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[μ-1,2-Bis(4-pyrid­yl)ethane-κ(2) N:N′]bis­[(4′-phenyl-2,2′:6′,2′′-terpyridine-κ(3) N,N′,N′′)silver(I)] bis­(trifluoro­methane­sulfonate)

In the title compound, [Ag(2)(C(12)H(12)N(2))(C(21)H(15)N(3))(2)](CF(3)SO(3))(2), the Ag(I) atom is coordinated by three N atoms of one 4′-phenyl-2,2′:6′,2′′-terpyridine (phtpy) ligand and one pyridyl N atom of the 1,2-bis­(4-pyrid­yl)ethane (bpe) ligand, displaying a distorted square-planar geometr...

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Detalles Bibliográficos
Autores principales: Ma, Yajun, Liu, Buming, Xue, Chenghu
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3008054/
https://www.ncbi.nlm.nih.gov/pubmed/21588522
http://dx.doi.org/10.1107/S1600536810031776
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author Ma, Yajun
Liu, Buming
Xue, Chenghu
author_facet Ma, Yajun
Liu, Buming
Xue, Chenghu
author_sort Ma, Yajun
collection PubMed
description In the title compound, [Ag(2)(C(12)H(12)N(2))(C(21)H(15)N(3))(2)](CF(3)SO(3))(2), the Ag(I) atom is coordinated by three N atoms of one 4′-phenyl-2,2′:6′,2′′-terpyridine (phtpy) ligand and one pyridyl N atom of the 1,2-bis­(4-pyrid­yl)ethane (bpe) ligand, displaying a distorted square-planar geometry. Two Ag(I) atoms are bridged by one trans-bpe ligand, generating a dinuclear cation. The dinuclear cation is located on a centre of inversion, which is in the middle of the ethyl­ene fragment of the bpe ligand. In the crystal, the pyridyl rings of neighboring dinuclear units are stacked by π–π inter­actions with centroid–centroid distances of 3.667 (2) and 3.835 (2) Å. The F and O atoms of the CF(3)SO(3) (−) anions are involved in inter­molecular C—H⋯F and C—H⋯O hydrogen-bonding inter­actions, respectively, with –CH groups from the phtpy ligands.
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spelling pubmed-30080542010-12-30 [μ-1,2-Bis(4-pyrid­yl)ethane-κ(2) N:N′]bis­[(4′-phenyl-2,2′:6′,2′′-terpyridine-κ(3) N,N′,N′′)silver(I)] bis­(trifluoro­methane­sulfonate) Ma, Yajun Liu, Buming Xue, Chenghu Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Ag(2)(C(12)H(12)N(2))(C(21)H(15)N(3))(2)](CF(3)SO(3))(2), the Ag(I) atom is coordinated by three N atoms of one 4′-phenyl-2,2′:6′,2′′-terpyridine (phtpy) ligand and one pyridyl N atom of the 1,2-bis­(4-pyrid­yl)ethane (bpe) ligand, displaying a distorted square-planar geometry. Two Ag(I) atoms are bridged by one trans-bpe ligand, generating a dinuclear cation. The dinuclear cation is located on a centre of inversion, which is in the middle of the ethyl­ene fragment of the bpe ligand. In the crystal, the pyridyl rings of neighboring dinuclear units are stacked by π–π inter­actions with centroid–centroid distances of 3.667 (2) and 3.835 (2) Å. The F and O atoms of the CF(3)SO(3) (−) anions are involved in inter­molecular C—H⋯F and C—H⋯O hydrogen-bonding inter­actions, respectively, with –CH groups from the phtpy ligands. International Union of Crystallography 2010-08-18 /pmc/articles/PMC3008054/ /pubmed/21588522 http://dx.doi.org/10.1107/S1600536810031776 Text en © Ma et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Ma, Yajun
Liu, Buming
Xue, Chenghu
[μ-1,2-Bis(4-pyrid­yl)ethane-κ(2) N:N′]bis­[(4′-phenyl-2,2′:6′,2′′-terpyridine-κ(3) N,N′,N′′)silver(I)] bis­(trifluoro­methane­sulfonate)
title [μ-1,2-Bis(4-pyrid­yl)ethane-κ(2) N:N′]bis­[(4′-phenyl-2,2′:6′,2′′-terpyridine-κ(3) N,N′,N′′)silver(I)] bis­(trifluoro­methane­sulfonate)
title_full [μ-1,2-Bis(4-pyrid­yl)ethane-κ(2) N:N′]bis­[(4′-phenyl-2,2′:6′,2′′-terpyridine-κ(3) N,N′,N′′)silver(I)] bis­(trifluoro­methane­sulfonate)
title_fullStr [μ-1,2-Bis(4-pyrid­yl)ethane-κ(2) N:N′]bis­[(4′-phenyl-2,2′:6′,2′′-terpyridine-κ(3) N,N′,N′′)silver(I)] bis­(trifluoro­methane­sulfonate)
title_full_unstemmed [μ-1,2-Bis(4-pyrid­yl)ethane-κ(2) N:N′]bis­[(4′-phenyl-2,2′:6′,2′′-terpyridine-κ(3) N,N′,N′′)silver(I)] bis­(trifluoro­methane­sulfonate)
title_short [μ-1,2-Bis(4-pyrid­yl)ethane-κ(2) N:N′]bis­[(4′-phenyl-2,2′:6′,2′′-terpyridine-κ(3) N,N′,N′′)silver(I)] bis­(trifluoro­methane­sulfonate)
title_sort [μ-1,2-bis(4-pyrid­yl)ethane-κ(2) n:n′]bis­[(4′-phenyl-2,2′:6′,2′′-terpyridine-κ(3) n,n′,n′′)silver(i)] bis­(trifluoro­methane­sulfonate)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3008054/
https://www.ncbi.nlm.nih.gov/pubmed/21588522
http://dx.doi.org/10.1107/S1600536810031776
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