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[μ-1,2-Bis(4-pyridyl)ethane-κ(2) N:N′]bis[(4′-phenyl-2,2′:6′,2′′-terpyridine-κ(3) N,N′,N′′)silver(I)] bis(trifluoromethanesulfonate)
In the title compound, [Ag(2)(C(12)H(12)N(2))(C(21)H(15)N(3))(2)](CF(3)SO(3))(2), the Ag(I) atom is coordinated by three N atoms of one 4′-phenyl-2,2′:6′,2′′-terpyridine (phtpy) ligand and one pyridyl N atom of the 1,2-bis(4-pyridyl)ethane (bpe) ligand, displaying a distorted square-planar geometr...
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2010
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3008054/ https://www.ncbi.nlm.nih.gov/pubmed/21588522 http://dx.doi.org/10.1107/S1600536810031776 |
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author | Ma, Yajun Liu, Buming Xue, Chenghu |
author_facet | Ma, Yajun Liu, Buming Xue, Chenghu |
author_sort | Ma, Yajun |
collection | PubMed |
description | In the title compound, [Ag(2)(C(12)H(12)N(2))(C(21)H(15)N(3))(2)](CF(3)SO(3))(2), the Ag(I) atom is coordinated by three N atoms of one 4′-phenyl-2,2′:6′,2′′-terpyridine (phtpy) ligand and one pyridyl N atom of the 1,2-bis(4-pyridyl)ethane (bpe) ligand, displaying a distorted square-planar geometry. Two Ag(I) atoms are bridged by one trans-bpe ligand, generating a dinuclear cation. The dinuclear cation is located on a centre of inversion, which is in the middle of the ethylene fragment of the bpe ligand. In the crystal, the pyridyl rings of neighboring dinuclear units are stacked by π–π interactions with centroid–centroid distances of 3.667 (2) and 3.835 (2) Å. The F and O atoms of the CF(3)SO(3) (−) anions are involved in intermolecular C—H⋯F and C—H⋯O hydrogen-bonding interactions, respectively, with –CH groups from the phtpy ligands. |
format | Text |
id | pubmed-3008054 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2010 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-30080542010-12-30 [μ-1,2-Bis(4-pyridyl)ethane-κ(2) N:N′]bis[(4′-phenyl-2,2′:6′,2′′-terpyridine-κ(3) N,N′,N′′)silver(I)] bis(trifluoromethanesulfonate) Ma, Yajun Liu, Buming Xue, Chenghu Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Ag(2)(C(12)H(12)N(2))(C(21)H(15)N(3))(2)](CF(3)SO(3))(2), the Ag(I) atom is coordinated by three N atoms of one 4′-phenyl-2,2′:6′,2′′-terpyridine (phtpy) ligand and one pyridyl N atom of the 1,2-bis(4-pyridyl)ethane (bpe) ligand, displaying a distorted square-planar geometry. Two Ag(I) atoms are bridged by one trans-bpe ligand, generating a dinuclear cation. The dinuclear cation is located on a centre of inversion, which is in the middle of the ethylene fragment of the bpe ligand. In the crystal, the pyridyl rings of neighboring dinuclear units are stacked by π–π interactions with centroid–centroid distances of 3.667 (2) and 3.835 (2) Å. The F and O atoms of the CF(3)SO(3) (−) anions are involved in intermolecular C—H⋯F and C—H⋯O hydrogen-bonding interactions, respectively, with –CH groups from the phtpy ligands. International Union of Crystallography 2010-08-18 /pmc/articles/PMC3008054/ /pubmed/21588522 http://dx.doi.org/10.1107/S1600536810031776 Text en © Ma et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Ma, Yajun Liu, Buming Xue, Chenghu [μ-1,2-Bis(4-pyridyl)ethane-κ(2) N:N′]bis[(4′-phenyl-2,2′:6′,2′′-terpyridine-κ(3) N,N′,N′′)silver(I)] bis(trifluoromethanesulfonate) |
title | [μ-1,2-Bis(4-pyridyl)ethane-κ(2)
N:N′]bis[(4′-phenyl-2,2′:6′,2′′-terpyridine-κ(3)
N,N′,N′′)silver(I)] bis(trifluoromethanesulfonate) |
title_full | [μ-1,2-Bis(4-pyridyl)ethane-κ(2)
N:N′]bis[(4′-phenyl-2,2′:6′,2′′-terpyridine-κ(3)
N,N′,N′′)silver(I)] bis(trifluoromethanesulfonate) |
title_fullStr | [μ-1,2-Bis(4-pyridyl)ethane-κ(2)
N:N′]bis[(4′-phenyl-2,2′:6′,2′′-terpyridine-κ(3)
N,N′,N′′)silver(I)] bis(trifluoromethanesulfonate) |
title_full_unstemmed | [μ-1,2-Bis(4-pyridyl)ethane-κ(2)
N:N′]bis[(4′-phenyl-2,2′:6′,2′′-terpyridine-κ(3)
N,N′,N′′)silver(I)] bis(trifluoromethanesulfonate) |
title_short | [μ-1,2-Bis(4-pyridyl)ethane-κ(2)
N:N′]bis[(4′-phenyl-2,2′:6′,2′′-terpyridine-κ(3)
N,N′,N′′)silver(I)] bis(trifluoromethanesulfonate) |
title_sort | [μ-1,2-bis(4-pyridyl)ethane-κ(2)
n:n′]bis[(4′-phenyl-2,2′:6′,2′′-terpyridine-κ(3)
n,n′,n′′)silver(i)] bis(trifluoromethanesulfonate) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3008054/ https://www.ncbi.nlm.nih.gov/pubmed/21588522 http://dx.doi.org/10.1107/S1600536810031776 |
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