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Poly[diaqua-μ(2)-oxalato-di-μ(4)-terephthalato-diytterbium(III)]

The crystal structure of the title complex, [Yb(2)(C(8)H(4)O(4))(2)(C(2)O(4))(H(2)O)(2)](n), features an extended three-dimensional framework made up of Yb(3+) ions coordinated by terephthalate ligands, oxalate ligands and water mol­ecules. The Yb(3+) ion has a distorted square-anti­prismatic coordi...

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Detalles Bibliográficos
Autores principales: Wang, Chun-Xiang, Li, Zhi-Feng
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3008045/
https://www.ncbi.nlm.nih.gov/pubmed/21588553
http://dx.doi.org/10.1107/S1600536810033052
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author Wang, Chun-Xiang
Li, Zhi-Feng
author_facet Wang, Chun-Xiang
Li, Zhi-Feng
author_sort Wang, Chun-Xiang
collection PubMed
description The crystal structure of the title complex, [Yb(2)(C(8)H(4)O(4))(2)(C(2)O(4))(H(2)O)(2)](n), features an extended three-dimensional framework made up of Yb(3+) ions coordinated by terephthalate ligands, oxalate ligands and water mol­ecules. The Yb(3+) ion has a distorted square-anti­prismatic coordination formed by one aqua ligand, two O atoms from an oxalate ligand and five O atoms belonging to four terephthalate anions. Two symmetry-independent terephthalate anions, as well as the oxalate anion, occupy special positions on inversion centers. The water molecule participates in O—H⋯O hydrogen bonding with both terephthalate anions.
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spelling pubmed-30080452010-12-30 Poly[diaqua-μ(2)-oxalato-di-μ(4)-terephthalato-diytterbium(III)] Wang, Chun-Xiang Li, Zhi-Feng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The crystal structure of the title complex, [Yb(2)(C(8)H(4)O(4))(2)(C(2)O(4))(H(2)O)(2)](n), features an extended three-dimensional framework made up of Yb(3+) ions coordinated by terephthalate ligands, oxalate ligands and water mol­ecules. The Yb(3+) ion has a distorted square-anti­prismatic coordination formed by one aqua ligand, two O atoms from an oxalate ligand and five O atoms belonging to four terephthalate anions. Two symmetry-independent terephthalate anions, as well as the oxalate anion, occupy special positions on inversion centers. The water molecule participates in O—H⋯O hydrogen bonding with both terephthalate anions. International Union of Crystallography 2010-08-25 /pmc/articles/PMC3008045/ /pubmed/21588553 http://dx.doi.org/10.1107/S1600536810033052 Text en © Wang and Li 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Wang, Chun-Xiang
Li, Zhi-Feng
Poly[diaqua-μ(2)-oxalato-di-μ(4)-terephthalato-diytterbium(III)]
title Poly[diaqua-μ(2)-oxalato-di-μ(4)-terephthalato-diytterbium(III)]
title_full Poly[diaqua-μ(2)-oxalato-di-μ(4)-terephthalato-diytterbium(III)]
title_fullStr Poly[diaqua-μ(2)-oxalato-di-μ(4)-terephthalato-diytterbium(III)]
title_full_unstemmed Poly[diaqua-μ(2)-oxalato-di-μ(4)-terephthalato-diytterbium(III)]
title_short Poly[diaqua-μ(2)-oxalato-di-μ(4)-terephthalato-diytterbium(III)]
title_sort poly[diaqua-μ(2)-oxalato-di-μ(4)-terephthalato-diytterbium(iii)]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3008045/
https://www.ncbi.nlm.nih.gov/pubmed/21588553
http://dx.doi.org/10.1107/S1600536810033052
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