Bis[2,4-dibromo-6-(n-propyl­imino­methyl)phenolato-κ(2) N,O]cobalt(II)

In the title complex, [Co(C(10)H(10)Br(2)NO)(2)], the Co(II) atom lies on a twofold rotation axis, the N(2)O(2) units having distorted tetra­hedral coordination environments comprising two bidentate chelate 2,4-dibromo-6-(n-propyl­imino­meth­yl)phenolate Schiff base ligands [Co—N = 1.989 (3) Å, Co—O...

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Detalles Bibliográficos
Autores principales: Li, Chunyan, Li, Rui, Zhang, Shufang
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3008039/
https://www.ncbi.nlm.nih.gov/pubmed/21588527
http://dx.doi.org/10.1107/S1600536810032162
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author Li, Chunyan
Li, Rui
Zhang, Shufang
author_facet Li, Chunyan
Li, Rui
Zhang, Shufang
author_sort Li, Chunyan
collection PubMed
description In the title complex, [Co(C(10)H(10)Br(2)NO)(2)], the Co(II) atom lies on a twofold rotation axis, the N(2)O(2) units having distorted tetra­hedral coordination environments comprising two bidentate chelate 2,4-dibromo-6-(n-propyl­imino­meth­yl)phenolate Schiff base ligands [Co—N = 1.989 (3) Å, Co—O = 1.924 (2) Å and O/N—Co—O/N = 94.53 (10)–125.40 (15)°]. In the crystal structure, the mol­ecules are linked via weak inter­molecular C—H⋯O hydrogen bonds [3.334 (5) Å] and there are also short inversion-related intermolecular Br⋯Br contacts [3.4263 (6) Å]
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spelling pubmed-30080392010-12-30 Bis[2,4-dibromo-6-(n-propyl­imino­methyl)phenolato-κ(2) N,O]cobalt(II) Li, Chunyan Li, Rui Zhang, Shufang Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [Co(C(10)H(10)Br(2)NO)(2)], the Co(II) atom lies on a twofold rotation axis, the N(2)O(2) units having distorted tetra­hedral coordination environments comprising two bidentate chelate 2,4-dibromo-6-(n-propyl­imino­meth­yl)phenolate Schiff base ligands [Co—N = 1.989 (3) Å, Co—O = 1.924 (2) Å and O/N—Co—O/N = 94.53 (10)–125.40 (15)°]. In the crystal structure, the mol­ecules are linked via weak inter­molecular C—H⋯O hydrogen bonds [3.334 (5) Å] and there are also short inversion-related intermolecular Br⋯Br contacts [3.4263 (6) Å] International Union of Crystallography 2010-08-18 /pmc/articles/PMC3008039/ /pubmed/21588527 http://dx.doi.org/10.1107/S1600536810032162 Text en © Li et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Li, Chunyan
Li, Rui
Zhang, Shufang
Bis[2,4-dibromo-6-(n-propyl­imino­methyl)phenolato-κ(2) N,O]cobalt(II)
title Bis[2,4-dibromo-6-(n-propyl­imino­methyl)phenolato-κ(2) N,O]cobalt(II)
title_full Bis[2,4-dibromo-6-(n-propyl­imino­methyl)phenolato-κ(2) N,O]cobalt(II)
title_fullStr Bis[2,4-dibromo-6-(n-propyl­imino­methyl)phenolato-κ(2) N,O]cobalt(II)
title_full_unstemmed Bis[2,4-dibromo-6-(n-propyl­imino­methyl)phenolato-κ(2) N,O]cobalt(II)
title_short Bis[2,4-dibromo-6-(n-propyl­imino­methyl)phenolato-κ(2) N,O]cobalt(II)
title_sort bis[2,4-dibromo-6-(n-propyl­imino­methyl)phenolato-κ(2) n,o]cobalt(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3008039/
https://www.ncbi.nlm.nih.gov/pubmed/21588527
http://dx.doi.org/10.1107/S1600536810032162
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AT lirui bis24dibromo6npropyliminomethylphenolatok2nocobaltii
AT zhangshufang bis24dibromo6npropyliminomethylphenolatok2nocobaltii

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