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Poly[diaqua-μ(2)-oxalato-di-μ(4)-terephthalato-diytterbium(III)]

The crystal structure of the title complex, [Yb(2)(C(8)H(4)O(4))(2)(C(2)O(4))(H(2)O)(2)](n), features an extended three-dimensional framework made up of Yb(3+) ions coordinated by terephthalate ligands, oxalate ligands and water mol­ecules. The Yb(3+) ion has a distorted square-anti­prismatic coordi...

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Detalles Bibliográficos
Autores principales: Wang, Chun-Xiang, Li, Zhi-Feng
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3008045/
https://www.ncbi.nlm.nih.gov/pubmed/21588553
http://dx.doi.org/10.1107/S1600536810033052
Descripción
Sumario:The crystal structure of the title complex, [Yb(2)(C(8)H(4)O(4))(2)(C(2)O(4))(H(2)O)(2)](n), features an extended three-dimensional framework made up of Yb(3+) ions coordinated by terephthalate ligands, oxalate ligands and water mol­ecules. The Yb(3+) ion has a distorted square-anti­prismatic coordination formed by one aqua ligand, two O atoms from an oxalate ligand and five O atoms belonging to four terephthalate anions. Two symmetry-independent terephthalate anions, as well as the oxalate anion, occupy special positions on inversion centers. The water molecule participates in O—H⋯O hydrogen bonding with both terephthalate anions.