4′-Chloro­biphenyl-3-yl 2,2,2-trichloro­ethyl sulfate

The title compound, C(14)H(10)Cl(4)O(4)S, is a 2,2,2-trichloro­ethyl-protected precursor of 4′-chloro­biphenyl-3-yl sulfate, a sulfuric acid ester of 4′-chloro­biphenyl-3-ol. The C(aromatic)—O and O—S bond lengths of the C(aromatic)—O—S unit are comparable to those in structurally analogous biphenyl...

Descripción completa

Detalles Bibliográficos
Autores principales: Li, Xueshu, Parkin, Sean, Duffel, Michael W., Robertson, Larry W., Lehmler, Hans-Joachim
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3008081/
https://www.ncbi.nlm.nih.gov/pubmed/21588655
http://dx.doi.org/10.1107/S1600536810031338
_version_ 1782194497998815232
author Li, Xueshu
Parkin, Sean
Duffel, Michael W.
Robertson, Larry W.
Lehmler, Hans-Joachim
author_facet Li, Xueshu
Parkin, Sean
Duffel, Michael W.
Robertson, Larry W.
Lehmler, Hans-Joachim
author_sort Li, Xueshu
collection PubMed
description The title compound, C(14)H(10)Cl(4)O(4)S, is a 2,2,2-trichloro­ethyl-protected precursor of 4′-chloro­biphenyl-3-yl sulfate, a sulfuric acid ester of 4′-chloro­biphenyl-3-ol. The C(aromatic)—O and O—S bond lengths of the C(aromatic)—O—S unit are comparable to those in structurally analogous biphenyl-4-yl 2,2,2-trichloro­ethyl sulfates with no electro­negative chlorine substituent in the benzene ring with the sulfate ester group. The dihedral angle between the aromatic rings is 27.47 (6)°.
format Text
id pubmed-3008081
institution National Center for Biotechnology Information
language English
publishDate 2010
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-30080812010-12-30 4′-Chloro­biphenyl-3-yl 2,2,2-trichloro­ethyl sulfate Li, Xueshu Parkin, Sean Duffel, Michael W. Robertson, Larry W. Lehmler, Hans-Joachim Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(14)H(10)Cl(4)O(4)S, is a 2,2,2-trichloro­ethyl-protected precursor of 4′-chloro­biphenyl-3-yl sulfate, a sulfuric acid ester of 4′-chloro­biphenyl-3-ol. The C(aromatic)—O and O—S bond lengths of the C(aromatic)—O—S unit are comparable to those in structurally analogous biphenyl-4-yl 2,2,2-trichloro­ethyl sulfates with no electro­negative chlorine substituent in the benzene ring with the sulfate ester group. The dihedral angle between the aromatic rings is 27.47 (6)°. International Union of Crystallography 2010-08-18 /pmc/articles/PMC3008081/ /pubmed/21588655 http://dx.doi.org/10.1107/S1600536810031338 Text en © Li et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Li, Xueshu
Parkin, Sean
Duffel, Michael W.
Robertson, Larry W.
Lehmler, Hans-Joachim
4′-Chloro­biphenyl-3-yl 2,2,2-trichloro­ethyl sulfate
title 4′-Chloro­biphenyl-3-yl 2,2,2-trichloro­ethyl sulfate
title_full 4′-Chloro­biphenyl-3-yl 2,2,2-trichloro­ethyl sulfate
title_fullStr 4′-Chloro­biphenyl-3-yl 2,2,2-trichloro­ethyl sulfate
title_full_unstemmed 4′-Chloro­biphenyl-3-yl 2,2,2-trichloro­ethyl sulfate
title_short 4′-Chloro­biphenyl-3-yl 2,2,2-trichloro­ethyl sulfate
title_sort 4′-chloro­biphenyl-3-yl 2,2,2-trichloro­ethyl sulfate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3008081/
https://www.ncbi.nlm.nih.gov/pubmed/21588655
http://dx.doi.org/10.1107/S1600536810031338
work_keys_str_mv AT lixueshu 4chlorobiphenyl3yl222trichloroethylsulfate
AT parkinsean 4chlorobiphenyl3yl222trichloroethylsulfate
AT duffelmichaelw 4chlorobiphenyl3yl222trichloroethylsulfate
AT robertsonlarryw 4chlorobiphenyl3yl222trichloroethylsulfate
AT lehmlerhansjoachim 4chlorobiphenyl3yl222trichloroethylsulfate

Ejemplares similares