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[2-(2,3-Dimethylanilino)phenyl]methanol
In the title compound, C(15)H(17)NO, the 2,3-dimethylphenyl group is disordered over two sites with an occupancy ratio of 0.869 (3):0.131 (3). The major and minor components of the 2,3-dimethylanilino group are planar, with r.m.s. deviations of 0.0214 and 0.0303 Å, respectively, and are oriented a...
Autores principales: | , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2010
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3008038/ https://www.ncbi.nlm.nih.gov/pubmed/21588712 http://dx.doi.org/10.1107/S1600536810033325 |
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author | Nasirullah, Islam, Nazar Ul Tahir, M. Nawaz Khan, Ikhtiar |
author_facet | Nasirullah, Islam, Nazar Ul Tahir, M. Nawaz Khan, Ikhtiar |
author_sort | Nasirullah, |
collection | PubMed |
description | In the title compound, C(15)H(17)NO, the 2,3-dimethylphenyl group is disordered over two sites with an occupancy ratio of 0.869 (3):0.131 (3). The major and minor components of the 2,3-dimethylanilino group are planar, with r.m.s. deviations of 0.0214 and 0.0303 Å, respectively, and are oriented at a dihedral angle of 2.6 (6)°. The phenylmethanol–benzene ring is oriented at dihedral angles of 83.16 (6) and 81.0 (3)° with respect to the major and minor components of the 2,3-dimethylanilino group, respectively. An S(6) ring motif is present due to intramolecular N—H⋯O hydrogen bonding. In the crystal, molecules are connected into supramolecular chains via O—H⋯O hydrogen bonding along the b axis. C—H⋯π interactions help to stabilize the crystal structure. |
format | Text |
id | pubmed-3008038 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2010 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-30080382010-12-30 [2-(2,3-Dimethylanilino)phenyl]methanol Nasirullah, Islam, Nazar Ul Tahir, M. Nawaz Khan, Ikhtiar Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(15)H(17)NO, the 2,3-dimethylphenyl group is disordered over two sites with an occupancy ratio of 0.869 (3):0.131 (3). The major and minor components of the 2,3-dimethylanilino group are planar, with r.m.s. deviations of 0.0214 and 0.0303 Å, respectively, and are oriented at a dihedral angle of 2.6 (6)°. The phenylmethanol–benzene ring is oriented at dihedral angles of 83.16 (6) and 81.0 (3)° with respect to the major and minor components of the 2,3-dimethylanilino group, respectively. An S(6) ring motif is present due to intramolecular N—H⋯O hydrogen bonding. In the crystal, molecules are connected into supramolecular chains via O—H⋯O hydrogen bonding along the b axis. C—H⋯π interactions help to stabilize the crystal structure. International Union of Crystallography 2010-08-21 /pmc/articles/PMC3008038/ /pubmed/21588712 http://dx.doi.org/10.1107/S1600536810033325 Text en © Nasirullah et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Nasirullah, Islam, Nazar Ul Tahir, M. Nawaz Khan, Ikhtiar [2-(2,3-Dimethylanilino)phenyl]methanol |
title | [2-(2,3-Dimethylanilino)phenyl]methanol |
title_full | [2-(2,3-Dimethylanilino)phenyl]methanol |
title_fullStr | [2-(2,3-Dimethylanilino)phenyl]methanol |
title_full_unstemmed | [2-(2,3-Dimethylanilino)phenyl]methanol |
title_short | [2-(2,3-Dimethylanilino)phenyl]methanol |
title_sort | [2-(2,3-dimethylanilino)phenyl]methanol |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3008038/ https://www.ncbi.nlm.nih.gov/pubmed/21588712 http://dx.doi.org/10.1107/S1600536810033325 |
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