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[2-(2,3-Dimethyl­anilino)phen­yl]methanol

In the title compound, C(15)H(17)NO, the 2,3-dimethyl­phenyl group is disordered over two sites with an occupancy ratio of 0.869 (3):0.131 (3). The major and minor components of the 2,3-dimethyl­anilino group are planar, with r.m.s. deviations of 0.0214 and 0.0303 Å, respectively, and are oriented a...

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Autores principales: Nasirullah, Islam, Nazar Ul, Tahir, M. Nawaz, Khan, Ikhtiar
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3008038/
https://www.ncbi.nlm.nih.gov/pubmed/21588712
http://dx.doi.org/10.1107/S1600536810033325
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author Nasirullah,
Islam, Nazar Ul
Tahir, M. Nawaz
Khan, Ikhtiar
author_facet Nasirullah,
Islam, Nazar Ul
Tahir, M. Nawaz
Khan, Ikhtiar
author_sort Nasirullah,
collection PubMed
description In the title compound, C(15)H(17)NO, the 2,3-dimethyl­phenyl group is disordered over two sites with an occupancy ratio of 0.869 (3):0.131 (3). The major and minor components of the 2,3-dimethyl­anilino group are planar, with r.m.s. deviations of 0.0214 and 0.0303 Å, respectively, and are oriented at a dihedral angle of 2.6 (6)°. The phenyl­methanol–benzene ring is oriented at dihedral angles of 83.16 (6) and 81.0 (3)° with respect to the major and minor components of the 2,3-dimethyl­anilino group, respectively. An S(6) ring motif is present due to intra­molecular N—H⋯O hydrogen bonding. In the crystal, mol­ecules are connected into supra­molecular chains via O—H⋯O hydrogen bonding along the b axis. C—H⋯π inter­actions help to stabilize the crystal structure.
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spelling pubmed-30080382010-12-30 [2-(2,3-Dimethyl­anilino)phen­yl]methanol Nasirullah, Islam, Nazar Ul Tahir, M. Nawaz Khan, Ikhtiar Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(15)H(17)NO, the 2,3-dimethyl­phenyl group is disordered over two sites with an occupancy ratio of 0.869 (3):0.131 (3). The major and minor components of the 2,3-dimethyl­anilino group are planar, with r.m.s. deviations of 0.0214 and 0.0303 Å, respectively, and are oriented at a dihedral angle of 2.6 (6)°. The phenyl­methanol–benzene ring is oriented at dihedral angles of 83.16 (6) and 81.0 (3)° with respect to the major and minor components of the 2,3-dimethyl­anilino group, respectively. An S(6) ring motif is present due to intra­molecular N—H⋯O hydrogen bonding. In the crystal, mol­ecules are connected into supra­molecular chains via O—H⋯O hydrogen bonding along the b axis. C—H⋯π inter­actions help to stabilize the crystal structure. International Union of Crystallography 2010-08-21 /pmc/articles/PMC3008038/ /pubmed/21588712 http://dx.doi.org/10.1107/S1600536810033325 Text en © Nasirullah et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Nasirullah,
Islam, Nazar Ul
Tahir, M. Nawaz
Khan, Ikhtiar
[2-(2,3-Dimethyl­anilino)phen­yl]methanol
title [2-(2,3-Dimethyl­anilino)phen­yl]methanol
title_full [2-(2,3-Dimethyl­anilino)phen­yl]methanol
title_fullStr [2-(2,3-Dimethyl­anilino)phen­yl]methanol
title_full_unstemmed [2-(2,3-Dimethyl­anilino)phen­yl]methanol
title_short [2-(2,3-Dimethyl­anilino)phen­yl]methanol
title_sort [2-(2,3-dimethyl­anilino)phen­yl]methanol
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3008038/
https://www.ncbi.nlm.nih.gov/pubmed/21588712
http://dx.doi.org/10.1107/S1600536810033325
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