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Quinoline-2-carbonitrile–fumaric acid (1/0.5)
The asymmetric unit of the title compound, C(10)H(6)N(2)·0.5C(4)H(4)O(4), consists of one quinoline-2-carbonitrile molecule and a half-molecule of fumaric acid, which lies on an inversion center. The quinoline-2-carbonitrile molecule is almost planar, with an r.m.s. deviation of 0.008 (1) Å. The...
Autores principales: | , , , |
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2010
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3008075/ https://www.ncbi.nlm.nih.gov/pubmed/21588699 http://dx.doi.org/10.1107/S1600536810032745 |
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author | Loh, Wan-Sin Quah, Ching Kheng Hemamalini, Madhukar Fun, Hoong-Kun |
author_facet | Loh, Wan-Sin Quah, Ching Kheng Hemamalini, Madhukar Fun, Hoong-Kun |
author_sort | Loh, Wan-Sin |
collection | PubMed |
description | The asymmetric unit of the title compound, C(10)H(6)N(2)·0.5C(4)H(4)O(4), consists of one quinoline-2-carbonitrile molecule and a half-molecule of fumaric acid, which lies on an inversion center. The quinoline-2-carbonitrile molecule is almost planar, with an r.m.s. deviation of 0.008 (1) Å. The acid and base are linked together via pairs of intermolecular C—H⋯O and O—H⋯N hydrogen bonds, forming R (2) (2)(8) ring motifs. In the crystal, the carbonitrile molecules are further linked by intermolecular C—H⋯N hydrogen bonds, generating R (2) (2)(10) ring motifs, resulting in zigzag chains running along the c axis. |
format | Text |
id | pubmed-3008075 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2010 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-30080752010-12-30 Quinoline-2-carbonitrile–fumaric acid (1/0.5) Loh, Wan-Sin Quah, Ching Kheng Hemamalini, Madhukar Fun, Hoong-Kun Acta Crystallogr Sect E Struct Rep Online Organic Papers The asymmetric unit of the title compound, C(10)H(6)N(2)·0.5C(4)H(4)O(4), consists of one quinoline-2-carbonitrile molecule and a half-molecule of fumaric acid, which lies on an inversion center. The quinoline-2-carbonitrile molecule is almost planar, with an r.m.s. deviation of 0.008 (1) Å. The acid and base are linked together via pairs of intermolecular C—H⋯O and O—H⋯N hydrogen bonds, forming R (2) (2)(8) ring motifs. In the crystal, the carbonitrile molecules are further linked by intermolecular C—H⋯N hydrogen bonds, generating R (2) (2)(10) ring motifs, resulting in zigzag chains running along the c axis. International Union of Crystallography 2010-08-21 /pmc/articles/PMC3008075/ /pubmed/21588699 http://dx.doi.org/10.1107/S1600536810032745 Text en © Loh et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Loh, Wan-Sin Quah, Ching Kheng Hemamalini, Madhukar Fun, Hoong-Kun Quinoline-2-carbonitrile–fumaric acid (1/0.5) |
title | Quinoline-2-carbonitrile–fumaric acid (1/0.5) |
title_full | Quinoline-2-carbonitrile–fumaric acid (1/0.5) |
title_fullStr | Quinoline-2-carbonitrile–fumaric acid (1/0.5) |
title_full_unstemmed | Quinoline-2-carbonitrile–fumaric acid (1/0.5) |
title_short | Quinoline-2-carbonitrile–fumaric acid (1/0.5) |
title_sort | quinoline-2-carbonitrile–fumaric acid (1/0.5) |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3008075/ https://www.ncbi.nlm.nih.gov/pubmed/21588699 http://dx.doi.org/10.1107/S1600536810032745 |
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