[2-(Diphenyl­phosphan­yl)benzene­thiol­ato-κ(2) P,S](pyridine-2-thiol­ato-κS)(triphenyl­phosphine-κP)palladium(II)

In the title compound, [Pd(C(5)H(4)NS)(C(18)H(14)PS)(C(18)H(15)P)], the Pd(II) atom has a slightly distorted square-planar environment. Two coordination sites are occupied by a P,S-chelating 2-(diphenyl­phosphan­yl)benzene­thiol­ate ligand and the other two by a P atom from a triphenyl­phosphine lig...

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Autores principales: Ríos-Sanchez, Raúl, Hernández-Ortega, Simón, Morales-Morales, David, Avila-Sorrosa, Alcives
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3008042/
https://www.ncbi.nlm.nih.gov/pubmed/21588560
http://dx.doi.org/10.1107/S160053681003357X
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author Ríos-Sanchez, Raúl
Hernández-Ortega, Simón
Morales-Morales, David
Avila-Sorrosa, Alcives
author_facet Ríos-Sanchez, Raúl
Hernández-Ortega, Simón
Morales-Morales, David
Avila-Sorrosa, Alcives
author_sort Ríos-Sanchez, Raúl
collection PubMed
description In the title compound, [Pd(C(5)H(4)NS)(C(18)H(14)PS)(C(18)H(15)P)], the Pd(II) atom has a slightly distorted square-planar environment. Two coordination sites are occupied by a P,S-chelating 2-(diphenyl­phosphan­yl)benzene­thiol­ate ligand and the other two by a P atom from a triphenyl­phosphine ligand and an S atom from a pyridine-2-thiol­ate ligand, exhibiting a trans arrangement of the two P-donor atoms. In the crystal structure, weak intra- and inter­molecular C—H⋯π and π–π inter­actions are observed. The pyridyl ring is equally disordered over two positions.
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spelling pubmed-30080422010-12-30 [2-(Diphenyl­phosphan­yl)benzene­thiol­ato-κ(2) P,S](pyridine-2-thiol­ato-κS)(triphenyl­phosphine-κP)palladium(II) Ríos-Sanchez, Raúl Hernández-Ortega, Simón Morales-Morales, David Avila-Sorrosa, Alcives Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Pd(C(5)H(4)NS)(C(18)H(14)PS)(C(18)H(15)P)], the Pd(II) atom has a slightly distorted square-planar environment. Two coordination sites are occupied by a P,S-chelating 2-(diphenyl­phosphan­yl)benzene­thiol­ate ligand and the other two by a P atom from a triphenyl­phosphine ligand and an S atom from a pyridine-2-thiol­ate ligand, exhibiting a trans arrangement of the two P-donor atoms. In the crystal structure, weak intra- and inter­molecular C—H⋯π and π–π inter­actions are observed. The pyridyl ring is equally disordered over two positions. International Union of Crystallography 2010-08-28 /pmc/articles/PMC3008042/ /pubmed/21588560 http://dx.doi.org/10.1107/S160053681003357X Text en © Ríos-Sanchez et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Ríos-Sanchez, Raúl
Hernández-Ortega, Simón
Morales-Morales, David
Avila-Sorrosa, Alcives
[2-(Diphenyl­phosphan­yl)benzene­thiol­ato-κ(2) P,S](pyridine-2-thiol­ato-κS)(triphenyl­phosphine-κP)palladium(II)
title [2-(Diphenyl­phosphan­yl)benzene­thiol­ato-κ(2) P,S](pyridine-2-thiol­ato-κS)(triphenyl­phosphine-κP)palladium(II)
title_full [2-(Diphenyl­phosphan­yl)benzene­thiol­ato-κ(2) P,S](pyridine-2-thiol­ato-κS)(triphenyl­phosphine-κP)palladium(II)
title_fullStr [2-(Diphenyl­phosphan­yl)benzene­thiol­ato-κ(2) P,S](pyridine-2-thiol­ato-κS)(triphenyl­phosphine-κP)palladium(II)
title_full_unstemmed [2-(Diphenyl­phosphan­yl)benzene­thiol­ato-κ(2) P,S](pyridine-2-thiol­ato-κS)(triphenyl­phosphine-κP)palladium(II)
title_short [2-(Diphenyl­phosphan­yl)benzene­thiol­ato-κ(2) P,S](pyridine-2-thiol­ato-κS)(triphenyl­phosphine-κP)palladium(II)
title_sort [2-(diphenyl­phosphan­yl)benzene­thiol­ato-κ(2) p,s](pyridine-2-thiol­ato-κs)(triphenyl­phosphine-κp)palladium(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3008042/
https://www.ncbi.nlm.nih.gov/pubmed/21588560
http://dx.doi.org/10.1107/S160053681003357X
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