol, Gary S., Stasiw, Daniel, Anna, Laura J., Rajaseelan, Edward
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3008037/
https://www.ncbi.nlm.nih.gov/pubmed/21588520
http://dx.doi.org/10.1107/S1600536810031727
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author Nichol, Gary S.
Stasiw, Daniel
Anna, Laura J.
Rajaseelan, Edward
author_facet Nichol, Gary S.
Stasiw, Daniel
Anna, Laura J.
Rajaseelan, Edward
author_sort Nichol, Gary S.
collection PubMed
description In the title compound, [Ir(C(8)H(12))(C(7)H(12)N(2))(C(18)H(15)P)]BF(4)·CH(2)Cl(2), the Ir(I) atom has a square-planar conformation with normal bond lengths. One of the phenyl rings, and the solvent dichloro­methane mol­ecule, were refined using separate two part disorder models, each in an approximately 1:1 ratio.
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spelling pubmed-30080372010-12-30 [(1,2,5,6-η)-1,5-Cyclo­octa­diene](1-isopropyl-3-methyl­imidazolin-2-yl­idene)(triphenyl­phosphine)iridium(I) tetra­fluorido­borate dichloro­methane solvate Nichol, Gary S. Stasiw, Daniel Anna, Laura J. Rajaseelan, Edward Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Ir(C(8)H(12))(C(7)H(12)N(2))(C(18)H(15)P)]BF(4)·CH(2)Cl(2), the Ir(I) atom has a square-planar conformation with normal bond lengths. One of the phenyl rings, and the solvent dichloro­methane mol­ecule, were refined using separate two part disorder models, each in an approximately 1:1 ratio. International Union of Crystallography 2010-08-18 /pmc/articles/PMC3008037/ /pubmed/21588520 http://dx.doi.org/10.1107/S1600536810031727 Text en © Nichol et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Nichol, Gary S.
Stasiw, Daniel
Anna, Laura J.
Rajaseelan, Edward
[(1,2,5,6-η)-1,5-Cyclo­octa­diene](1-isopropyl-3-methyl­imidazolin-2-yl­idene)(triphenyl­phosphine)iridium(I) tetra­fluorido­borate dichloro­methane solvate
title [(1,2,5,6-η)-1,5-Cyclo­octa­diene](1-isopropyl-3-methyl­imidazolin-2-yl­idene)(triphenyl­phosphine)iridium(I) tetra­fluorido­borate dichloro­methane solvate
title_full [(1,2,5,6-η)-1,5-Cyclo­octa­diene](1-isopropyl-3-methyl­imidazolin-2-yl­idene)(triphenyl­phosphine)iridium(I) tetra­fluorido­borate dichloro­methane solvate
title_fullStr [(1,2,5,6-η)-1,5-Cyclo­octa­diene](1-isopropyl-3-methyl­imidazolin-2-yl­idene)(triphenyl­phosphine)iridium(I) tetra­fluorido­borate dichloro­methane solvate
title_full_unstemmed [(1,2,5,6-η)-1,5-Cyclo­octa­diene](1-isopropyl-3-methyl­imidazolin-2-yl­idene)(triphenyl­phosphine)iridium(I) tetra­fluorido­borate dichloro­methane solvate
title_short [(1,2,5,6-η)-1,5-Cyclo­octa­diene](1-isopropyl-3-methyl­imidazolin-2-yl­idene)(triphenyl­phosphine)iridium(I) tetra­fluorido­borate dichloro­methane solvate
title_sort [(1,2,5,6-η)-1,5-cyclo­octa­diene](1-isopropyl-3-methyl­imidazolin-2-yl­idene)(triphenyl­phosphine)iridium(i) tetra­fluorido­borate dichloro­methane solvate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3008037/
https://www.ncbi.nlm.nih.gov/pubmed/21588520
http://dx.doi.org/10.1107/S1600536810031727
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AT annalauraj 1256ē15cyclooctadiene1isopropyl3methylimidazolin2ylidenetriphenylphosphineiridiumitetrafluoridoboratedichloromethanesolvate
AT rajaseelanedward 1256ē15cyclooctadiene1isopropyl3methylimidazolin2ylidenetriphenylphosphineiridiumitetrafluoridoboratedichloromethanesolvate

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