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μ-Oxalato-bis[(2,2′-bipyridyl)copper(II)] bis(perchlorate) dimethylformamide disolvate monohydrate
The title compound, [Cu(2)(C(2)O(4))(C(10)H(8)N(2))(4)](ClO(4))(2)·2C(3)H(7)NO·H(2)O, contains doubly charged centrosymmetric dinuclear oxalato-bridged copper(II) complex cations, perchlorate anions, and DMF and water solvate molecules. In the complex cation, the oxalate ligand is coordinated in a...
Autores principales: | , , , , |
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2010
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3008067/ https://www.ncbi.nlm.nih.gov/pubmed/21588513 http://dx.doi.org/10.1107/S1600536810031569 |
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author | Boyko, Alexander N. Haukka, Matti Golenya, Irina A. Pavlova, Svetlana V. Usenko, Natalia I. |
author_facet | Boyko, Alexander N. Haukka, Matti Golenya, Irina A. Pavlova, Svetlana V. Usenko, Natalia I. |
author_sort | Boyko, Alexander N. |
collection | PubMed |
description | The title compound, [Cu(2)(C(2)O(4))(C(10)H(8)N(2))(4)](ClO(4))(2)·2C(3)H(7)NO·H(2)O, contains doubly charged centrosymmetric dinuclear oxalato-bridged copper(II) complex cations, perchlorate anions, and DMF and water solvate molecules. In the complex cation, the oxalate ligand is coordinated in a bis-bidentate bridging mode to the Cu atoms. Each Cu atom has a distorted tetragonal-bipyramidal environment, being coordinated by two N atoms of the two chelating bipy ligands and two O atoms of the doubly deprotonated oxalate anion. Pairs of perchlorate anions and water molecules are linked into rectangles by O—H⋯O bonds in which the perchlorate O atoms act as acceptors and the water molecules as donors. Methyl groups of the DMF solvent molecule are disordered over two sites with occupancies of 0.453 (7):0.547 (7), and the water molecule is half-occupied. |
format | Text |
id | pubmed-3008067 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2010 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-30080672010-12-30 μ-Oxalato-bis[(2,2′-bipyridyl)copper(II)] bis(perchlorate) dimethylformamide disolvate monohydrate Boyko, Alexander N. Haukka, Matti Golenya, Irina A. Pavlova, Svetlana V. Usenko, Natalia I. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Cu(2)(C(2)O(4))(C(10)H(8)N(2))(4)](ClO(4))(2)·2C(3)H(7)NO·H(2)O, contains doubly charged centrosymmetric dinuclear oxalato-bridged copper(II) complex cations, perchlorate anions, and DMF and water solvate molecules. In the complex cation, the oxalate ligand is coordinated in a bis-bidentate bridging mode to the Cu atoms. Each Cu atom has a distorted tetragonal-bipyramidal environment, being coordinated by two N atoms of the two chelating bipy ligands and two O atoms of the doubly deprotonated oxalate anion. Pairs of perchlorate anions and water molecules are linked into rectangles by O—H⋯O bonds in which the perchlorate O atoms act as acceptors and the water molecules as donors. Methyl groups of the DMF solvent molecule are disordered over two sites with occupancies of 0.453 (7):0.547 (7), and the water molecule is half-occupied. International Union of Crystallography 2010-08-18 /pmc/articles/PMC3008067/ /pubmed/21588513 http://dx.doi.org/10.1107/S1600536810031569 Text en © Boyko et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Boyko, Alexander N. Haukka, Matti Golenya, Irina A. Pavlova, Svetlana V. Usenko, Natalia I. μ-Oxalato-bis[(2,2′-bipyridyl)copper(II)] bis(perchlorate) dimethylformamide disolvate monohydrate |
title | μ-Oxalato-bis[(2,2′-bipyridyl)copper(II)] bis(perchlorate) dimethylformamide disolvate monohydrate |
title_full | μ-Oxalato-bis[(2,2′-bipyridyl)copper(II)] bis(perchlorate) dimethylformamide disolvate monohydrate |
title_fullStr | μ-Oxalato-bis[(2,2′-bipyridyl)copper(II)] bis(perchlorate) dimethylformamide disolvate monohydrate |
title_full_unstemmed | μ-Oxalato-bis[(2,2′-bipyridyl)copper(II)] bis(perchlorate) dimethylformamide disolvate monohydrate |
title_short | μ-Oxalato-bis[(2,2′-bipyridyl)copper(II)] bis(perchlorate) dimethylformamide disolvate monohydrate |
title_sort | μ-oxalato-bis[(2,2′-bipyridyl)copper(ii)] bis(perchlorate) dimethylformamide disolvate monohydrate |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3008067/ https://www.ncbi.nlm.nih.gov/pubmed/21588513 http://dx.doi.org/10.1107/S1600536810031569 |
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