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Diaqua­bis­(5-carb­oxy-2-propyl-1H-imidazole-4-carboxyl­ato-κ(2) N (3),O (4))zinc(II) 3.5-hydrate

In the title complex, [Zn(C(8)H(9)N(2)O(4))(2)(H(2)O)(2)]·3.5H(2)O, the Zn(II) ion is coordinated by two N,O-bidentate H(2)pimda ligands (H(3)pimda = 2-propyl-1H-imidazole-4,5-dicarb­oxy­lic acid) and two water mol­ecules in a distorted octa­hedral environment. In the crystal structure, extensive in...

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Autores principales: Li, Shi-Jie, Song, Wen-Dong, Li, Shi-Hong, Dong, Jing-Jing, Yan, Jian-Bin
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3008058/
https://www.ncbi.nlm.nih.gov/pubmed/21588509
http://dx.doi.org/10.1107/S1600536810031478
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author Li, Shi-Jie
Song, Wen-Dong
Li, Shi-Hong
Dong, Jing-Jing
Yan, Jian-Bin
author_facet Li, Shi-Jie
Song, Wen-Dong
Li, Shi-Hong
Dong, Jing-Jing
Yan, Jian-Bin
author_sort Li, Shi-Jie
collection PubMed
description In the title complex, [Zn(C(8)H(9)N(2)O(4))(2)(H(2)O)(2)]·3.5H(2)O, the Zn(II) ion is coordinated by two N,O-bidentate H(2)pimda ligands (H(3)pimda = 2-propyl-1H-imidazole-4,5-dicarb­oxy­lic acid) and two water mol­ecules in a distorted octa­hedral environment. In the crystal structure, extensive inter­molecular O—H⋯O and N—H⋯O hydrogen bonds stabilize the three-dimensional supra­molecular network. Intra­molecular O—H⋯O hydrogen bonds between the carboxyl groups are also observed. The propyl groups of the two H(2)pimda ligands are disordered each over two sites, with occupancy factors of 0.752 (5):0.248 (5) and 0.519 (7):0.481 (7). One of the water mol­ecules is half-occupied.
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spelling pubmed-30080582010-12-30 Diaqua­bis­(5-carb­oxy-2-propyl-1H-imidazole-4-carboxyl­ato-κ(2) N (3),O (4))zinc(II) 3.5-hydrate Li, Shi-Jie Song, Wen-Dong Li, Shi-Hong Dong, Jing-Jing Yan, Jian-Bin Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [Zn(C(8)H(9)N(2)O(4))(2)(H(2)O)(2)]·3.5H(2)O, the Zn(II) ion is coordinated by two N,O-bidentate H(2)pimda ligands (H(3)pimda = 2-propyl-1H-imidazole-4,5-dicarb­oxy­lic acid) and two water mol­ecules in a distorted octa­hedral environment. In the crystal structure, extensive inter­molecular O—H⋯O and N—H⋯O hydrogen bonds stabilize the three-dimensional supra­molecular network. Intra­molecular O—H⋯O hydrogen bonds between the carboxyl groups are also observed. The propyl groups of the two H(2)pimda ligands are disordered each over two sites, with occupancy factors of 0.752 (5):0.248 (5) and 0.519 (7):0.481 (7). One of the water mol­ecules is half-occupied. International Union of Crystallography 2010-08-18 /pmc/articles/PMC3008058/ /pubmed/21588509 http://dx.doi.org/10.1107/S1600536810031478 Text en © Li et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Li, Shi-Jie
Song, Wen-Dong
Li, Shi-Hong
Dong, Jing-Jing
Yan, Jian-Bin
Diaqua­bis­(5-carb­oxy-2-propyl-1H-imidazole-4-carboxyl­ato-κ(2) N (3),O (4))zinc(II) 3.5-hydrate
title Diaqua­bis­(5-carb­oxy-2-propyl-1H-imidazole-4-carboxyl­ato-κ(2) N (3),O (4))zinc(II) 3.5-hydrate
title_full Diaqua­bis­(5-carb­oxy-2-propyl-1H-imidazole-4-carboxyl­ato-κ(2) N (3),O (4))zinc(II) 3.5-hydrate
title_fullStr Diaqua­bis­(5-carb­oxy-2-propyl-1H-imidazole-4-carboxyl­ato-κ(2) N (3),O (4))zinc(II) 3.5-hydrate
title_full_unstemmed Diaqua­bis­(5-carb­oxy-2-propyl-1H-imidazole-4-carboxyl­ato-κ(2) N (3),O (4))zinc(II) 3.5-hydrate
title_short Diaqua­bis­(5-carb­oxy-2-propyl-1H-imidazole-4-carboxyl­ato-κ(2) N (3),O (4))zinc(II) 3.5-hydrate
title_sort diaqua­bis­(5-carb­oxy-2-propyl-1h-imidazole-4-carboxyl­ato-κ(2) n (3),o (4))zinc(ii) 3.5-hydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3008058/
https://www.ncbi.nlm.nih.gov/pubmed/21588509
http://dx.doi.org/10.1107/S1600536810031478
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