Aqua­[1,3-bis­(benzimidazol-2-yl)-2-oxapropane]­diethano­lmanganese(II) dipicrate ethanol disolvate

In the title complex, [Mn(C(16)H(14)N(4)O)(C(2)H(5)OH)(2)(H(2)O)](C(6)H(2)N(3)O(7))(2)·2C(2)H(5)OH, the Mn(II) ion is in a distorted octa­hedral coordination environment, defined by an MnN(2)O(4) donor set. The 1,3-bis­(benz­imid­azol-2-yl)-2-oxapropane ligand is tridentate. In the crystal structure...

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Detalles Bibliográficos
Autores principales: Sun, Tao, Li, Ke, Lai, Yulin, Chen, Ruihuan, Wu, Huilu
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3008082/
https://www.ncbi.nlm.nih.gov/pubmed/21588483
http://dx.doi.org/10.1107/S1600536810030357
Descripción
Sumario:In the title complex, [Mn(C(16)H(14)N(4)O)(C(2)H(5)OH)(2)(H(2)O)](C(6)H(2)N(3)O(7))(2)·2C(2)H(5)OH, the Mn(II) ion is in a distorted octa­hedral coordination environment, defined by an MnN(2)O(4) donor set. The 1,3-bis­(benz­imid­azol-2-yl)-2-oxapropane ligand is tridentate. In the crystal structure, inter­molecular N—H⋯O and O—H⋯O hydrogen bonds link the components into a three-dimensional network. The O atoms of one of the nitro groups are disordered over two sets of sites with refined occupancies of 0.577 (11) and 0.423 (11).

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