Cyclo­hexane-1,3-diyl bis­(N-phenyl­carbamate)

The asymmetric unit of the title compound, C(20)H(22)N(2)O(4), comprises two crystallographically independent mol­ecules (A and B) with slightly different geometries. The dihedral angle between the two terminal phenyl rings is 61.7 (1)° in mol­ecule A and 29.6 (1)° in B. The cyclo­hexane rings adopt...

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Autores principales: Ghalib, Raza Murad, Sulaiman, Othman, Mehdi, Sayed Hasan, Goh, Jia Hao, Fun, Hoong-Kun
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3008041/
https://www.ncbi.nlm.nih.gov/pubmed/21588737
http://dx.doi.org/10.1107/S1600536810033817
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author Ghalib, Raza Murad
Sulaiman, Othman
Mehdi, Sayed Hasan
Goh, Jia Hao
Fun, Hoong-Kun
author_facet Ghalib, Raza Murad
Sulaiman, Othman
Mehdi, Sayed Hasan
Goh, Jia Hao
Fun, Hoong-Kun
author_sort Ghalib, Raza Murad
collection PubMed
description The asymmetric unit of the title compound, C(20)H(22)N(2)O(4), comprises two crystallographically independent mol­ecules (A and B) with slightly different geometries. The dihedral angle between the two terminal phenyl rings is 61.7 (1)° in mol­ecule A and 29.6 (1)° in B. The cyclo­hexane rings adopt chair conformations. In the crystal packing, inter­molecular N—H⋯O hydrogen bonds inter­connect adjacent mol­ecules into a ladder-like structure along the c axis incorporating R (2) (2)(20) ring motifs. The crystal packing is further stabilized by weak inter­molecular C—H⋯π inter­actions.
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spelling pubmed-30080412010-12-30 Cyclo­hexane-1,3-diyl bis­(N-phenyl­carbamate) Ghalib, Raza Murad Sulaiman, Othman Mehdi, Sayed Hasan Goh, Jia Hao Fun, Hoong-Kun Acta Crystallogr Sect E Struct Rep Online Organic Papers The asymmetric unit of the title compound, C(20)H(22)N(2)O(4), comprises two crystallographically independent mol­ecules (A and B) with slightly different geometries. The dihedral angle between the two terminal phenyl rings is 61.7 (1)° in mol­ecule A and 29.6 (1)° in B. The cyclo­hexane rings adopt chair conformations. In the crystal packing, inter­molecular N—H⋯O hydrogen bonds inter­connect adjacent mol­ecules into a ladder-like structure along the c axis incorporating R (2) (2)(20) ring motifs. The crystal packing is further stabilized by weak inter­molecular C—H⋯π inter­actions. International Union of Crystallography 2010-08-28 /pmc/articles/PMC3008041/ /pubmed/21588737 http://dx.doi.org/10.1107/S1600536810033817 Text en © Ghalib et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Ghalib, Raza Murad
Sulaiman, Othman
Mehdi, Sayed Hasan
Goh, Jia Hao
Fun, Hoong-Kun
Cyclo­hexane-1,3-diyl bis­(N-phenyl­carbamate)
title Cyclo­hexane-1,3-diyl bis­(N-phenyl­carbamate)
title_full Cyclo­hexane-1,3-diyl bis­(N-phenyl­carbamate)
title_fullStr Cyclo­hexane-1,3-diyl bis­(N-phenyl­carbamate)
title_full_unstemmed Cyclo­hexane-1,3-diyl bis­(N-phenyl­carbamate)
title_short Cyclo­hexane-1,3-diyl bis­(N-phenyl­carbamate)
title_sort cyclo­hexane-1,3-diyl bis­(n-phenyl­carbamate)
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3008041/
https://www.ncbi.nlm.nih.gov/pubmed/21588737
http://dx.doi.org/10.1107/S1600536810033817
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AT sulaimanothman cyclohexane13diylbisnphenylcarbamate
AT mehdisayedhasan cyclohexane13diylbisnphenylcarbamate
AT gohjiahao cyclohexane13diylbisnphenylcarbamate
AT funhoongkun cyclohexane13diylbisnphenylcarbamate

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