{4-Chloro-2-[(2-hy­droxy­eth­yl)imino­meth­yl]phenolato}{4-chloro-2-[(2-oxido­eth­yl)imino­meth­yl]phenolato}cobalt(III)

In the title mononuclear cobalt(III) compound, [Co(C(9)H(8)ClNO(2))(C(9)H(9)ClNO(2))], the Co(II) atom is six-coordinated by two imine N atoms, two phenolate O atoms, and one hy­droxy and one oxide O atom from two Schiff base ligands, forming an octa­hedral geometry. In the crystal structure, adjace...

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Detalles Bibliográficos
Autor principal: Liu, Li-Jun
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3008055/
https://www.ncbi.nlm.nih.gov/pubmed/21588541
http://dx.doi.org/10.1107/S1600536810033088
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author Liu, Li-Jun
author_facet Liu, Li-Jun
author_sort Liu, Li-Jun
collection PubMed
description In the title mononuclear cobalt(III) compound, [Co(C(9)H(8)ClNO(2))(C(9)H(9)ClNO(2))], the Co(II) atom is six-coordinated by two imine N atoms, two phenolate O atoms, and one hy­droxy and one oxide O atom from two Schiff base ligands, forming an octa­hedral geometry. In the crystal structure, adjacent mol­ecules are linked through inter­molecular O—H⋯O hydrogen bonds. The 2-oxidoethyl group is disordered over two positions in a 0.638 (3):0.362 (3) ratio.
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spelling pubmed-30080552010-12-30 {4-Chloro-2-[(2-hy­droxy­eth­yl)imino­meth­yl]phenolato}{4-chloro-2-[(2-oxido­eth­yl)imino­meth­yl]phenolato}cobalt(III) Liu, Li-Jun Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title mononuclear cobalt(III) compound, [Co(C(9)H(8)ClNO(2))(C(9)H(9)ClNO(2))], the Co(II) atom is six-coordinated by two imine N atoms, two phenolate O atoms, and one hy­droxy and one oxide O atom from two Schiff base ligands, forming an octa­hedral geometry. In the crystal structure, adjacent mol­ecules are linked through inter­molecular O—H⋯O hydrogen bonds. The 2-oxidoethyl group is disordered over two positions in a 0.638 (3):0.362 (3) ratio. International Union of Crystallography 2010-08-21 /pmc/articles/PMC3008055/ /pubmed/21588541 http://dx.doi.org/10.1107/S1600536810033088 Text en © Li-Jun Liu 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Liu, Li-Jun
{4-Chloro-2-[(2-hy­droxy­eth­yl)imino­meth­yl]phenolato}{4-chloro-2-[(2-oxido­eth­yl)imino­meth­yl]phenolato}cobalt(III)
title {4-Chloro-2-[(2-hy­droxy­eth­yl)imino­meth­yl]phenolato}{4-chloro-2-[(2-oxido­eth­yl)imino­meth­yl]phenolato}cobalt(III)
title_full {4-Chloro-2-[(2-hy­droxy­eth­yl)imino­meth­yl]phenolato}{4-chloro-2-[(2-oxido­eth­yl)imino­meth­yl]phenolato}cobalt(III)
title_fullStr {4-Chloro-2-[(2-hy­droxy­eth­yl)imino­meth­yl]phenolato}{4-chloro-2-[(2-oxido­eth­yl)imino­meth­yl]phenolato}cobalt(III)
title_full_unstemmed {4-Chloro-2-[(2-hy­droxy­eth­yl)imino­meth­yl]phenolato}{4-chloro-2-[(2-oxido­eth­yl)imino­meth­yl]phenolato}cobalt(III)
title_short {4-Chloro-2-[(2-hy­droxy­eth­yl)imino­meth­yl]phenolato}{4-chloro-2-[(2-oxido­eth­yl)imino­meth­yl]phenolato}cobalt(III)
title_sort {4-chloro-2-[(2-hy­droxy­eth­yl)imino­meth­yl]phenolato}{4-chloro-2-[(2-oxido­eth­yl)imino­meth­yl]phenolato}cobalt(iii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3008055/
https://www.ncbi.nlm.nih.gov/pubmed/21588541
http://dx.doi.org/10.1107/S1600536810033088
work_keys_str_mv AT liulijun 4chloro22hydroxyethyliminomethylphenolato4chloro22oxidoethyliminomethylphenolatocobaltiii

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