Cargando…
Diaquabis(5-carboxy-2-propyl-1H-imidazole-4-carboxylato-κ(2) N (3),O (4))zinc(II) 3.5-hydrate
In the title complex, [Zn(C(8)H(9)N(2)O(4))(2)(H(2)O)(2)]·3.5H(2)O, the Zn(II) ion is coordinated by two N,O-bidentate H(2)pimda ligands (H(3)pimda = 2-propyl-1H-imidazole-4,5-dicarboxylic acid) and two water molecules in a distorted octahedral environment. In the crystal structure, extensive in...
Autores principales: | , , , , |
---|---|
Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2010
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3008058/ https://www.ncbi.nlm.nih.gov/pubmed/21588509 http://dx.doi.org/10.1107/S1600536810031478 |
_version_ | 1782194492293513216 |
---|---|
author | Li, Shi-Jie Song, Wen-Dong Li, Shi-Hong Dong, Jing-Jing Yan, Jian-Bin |
author_facet | Li, Shi-Jie Song, Wen-Dong Li, Shi-Hong Dong, Jing-Jing Yan, Jian-Bin |
author_sort | Li, Shi-Jie |
collection | PubMed |
description | In the title complex, [Zn(C(8)H(9)N(2)O(4))(2)(H(2)O)(2)]·3.5H(2)O, the Zn(II) ion is coordinated by two N,O-bidentate H(2)pimda ligands (H(3)pimda = 2-propyl-1H-imidazole-4,5-dicarboxylic acid) and two water molecules in a distorted octahedral environment. In the crystal structure, extensive intermolecular O—H⋯O and N—H⋯O hydrogen bonds stabilize the three-dimensional supramolecular network. Intramolecular O—H⋯O hydrogen bonds between the carboxyl groups are also observed. The propyl groups of the two H(2)pimda ligands are disordered each over two sites, with occupancy factors of 0.752 (5):0.248 (5) and 0.519 (7):0.481 (7). One of the water molecules is half-occupied. |
format | Text |
id | pubmed-3008058 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2010 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-30080582010-12-30 Diaquabis(5-carboxy-2-propyl-1H-imidazole-4-carboxylato-κ(2) N (3),O (4))zinc(II) 3.5-hydrate Li, Shi-Jie Song, Wen-Dong Li, Shi-Hong Dong, Jing-Jing Yan, Jian-Bin Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [Zn(C(8)H(9)N(2)O(4))(2)(H(2)O)(2)]·3.5H(2)O, the Zn(II) ion is coordinated by two N,O-bidentate H(2)pimda ligands (H(3)pimda = 2-propyl-1H-imidazole-4,5-dicarboxylic acid) and two water molecules in a distorted octahedral environment. In the crystal structure, extensive intermolecular O—H⋯O and N—H⋯O hydrogen bonds stabilize the three-dimensional supramolecular network. Intramolecular O—H⋯O hydrogen bonds between the carboxyl groups are also observed. The propyl groups of the two H(2)pimda ligands are disordered each over two sites, with occupancy factors of 0.752 (5):0.248 (5) and 0.519 (7):0.481 (7). One of the water molecules is half-occupied. International Union of Crystallography 2010-08-18 /pmc/articles/PMC3008058/ /pubmed/21588509 http://dx.doi.org/10.1107/S1600536810031478 Text en © Li et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Li, Shi-Jie Song, Wen-Dong Li, Shi-Hong Dong, Jing-Jing Yan, Jian-Bin Diaquabis(5-carboxy-2-propyl-1H-imidazole-4-carboxylato-κ(2) N (3),O (4))zinc(II) 3.5-hydrate |
title | Diaquabis(5-carboxy-2-propyl-1H-imidazole-4-carboxylato-κ(2)
N
(3),O
(4))zinc(II) 3.5-hydrate |
title_full | Diaquabis(5-carboxy-2-propyl-1H-imidazole-4-carboxylato-κ(2)
N
(3),O
(4))zinc(II) 3.5-hydrate |
title_fullStr | Diaquabis(5-carboxy-2-propyl-1H-imidazole-4-carboxylato-κ(2)
N
(3),O
(4))zinc(II) 3.5-hydrate |
title_full_unstemmed | Diaquabis(5-carboxy-2-propyl-1H-imidazole-4-carboxylato-κ(2)
N
(3),O
(4))zinc(II) 3.5-hydrate |
title_short | Diaquabis(5-carboxy-2-propyl-1H-imidazole-4-carboxylato-κ(2)
N
(3),O
(4))zinc(II) 3.5-hydrate |
title_sort | diaquabis(5-carboxy-2-propyl-1h-imidazole-4-carboxylato-κ(2)
n
(3),o
(4))zinc(ii) 3.5-hydrate |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3008058/ https://www.ncbi.nlm.nih.gov/pubmed/21588509 http://dx.doi.org/10.1107/S1600536810031478 |
work_keys_str_mv | AT lishijie diaquabis5carboxy2propyl1himidazole4carboxylatok2n3o4zincii35hydrate AT songwendong diaquabis5carboxy2propyl1himidazole4carboxylatok2n3o4zincii35hydrate AT lishihong diaquabis5carboxy2propyl1himidazole4carboxylatok2n3o4zincii35hydrate AT dongjingjing diaquabis5carboxy2propyl1himidazole4carboxylatok2n3o4zincii35hydrate AT yanjianbin diaquabis5carboxy2propyl1himidazole4carboxylatok2n3o4zincii35hydrate |