2-[(E)-(2-Chloro­phen­yl)imino­meth­yl]-6-methyl­phenol

The title compound, C(14)H(12)ClNO, a Schiff base derived from 3-methyl­salicyl­aldehyde, crystallizes in the phenol–imine tautomeric form with an E conformation for the imine functionality. The mol­ecule is not planar, the dihedral angle between the aromatic rings being 36.38 (5)°. The hy­droxy H a...

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Detalles Bibliográficos
Autores principales: Zhu, Peihua, Yu, Jiemei, Wang, Hongyan, Zhang, Chunlai, Yang, Dongming
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3008053/
https://www.ncbi.nlm.nih.gov/pubmed/21588779
http://dx.doi.org/10.1107/S1600536810033969
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author Zhu, Peihua
Yu, Jiemei
Wang, Hongyan
Zhang, Chunlai
Yang, Dongming
author_facet Zhu, Peihua
Yu, Jiemei
Wang, Hongyan
Zhang, Chunlai
Yang, Dongming
author_sort Zhu, Peihua
collection PubMed
description The title compound, C(14)H(12)ClNO, a Schiff base derived from 3-methyl­salicyl­aldehyde, crystallizes in the phenol–imine tautomeric form with an E conformation for the imine functionality. The mol­ecule is not planar, the dihedral angle between the aromatic rings being 36.38 (5)°. The hy­droxy H atom is involved in a strong intra­molecular O—H⋯N hydrogen bond, generating an S(6) ring.
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spelling pubmed-30080532010-12-30 2-[(E)-(2-Chloro­phen­yl)imino­meth­yl]-6-methyl­phenol Zhu, Peihua Yu, Jiemei Wang, Hongyan Zhang, Chunlai Yang, Dongming Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(14)H(12)ClNO, a Schiff base derived from 3-methyl­salicyl­aldehyde, crystallizes in the phenol–imine tautomeric form with an E conformation for the imine functionality. The mol­ecule is not planar, the dihedral angle between the aromatic rings being 36.38 (5)°. The hy­droxy H atom is involved in a strong intra­molecular O—H⋯N hydrogen bond, generating an S(6) ring. International Union of Crystallography 2010-08-28 /pmc/articles/PMC3008053/ /pubmed/21588779 http://dx.doi.org/10.1107/S1600536810033969 Text en © Zhu et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Zhu, Peihua
Yu, Jiemei
Wang, Hongyan
Zhang, Chunlai
Yang, Dongming
2-[(E)-(2-Chloro­phen­yl)imino­meth­yl]-6-methyl­phenol
title 2-[(E)-(2-Chloro­phen­yl)imino­meth­yl]-6-methyl­phenol
title_full 2-[(E)-(2-Chloro­phen­yl)imino­meth­yl]-6-methyl­phenol
title_fullStr 2-[(E)-(2-Chloro­phen­yl)imino­meth­yl]-6-methyl­phenol
title_full_unstemmed 2-[(E)-(2-Chloro­phen­yl)imino­meth­yl]-6-methyl­phenol
title_short 2-[(E)-(2-Chloro­phen­yl)imino­meth­yl]-6-methyl­phenol
title_sort 2-[(e)-(2-chloro­phen­yl)imino­meth­yl]-6-methyl­phenol
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3008053/
https://www.ncbi.nlm.nih.gov/pubmed/21588779
http://dx.doi.org/10.1107/S1600536810033969
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AT wanghongyan 2e2chlorophenyliminomethyl6methylphenol
AT zhangchunlai 2e2chlorophenyliminomethyl6methylphenol
AT yangdongming 2e2chlorophenyliminomethyl6methylphenol

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