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Quinoline-2-carbonitrile–fumaric acid (1/0.5)

The asymmetric unit of the title compound, C(10)H(6)N(2)·0.5C(4)H(4)O(4), consists of one quinoline-2-carbonitrile mol­ecule and a half-mol­ecule of fumaric acid, which lies on an inversion center. The quinoline-2-carbonitrile mol­ecule is almost planar, with an r.m.s. deviation of 0.008 (1) Å. The...

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Detalles Bibliográficos
Autores principales: Loh, Wan-Sin, Quah, Ching Kheng, Hemamalini, Madhukar, Fun, Hoong-Kun
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3008075/
https://www.ncbi.nlm.nih.gov/pubmed/21588699
http://dx.doi.org/10.1107/S1600536810032745
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author Loh, Wan-Sin
Quah, Ching Kheng
Hemamalini, Madhukar
Fun, Hoong-Kun
author_facet Loh, Wan-Sin
Quah, Ching Kheng
Hemamalini, Madhukar
Fun, Hoong-Kun
author_sort Loh, Wan-Sin
collection PubMed
description The asymmetric unit of the title compound, C(10)H(6)N(2)·0.5C(4)H(4)O(4), consists of one quinoline-2-carbonitrile mol­ecule and a half-mol­ecule of fumaric acid, which lies on an inversion center. The quinoline-2-carbonitrile mol­ecule is almost planar, with an r.m.s. deviation of 0.008 (1) Å. The acid and base are linked together via pairs of inter­molecular C—H⋯O and O—H⋯N hydrogen bonds, forming R (2) (2)(8) ring motifs. In the crystal, the carbonitrile mol­ecules are further linked by inter­molecular C—H⋯N hydrogen bonds, generating R (2) (2)(10) ring motifs, resulting in zigzag chains running along the c axis.
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spelling pubmed-30080752010-12-30 Quinoline-2-carbonitrile–fumaric acid (1/0.5) Loh, Wan-Sin Quah, Ching Kheng Hemamalini, Madhukar Fun, Hoong-Kun Acta Crystallogr Sect E Struct Rep Online Organic Papers The asymmetric unit of the title compound, C(10)H(6)N(2)·0.5C(4)H(4)O(4), consists of one quinoline-2-carbonitrile mol­ecule and a half-mol­ecule of fumaric acid, which lies on an inversion center. The quinoline-2-carbonitrile mol­ecule is almost planar, with an r.m.s. deviation of 0.008 (1) Å. The acid and base are linked together via pairs of inter­molecular C—H⋯O and O—H⋯N hydrogen bonds, forming R (2) (2)(8) ring motifs. In the crystal, the carbonitrile mol­ecules are further linked by inter­molecular C—H⋯N hydrogen bonds, generating R (2) (2)(10) ring motifs, resulting in zigzag chains running along the c axis. International Union of Crystallography 2010-08-21 /pmc/articles/PMC3008075/ /pubmed/21588699 http://dx.doi.org/10.1107/S1600536810032745 Text en © Loh et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Loh, Wan-Sin
Quah, Ching Kheng
Hemamalini, Madhukar
Fun, Hoong-Kun
Quinoline-2-carbonitrile–fumaric acid (1/0.5)
title Quinoline-2-carbonitrile–fumaric acid (1/0.5)
title_full Quinoline-2-carbonitrile–fumaric acid (1/0.5)
title_fullStr Quinoline-2-carbonitrile–fumaric acid (1/0.5)
title_full_unstemmed Quinoline-2-carbonitrile–fumaric acid (1/0.5)
title_short Quinoline-2-carbonitrile–fumaric acid (1/0.5)
title_sort quinoline-2-carbonitrile–fumaric acid (1/0.5)
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3008075/
https://www.ncbi.nlm.nih.gov/pubmed/21588699
http://dx.doi.org/10.1107/S1600536810032745
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