Cargando…
Poly[diaqua-μ(2)-oxalato-di-μ(4)-terephthalato-diytterbium(III)]
The crystal structure of the title complex, [Yb(2)(C(8)H(4)O(4))(2)(C(2)O(4))(H(2)O)(2)](n), features an extended three-dimensional framework made up of Yb(3+) ions coordinated by terephthalate ligands, oxalate ligands and water molecules. The Yb(3+) ion has a distorted square-antiprismatic coordi...
Autores principales: | , |
---|---|
Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2010
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3008045/ https://www.ncbi.nlm.nih.gov/pubmed/21588553 http://dx.doi.org/10.1107/S1600536810033052 |
_version_ | 1782194489214894080 |
---|---|
author | Wang, Chun-Xiang Li, Zhi-Feng |
author_facet | Wang, Chun-Xiang Li, Zhi-Feng |
author_sort | Wang, Chun-Xiang |
collection | PubMed |
description | The crystal structure of the title complex, [Yb(2)(C(8)H(4)O(4))(2)(C(2)O(4))(H(2)O)(2)](n), features an extended three-dimensional framework made up of Yb(3+) ions coordinated by terephthalate ligands, oxalate ligands and water molecules. The Yb(3+) ion has a distorted square-antiprismatic coordination formed by one aqua ligand, two O atoms from an oxalate ligand and five O atoms belonging to four terephthalate anions. Two symmetry-independent terephthalate anions, as well as the oxalate anion, occupy special positions on inversion centers. The water molecule participates in O—H⋯O hydrogen bonding with both terephthalate anions. |
format | Text |
id | pubmed-3008045 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2010 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-30080452010-12-30 Poly[diaqua-μ(2)-oxalato-di-μ(4)-terephthalato-diytterbium(III)] Wang, Chun-Xiang Li, Zhi-Feng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The crystal structure of the title complex, [Yb(2)(C(8)H(4)O(4))(2)(C(2)O(4))(H(2)O)(2)](n), features an extended three-dimensional framework made up of Yb(3+) ions coordinated by terephthalate ligands, oxalate ligands and water molecules. The Yb(3+) ion has a distorted square-antiprismatic coordination formed by one aqua ligand, two O atoms from an oxalate ligand and five O atoms belonging to four terephthalate anions. Two symmetry-independent terephthalate anions, as well as the oxalate anion, occupy special positions on inversion centers. The water molecule participates in O—H⋯O hydrogen bonding with both terephthalate anions. International Union of Crystallography 2010-08-25 /pmc/articles/PMC3008045/ /pubmed/21588553 http://dx.doi.org/10.1107/S1600536810033052 Text en © Wang and Li 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Wang, Chun-Xiang Li, Zhi-Feng Poly[diaqua-μ(2)-oxalato-di-μ(4)-terephthalato-diytterbium(III)] |
title | Poly[diaqua-μ(2)-oxalato-di-μ(4)-terephthalato-diytterbium(III)] |
title_full | Poly[diaqua-μ(2)-oxalato-di-μ(4)-terephthalato-diytterbium(III)] |
title_fullStr | Poly[diaqua-μ(2)-oxalato-di-μ(4)-terephthalato-diytterbium(III)] |
title_full_unstemmed | Poly[diaqua-μ(2)-oxalato-di-μ(4)-terephthalato-diytterbium(III)] |
title_short | Poly[diaqua-μ(2)-oxalato-di-μ(4)-terephthalato-diytterbium(III)] |
title_sort | poly[diaqua-μ(2)-oxalato-di-μ(4)-terephthalato-diytterbium(iii)] |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3008045/ https://www.ncbi.nlm.nih.gov/pubmed/21588553 http://dx.doi.org/10.1107/S1600536810033052 |
work_keys_str_mv | AT wangchunxiang polydiaquam2oxalatodim4terephthalatodiytterbiumiii AT lizhifeng polydiaquam2oxalatodim4terephthalatodiytterbiumiii |